ISSN:
1573-9171
Keywords:
vanadatrane
;
crystal structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract An X-ray diffraction study of a substituted vanadatrane-1-one (space groupPna21,R= 0.019 for 1394 reflections, the absolute structure was determined) showed that the geometry of its atrane framework is similar to that of the Si- and Ge-analogs. The bond lengths are: V=O, 1.614(2) Å; V←N, 2.329(2) Å; V-O, 1.800–1.806(2) Å. The deviation of the V atom having distorted trigonal bipyramidal coordination from the equatorial plane of the O atoms is 0.35 Å, the 0=V←N bond angle is 179.4(1)°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00699945
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