ISSN:
0044-2313
Keywords:
Metallocene dichlorides, bridged cyclopentadienyl and indenyl compounds
;
crystal structure
;
1H
;
13C
;
29Si n.m.r., and MS spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Tetramethyldisilane-1,2-diyl bridged Dicyclopentadienyl and Diindenyl Metal Dichlorides of the Group 4 Metals - Crystal Structure of Dicyclopentadienyl and diindenyl metal dichlorides of the type Cp′—SiMe2SiMe2—Cp′MCl2 (Cp′ = C5H4, M = Ti (1), Zr (2), Hf (3); Cp′ = C9H7, M = Zr (4), Hf (5)) were synthesized and characterized by means of their 1H, 13C, 29Si-n.m.r., MS, and IR spectra. The crystal structure of 2 was determined.
Notes:
Dicyclopentadienyl- und Diindenylmetalldichloride des Typs Cp′—Me2Si—Me2Si—Cp′MCl2(Cp′ = C5H4; M = Ti(1), Zr (2), Hf (3); Cp′ = C9H7; M = Zr (4), Hf (5)) wurden synthetisiert und mittels ihrer 1H-, 13C- und 29Si-NMR-Spektren sowie MS- und IR-Spektren charakterisiert. Die Kristallstruktur von 2 wurde ermittelt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19966221028
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