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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 618 (1992), S. 107-110 
    ISSN: 0044-2313
    Keywords: Sodium ; Barium ; Copper Oxovanadates ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Na2BaCuV2O8: A New Structure Type of the Alkaline-Alkaline Earth Copper OxovanadatesSingle crystals of Na2BaCuV2O8 were prepared by a high temperature flux. It crystallizes with monoclinic symmetry space group C2h6-C2/c, a = 9.4329 Å, b = 5.6858 Å, c = 14.0488 Å, β = 92.344° Z = 4 and represents a new structure type. The crystal structure show VO4 tetrahedra, stretched CuO6 octahedra, trigonal bipyramids around Na+ and a BaO10+2 polyedron.
    Notes: Einkristalle von Na2BaCuV2O8 wurden bei relativ hohen Temperaturen aus einer Schmelze erhalten. Die bisher unbekannte Verbindung repräsentiert einen neuen Strukturtyp. Na2BaCuV2O8 kristallisiert monoklin in der Raumgruppe C2h6-C2/c mit a = 9,4329 Å, b = 5,6858 Å, c = 14,0488 Å, β = 92,344°, Z = 4. Die Kristallstruktur zeigt VO4-Tetraeder, gestreckte CuO6-Oktaeder, trigonale Bipyramiden um Na+ und ein BaO10+2-Polyeder.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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