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Iron-chromium-molybdenum oxide catalysts for methanol oxidation

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Abstract

The activity and selectivity of a precipitated iron-chromium-molybdenum oxide catalyst (Mo/(Fe + Cr) = 2.5/(0.5 + 0.5)) towards methanol mild oxidation have been studied by a flow-circulation method. Commensurable activity and selectivity with those of the industrial Fe2 (MoO4)3-MoO3 catalysts as well as an enhanced stability have been found. The Mössbauer spectra of fresh and tested catalysts show that during the catalytic reaction a partial reduction occurs and a steady state composition differing from the initial one is formed.

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References

  1. P. Jiru, B. Wichterlowa and J. Tichy,Proc. 3rd Int. Congr. on Catalysis (Elsevier, Amsterdam, 1964) p. 199.

    Google Scholar 

  2. M. Dente, R. Poppi and I. Pasquon, Chim. Ind. (Milan) 46 (1964) 1326.

    Google Scholar 

  3. G.K. Boreskov, G.D. Kolovertnov, L.M. Kefeli, L.M. Plyasova, L.G. Karakchiev, V.N. Mastikchin, B.I. Popov, V. A. Dzis'ko and D.V. Tarasova, Kinet. Katal. 7 (1966) 144.

    Google Scholar 

  4. M. del Arco, C. Martin, V. Rives, A.M. Estevez, M.C. Marquez and A.F. Tena, Mater. Chem. Phys. 23 (1989) 517.

    Google Scholar 

  5. A.M. Estevez, M.C. Marquez, A.F. Tena, M. del Arco, C. Martin and V. Rives, Chem. Biochem. Eng. Q. 4 (1990) 61.

    Google Scholar 

  6. T.S. Popov, B.I. Popov, V.N. Bibin, G.M. Bliznakov and G.K. Boreskov, React. Kinet. Catal. Lett. 3 (1975) 169.

    Google Scholar 

  7. B.I. Popov, L.L. Sedova, G.N. Kustova, L.M. Plyasova, Yu.V. Maksimov and A.I. Matweev, React. Kinet. Catal. Lett. 5 (1976) 43.

    Google Scholar 

  8. G.M. Bliznakov, D. Klissurski, K. Cheshkova and V. Savova, Chim. Ind. (Bulgaria) 4 (1979) 157.

    Google Scholar 

  9. D. Klissurski, I. Mitov, K. Cheshkova, S. Angelov, K. Petrov and S. Georgiev, Kinet. Katal. 30 (1989) 403.

    Google Scholar 

  10. Bulgarian Patent N 45524.

  11. M. del Arco, C. Martin, V. Rives, A.M. Estevez, A.F. Tena and M.C. Marquez, J. Mater. Sci. 24(1989) 3750.

    Google Scholar 

  12. J.E. Huheey, Inorganic Chemistry, Principles of Structure and Reactivity, 3rd Ed. (Harper, Cambridge, 1983).

    Google Scholar 

  13. G.M. Bliznakov, M. Marinov, D. Klissurski, V. Kozhukharov and J. Pesheva, Chem. Commun. (Bulg. Acad. Sci.) 15 (1982) 261.

    Google Scholar 

  14. V.N. Bibin and B.I. Popov, Kinet. Katal. 9 (1968) 618.

    Google Scholar 

  15. V.N. Bibin and B.I. Popov, Kinet. Katal. 10 (1969) 1326.

    Google Scholar 

  16. N.H. Rapposchi, J.B. Anderson and E. Kostiner, Inorg. Chem. 19 (1980) 3531.

    Google Scholar 

  17. Yu. V. Maksimov, I.P. Suzdalev, V.I. Gol'danskii, A.I. Matweev, E.F. Makarov and L.Ya. Margolis, Compt. Rend. Acad. Sci. USSR 225 (1975) 133.

    Google Scholar 

  18. Yu. V. Maksimov, I.P. Suzdalev, V.I. Gol'danskii, O.V. Krilov, L.Ya. Margolis and A.E. Nechitailo, Compt. Rend. Acad. Sci. USSR 221 (1975) 880.

    Google Scholar 

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

    D. Klissurski, V. Rives, Y. Pesheva, I. Mitov & N. Abadzhjieva

  2. Departamento de Química Inorgánica, Universidad de Salamanca, Facultad de Farmacia, Salamanca, E-37007, Salamanca, Spain

    V. Rives

  3. Institute of Kinetics and Catalysis, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

    I. Mitov

Authors
  1. D. Klissurski
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  2. V. Rives
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  3. Y. Pesheva
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  4. I. Mitov
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  5. N. Abadzhjieva
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Klissurski, D., Rives, V., Pesheva, Y. et al. Iron-chromium-molybdenum oxide catalysts for methanol oxidation. Catal Lett 18, 265–271 (1993). https://doi.org/10.1007/BF00769446

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  • DOI: https://doi.org/10.1007/BF00769446

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