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Polysilane spherulites and their high photoluminescence quantum yields (1997)

Majima, Yutaka ; Kawata, Yasushi ; Nakano, Yoshihiko ; [et al.]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 427-430

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ISSN: 0887-624X

Keywords: polysilane ; spherulite ; photoluminescence ; quantum yield ; Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Large polysilane spherulites have been observed. The spherulites were prepared by controlling the removal rate of solvents from poly(n-butyl-n-pentylsilane) under a xylene atmosphere. The diameter of the spherulites was greater than 0.1 mm. The structure of the spherulites was compared with that of the polysilane powder by polarized microscopy, SEM, DSC, and x-ray diffractometry. A high photoluminescence quantum yield of 0.3 was obtained for the spherulites. © 1997 John Wiley & Sons, Inc.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

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