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  • 11
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3609-3611 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: For the binary Ti–Al system, an ordering transformation in Ti3Al has been shown to result in a significant lowering of the electronic heat-capacity coefficient, γ, by removing electrons from conducting states. When γ is normalized to a per Ti atom basis, the same tendency is found in low temperature calorimetric studies of the conducting ternary carbides Ti3Al1.1C1.8, Ti4AlN3, and Ti3SiC2 reported herein. As a consequence of C- or N-induced covalent-like bond formation, the Debye temperatures in these ternaries are in excess of 700 K. © 1999 American Institute of Physics.
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  • 12
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 80 (1958), S. 2132-2141 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 13
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 76 (1954), S. 5136-5140 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 14
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 7205-7215 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The interaction of pulsed laser irradiation of nanosecond duration with a metal surface is studied by numerical simulation. The heat transfer in the solid substrate and the melted liquid is modeled as one-dimensional transient heat conduction using the enthalpy formulation for the solution of phase change problems. A discontinuity layer is assumed just above the liquid surface. Mass, momentum, and energy conservation are expressed across this layer, while the vapor across the discontinuity is modeled as an ideal gas. The compressible gas dynamics is computed numerically by solving the system of Euler equations for mass, momentum, and energy, supplemented with an isentropic equation of state in a two-dimensional axisymmetric system of coordinates. The excimer laser-beam absorption and radiation transport in the vapor phase are modeled using the discrete ordinates method. The rates for ionization are computed using the Saha–Eggert equation assuming conditions of local thermal equilibrium. The inverse bremsstrahlung mechanism is considered as the main mechanism of plasma absorption. Results show that a thin, submicron vapor layer is formed above the target surface in the duration of laser pulse while thermal radiation plays the key role for plume cooling during the period of strong absorption by the plasma. The release of a very strong shock wave, propagating with a speed of 104 m/s, is observed in the evaporating plume. © 1996 American Institute of Physics.
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  • 15
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5435-5435 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Several fine powder samples of ZnxMg1−xFe2O4, 0≤x≤1, were prepared by the supercritical sol-gel (aerogel) process, and were annealed at 500 °C for 2 h. The structure, crystallite size and inversion parameter were determined by x-ray diffraction. The crystallite diameter of the as-prepared powders ranged from 6.5 to 8.5 nm. The minimum size was achieved for the samples with 0.25≤x≤0.50. After annealing the crystallite size increased by an average of 3 nm. The values of the inversion parameters, before and after annealing, reflect roughly the chemical preference of Zn cations to the tetrahedral sites and Mg cations to the octahedral sites of the spinel structure. However, these values indicate that the as-prepared materials were not in the equilibrium state. The magnetic properties were studied by 57Fe Mössbauer spectroscopy over a temperature range of 25 K to room temperature. Taking advantage of their sensitivity to the superparamagnetic behavior induced by the size effects, the Mössbauer spectra were used to determine the blocking temperatures. The calculated values peaked at x=0.50 for both the as-prepared and annealed powders. SQUID magnetometry measurements are currently underway. © 1996 American Institute of Physics.
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  • 16
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 4696-4709 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Pulsed laser irradiation of nanosecond duration is used in a variety of applications, including laser deposition of thin films and micromachining. Of fundamental interest is the prediction of the evaporative material removal rates, as well as the velocity, density, and temperature distributions of the ejected particles as functions of the laser-beam pulse energy, temporal distribution, and irradiance density on the target material surface. In order to address these issues, the present work establishes a new computational approach for the thorough treatment of the heat transfer and fluid flow phenomena in pulsed laser processing of metals. The heat conduction in the solid substrate and the liquid melt is solved by a one-dimensional transient heat transfer model. The ejected high-pressure vapor generates shock waves against the ambient background pressure. The compressible gas dynamics is computed numerically by solving the system of Euler equations for mass, momentum, and energy, supplemented by an isentropic gas equation of state. The aluminum, copper, and gold targets considered were subjected to pulsed ultraviolet excimer laser irradiation of nanosecond duration. Results are given for the temperature distribution, evaporation rate, and melting depth in the target, as well as the pressure, velocity, and temperature distributions in the vapor phase. © 1995 American Institute of Physics.
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  • 17
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5431-5431 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Divalent zinc is commonly used as a replacement cation in ferrites, as it increases the material magnetization when substituted in moderate amounts. However, pure zinc ferrite (ZnFe2O4) is a normal spinel, as zinc has a strong preference for the tetrahedral (A) site in the spinel structure, with Fe occupying the octahedral (B) sites. Then antiferromagnetic B–B coupling dominates the magnetic behavior yielding a material with a Neel temperature near 10 K. It is typically difficult to produce inverted zinc ferrite due to this strong site preference, but recently we produced fine zinc ferrite powders having an inversion parameter of 0.20 using an aerogel process. Ball milling these powders increased the inversion parameter to 0.55, and the median particle size from 14 to 40 nm. To confirm the x-ray diffraction inversion parameters, extended x-ray absorption fine structure (EXAFS) measurements were taken on these powders and ZnFe2O4 standards for both the Fe Kα and Zn Kα absorption edges. Fourier transformed results were fingerprinted against theroretical radial distrubtion functions generated from multiple-scattering FEFF codes for scattering atoms located on the tetrahedral and octahedral sites. Qualitatively, the zinc ferrite standard appears as a normal spinel, while both the iron and zinc radial distributions for the ball milled sample showed large site occupation of both A and B sites. This sample shows superparamagnetic behavior at room temperature, with some ferrimagnetic particles exceeding the critical volume, as indicated by a 15 Oe coercive field. The saturation magnetization of the metastable ball milled powder exceeds 2100 G. © 1996 American Institute of Physics.
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  • 18
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 2591-2593 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Superconducting Bi-Pb-Sr-Ca-Cu-O films doped with Sb have been fabricated on MgO single-crystal substrates without post-annealing, using pulsed excimer laser deposition. Deposition at 800 °C in 0.2 Torr oxygen environment from a target doped with Sb yielded as-deposited superconducting films with zero resistance at 70 K. X-ray diffraction data show the films are c-axis oriented 2212 phase material. Scanning electron micrographs indicate that doping with Sb enhances grain growth. These results demonstrate that Sb acts to stabilize the 2212 phase in the as-deposited films.
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  • 19
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 2426-2428 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Sub-micron homogeneous powders of YBa2Cu4O8 having Tc∼80 K were synthesised from aqueous solutions containing Y, Ba, Cu salts, and oxalic acid as a precipitant via a chemical coprecipitation method using triethylamine as a base. An accelerated formation−within 24 h−of nearly single phase YBa2Cu4O8 powders was achieved. The intragrain critical current density at 5 K and H=1 T was determined to be 3.9×107 A/cm2. This process may have considerable potential in the large-scale preparation of YBa2Cu4O8.
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  • 20
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 1851-1857 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Fine powders of ZnFe2O4 with an average particle size of 10 nm and inversion parameter of 0.21 were synthesized by the aerogel procedure. Portions of the powders were calcined in air at 500 and 800 °C and other portions were ball-milled for 10 h. The materials were characterized by x-ray diffractometry, vibrating sample, and SQUID magnetometry, Mössbauer spectrometry, and low temperature calorimetry. Upon calcination the powders underwent significant changes in grain size, inversion parameter, and hence magnetic properties. The magnetic state of the as-produced and calcined samples is best described as disordered and highly dependent on temperature. Upon ball-milling the grain size varied widely and the inversion parameter attained a value of 0.55. The magnetic properties of the ball-milled sample are similar to those of ferrimagnetic MgFe2O4 powders having comparable grain size and inversion parameters. © 1997 American Institute of Physics.
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