ISSN:
0044-2313
Keywords:
Tetramethyltitanium tetrahydrofuran
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Transition Metal Alkyl Compounds. 63. Preparation and Crystal Structure of Tetramethyltitanium TetrahydrofuranMe4Ti · 2THF 1 dissoziates partially in n-pentane. The formed Me4Ti · THF 2 could be isolated. According to X-ray structure determination the molecules of 2 have a trigonalbipyramidal shape with the THF molecule in axial position.
Notes:
Me4Ti · 2THF 1 unterliegt in n-Pentan einer partiellen Dissoziation. Das dabei entstehende Me4Ti · THF 2 konnte isoliert und die Kristallstruktur ermittelt werden. Danach liegen die Moleküle von 2 im Kristall in trigonal-bipyramidaler Form vor, mit dem THF-Molekül in axialer Position.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210526
