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  • 11
    Publication Date: 2023-02-01
    Description: Geomagnetic excursions represent the dynamic nature of the geodynamo. Accumulated palaeomagnetic records indicate that such excursions are dominated by dipolar-fields, but exhibit different structures. Here we report a palaeomagnetic record from the varved sediments of Lake Suigetsu, central Japan, which reveals fine structures in the Laschamp Excursion and a new post-Laschamp excursion that coincides with the Δ14C maxima. The record’s high-resolution chronology provides IntCal20 mid-ages and varve-counted durations. Both excursions comprise multiple subcentennial directional-swings. Simulations of filtering effects on sediment-magnetisations demonstrate that this high-resolution record replicates most of the features in existing, lower-resolution Laschamp excursion records, including the apparent clockwise open-loop of the virtual geomagnetic pole pass. The virtual geomagnetic poles during the ‘swing’ phases make four clusters centred in hemispherically-symmetric regions, three of which encompass the virtual geomagnetic poles associated with the Laschamp Excursion recorded in lavas at various locations. The stationary dipolar-field sources under each cluster should have intermittently dominated one after another during the excursions.
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 12
    Publication Date: 2024-04-22
    Description: The Campi Flegrei (CF) caldera, in southern Italy, is the source of some of the most powerful Late Pleistocene eruptions of the European sub-continent (e.g., Campanian Ignimbrite, Neapolitan Yellow Tuff eruptions). Although the CF caldera has been continuously and intensively investigated for decades, relatively little is known regarding its earliest volcanic activity. In this work, integrating existing and new tephrostratigraphic data, we provide a comprehensive and updated framework for the CF volcanic activity which has occurred at ∼160 ka and between ∼110 ka and ∼90 ka. The new tephrostratigraphic, geochemical (EMPA + LA-ICP-MS), chronological (40Ar/39Ar dating) and grain-size distribution data relate to CF tephra deposits preserved in mid-proximal (Campanian Plain), distal (Tyrrhenian Sea) and ultra-distal (Lower Danube area) sedimentary archives. Our results allowed us to recognize the presence of at least 13 CF eruptions covering the investigated time frame, with 12 eruptions occurring between 110 and 90 ka. Our high-resolution stratigraphic and chronological investigation also allowed us to recognize that the Triflisco/C-22 tephra, previously considered as a single marker layer, can be actually separated into three different events, sourced from within the CF area in the short time interval of ∼93-90 ka, suggesting a more complex and intense volcanic history than previously thought. Moreover, a Bayesian age-depth model, constrained by previous and new high precision 40Ar/39Ar ages, has led to a reliable estimate of the ages of those undated CF eruptions. Overall, the updated framework on the stratigraphy, chronology, dispersion, and geochemistry of the CF tephra of ∼160 ka and between 110 ka and 90 ka consolidates the notion that the Middle-Late Pleistocene activity in theCF area represents a significant stage of its volcanic evolution, characterised by intense and frequent explosive eruptions.
    Type: info:eu-repo/semantics/article
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  • 13
    Publication Date: 2024-03-21
    Description: Understanding the temporal and spatial environmental response to past climate change during the Last Glacial-Interglacial Transition (LGIT, 16-8 ka) across Europe relies on precise chronologies for palaeoenvironmental records. Tephra layers (volcanic ash) are a powerful chronological tool to synchronise disparate records across the continent. Yet, some regions remain overlooked in terms of cryptotephra investigations. Building on earlier work at the same sites, we present the first complete LGIT high-resolution cryptotephra investigation of two lake records in the Carpathian Mountains in Romania, Lake Brazi and Lake Lia. Numerous volcanic glass shards have been recognised as originating from various volcanic regions, including: Iceland (Katla, Askja, and Torfajokull), Italy (Campi Flegrei, Ischia, Lipari, and Pantelleria), and central Anatolia (Acigol and Ericyes). In total, four distinct tephra horizons have now been identified in these records: 1) an LGIT Lipari tephra (11,515–12,885 cal BP, 95.4% range); 2) Askja-S (11,070–10,720 cal BP, 95.4% range); 3) an Early Holocene Lipari tephra,(12,590–10,845 cal BP, 95.4% range) and; 4) an Early Holocene Ischia tephra (11,120–10,740 cal BP, 95.4% range). The use of trace element analysis on selected cryptotephra layers provided additional important information in identifying volcanic source and facilitating correlations. These tephra layers, along with numerous other discrete cryptotephra layers, offer promise as significant future isochrons for comprehending the spatial and temporal fluctuations in past climate change throughout Europe and the Mediterranean area. This research has emphasized the significance of the Carpathian region in expanding the European and Mediterranean tephra lattice and establishing it as a keystone area within the framework.
    Type: info:eu-repo/semantics/article
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  • 14
    Publication Date: 2021-03-17
    Description: The effect of stoichiometry on the new formation and subsequent growth of CaCO3 was investigated over a large range of solution stoichiometries (10–4 〈 raq 〈 104, where raq = {Ca2+}:{CO32–}) at various, initially constant degrees of supersaturation (30 〈 Ωcal 〈 200, where Ωcal = {Ca2+}{CO32–}/Ksp), pH of 10.5 ± 0.27, and ambient temperature and pressure. At raq = 1 and Ωcal 〈 150, dynamic light scattering (DLS) showed that ion adsorption onto nuclei (1–10 nm) was the dominant mechanism. At higher supersaturation levels, no continuum of particle sizes is observed with time, suggesting aggregation of prenucleation clusters into larger particles as the dominant growth mechanism. At raq ≠ 1 (Ωcal = 100), prenucleation particles remained smaller than 10 nm for up to 15 h. Cross-polarized light in optical light microscopy was used to measure the time needed for new particle formation and growth to at least 20 μm. This precipitation time depends strongly and asymmetrically on raq. Complementary molecular dynamics (MD) simulations confirm that raq affects CaCO3 nanoparticle formation substantially. At raq = 1 and Ωcal ≫ 1000, the largest nanoparticle in the system had a 21–68% larger gyration radius after 20 ns of simulation time than in nonstoichiometric systems. Our results imply that, besides Ωcal, stoichiometry affects particle size, persistence, growth time, and ripening time toward micrometer-sized crystals. Our results may help us to improve the understanding, prediction, and formation of CaCO3 in geological, industrial, and geo-engineering settings.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 15
    Publication Date: 2021-12-15
    Description: The 40 ka caldera-forming eruption of Campi Flegrei (Italy) is the largest known erup- tion in Europe during the last 200 k.y., but little is known about other large eruptions at the volcano prior to a more recent caldera-forming event at 15 ka. At 29 ka a widespread volcanic ash layer, termed the Y-3 tephra, covered 〉150,000 km2 of the Mediterranean. The glass compositions of the layer are consistent with Campi Flegrei being the source, but no prominent proximal equivalent in the appropriate chrono-stratigraphic position had been previously identified. Here we report new glass chemistry data and 40Ar/39Ar ages (29.3 ± 0.7 ka [2σ]) that reveal the near-source Y-3 eruption deposit in a sequence at Ponti Rossi and a nearby borehole (S-19) in Naples. The dispersal and thickness of the deposits associ- ated with this eruption, herein named the Masseria del Monte Tuff, were simulated using a tephra sedimentation model. The model indicates that ~16 km3 dense rock equivalent of the magma erupted was deposited as fall. This volume and the areal distribution suggest that the Masseria del Monte Tuff resulted from a magnitude (M) 6.6 eruption (corresponding to volcanic explosivity index [VEI] 6), similar to the 15 ka caldera-forming Neapolitan Yellow Tuff (M 6.8) eruption at Campi Flegrei. However, the lack of coarse, thick, traceable, near- vent deposit suggests peculiar eruption dynamics. Our reconstruction and modeling of the eruption show the fundamental role that distal tephrostratigraphy can play in constraining the scale and tempo of past activity, especially at highly productive volcanoes.
    Description: Published
    Description: 595-599
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 16
    Publication Date: 2021-12-06
    Description: The increasing application of cryptotephra studies is leading the identification of new tephra marker layers the sources of which in many cases may not be known or may be ambiguous. In this contribution, we discuss the controls on tephra geochemistry in the context of establishing the provenance of an unknown tephra layer. We use the RESET database (https://c14.arch.ox.ac.uk), which contains major and trace element data for a number of European silicic tephra erupted in the period 100 ka to ca 10 ka, to define new and modify existing tectonic setting discrimination diagrams for use with volcanic glass analyses. Bivariate plots of the elements Rb, Nb, Ta, Y and Th and K2O, SiO2, FeO and MgO can be used to identify tephra from different tectonic settings. New, detailed glass chemistry shows that tephra from the productive Neapolitan volcanic centres, Somma-Vesuvius (22e4 ka activity), Campi Flegrei (60e15 ka) and Ischia (75e20 ka), can be separated using major elements, CaOeSiO2, Na2O/K2OeCaO and CaOeMgO. In each of these centres, the tephrostratigraphic record is characterized by the repeated occurrence of similar glass compositions, punctuated by significant changes in magma chemistry. The glass compositions of successive eruptions from Campi Flegrei are similar but there is a significant change in the composition following the Campanian Ignimbrite, and there are comparable compositional changes at Ischia following the Monte Epomeo Green Tuff eruption and at Somma-Vesuvius following the Verdoline event. Distinguishing different tephras from a single volcanic centre is more problematic, and in some instances even impossible, without good chronological and stratigraphic control and/or high-resolution trace element glass data. At Somma-Vesuvius certain major elements can be used to separate glasses from the major chronological phases (Group 1 e Pomici di Base and Verdoline; Group 2 e Mercato and Avellino), but separating tephras within a single group on the basis of glass composition can be problematic.
    Description: Published
    Description: 48-66
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Tephrochronology ; Major and trace element ; Discrimination diagrams ; Somma-Vesuvius
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 17
    Publication Date: 2021-12-06
    Description: Major, minor and trace element analysis of volcanic glass in proximal and distal (〈 2 mm) tephra deposits underpins tephrochronology. This approach has been tested in the Aeolian Islands and the Tyrrhenian Sea using juvenile clasts in pyroclastic fall and flow deposits. Geochemical data are used to link marine tephras in the Marsili Basin (core TIR2000-C01) to explosive eruptions of (1) Lipari (Monte Pilato; 776 cal AD); (2) Vulcano; and (3) Campi Flegrei (Soccavo 1; 11,915–12,721 cal years BP). Whether a polymictic coarse grained volcaniclastic turbidite in the Marsili Basin originated from collapse on Salina remains unresolved because multi-elemental analysis raises doubt about the published correlation to the Pollara region. It is evident that correlation of proximal continental and distal marine tephras, at a high level of confidence, requires a full complement of major, minor and trace element data. In conjunction with considerations of the mineralogy and morphology of juvenile deposits these data help define petrological lineages such that precise provenance can be established. Whilst a precise proximal–distal match must be based on identical major, minor and trace element concentrations it is clear that resurgent activity from a single volcano can produce magmas with identical compositions. In such cases stratigraphic relationships must complement any geochemical study. Occasionally proximal stratigraphies may be unrepresentative of the complete eruptive history because of a lack of exposure due to burial by more recent effusive and explosive activity, or sector collapse which can remove vital stratigraphy particularly on volcanic islands.
    Description: Published
    Description: 74-94
    Description: JCR Journal
    Description: restricted
    Keywords: Marsili Basin ; Glass chemistry ; Tephra ; Trace element ; Aeolian Islands ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 18
    Publication Date: 2021-12-06
    Description: Marked changes in human dispersal and development during the Middle to Upper Paleolithic transition have been attributed to massive volcanic eruption and/or severe climatic deterioration. We test this concept using records of volcanic ash layers of the Campanian Ignimbrite eruption dated to ca. 40,000 y ago (40 ka B.P.). The distribution of the Campanian Ignimbrite has been enhanced by the discovery of cryptotephra deposits (volcanic ash layers that are not visible to the naked eye) in archaeological cave sequences. They enable us to synchronize archaeological and paleoclimatic records through the period of transition from Neanderthal to the earliest anatomically modern human populations in Europe. Our results con!rm that the combined effects of a major volcanic eruption and severe climatic cooling failed to have lasting impacts on Neanderthals or early modern humans in Europe. We infer that modern humans proved a greater competitive threat to indigenous populations than natural disasters.
    Description: funded by the United Kingdom Natural Environment Research Council through a Response of Humans to Abrupt Environmental Transitions (RESET) Consortium Grant
    Description: Published
    Description: 13532–13537
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Neanderthals ; modern humans ; cryptotephra deposits ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 19
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 17 (1913), S. 154-161 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 17 (1913), S. 252-263 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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