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Iron-chromium-molybdenum oxide catalysts for methanol oxidation (1993)

Klissurski, D. ; Rives, V. ; Pesheva, Y. ; [et al.]

Springer

Catalysis letters 18 (1993), S. 265-271

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ISSN: 1572-879X

Keywords: Methanol oxidation ; iron-chromium-molybdenum oxide catalysts ; formaldehyde synthesis ; partial oxidation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The activity and selectivity of a precipitated iron-chromium-molybdenum oxide catalyst (Mo/(Fe + Cr) = 2.5/(0.5 + 0.5)) towards methanol mild oxidation have been studied by a flow-circulation method. Commensurable activity and selectivity with those of the industrial Fe2 (MoO4)3-MoO3 catalysts as well as an enhanced stability have been found. The Mössbauer spectra of fresh and tested catalysts show that during the catalytic reaction a partial reduction occurs and a steady state composition differing from the initial one is formed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00769446

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