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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 9 (1958), S. 755-760 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Protection against Corrosion by sprayed Zinc and Aluminium CoatingsUsed since 1922, metal spraying now has wide applications especially in the protection of steels against corrosion. Low-melting metals such as zinc and aluminium are mainly used. Both these metals may be applied by the powder as well as by the wire method. The physical properties of coatings produced by these two methods are different. Considering hitherto gained experience, the properties of the sprayed zinc and aluminium coatings are discussed in detail. The result is that sprayed coatings of aluminium and zinc afford effective protection of mild steel in water and in air. Besides giving cathodic protection, a protective effect may be obtained by blocking the pores of the metal coating by the corrosion products. In the case of aluminium the absorbing, amphothere hydroxide film on the metal surface may be involved in chemical reactions. In selecting the protective metal one must consider that sprayed aluminium is much more reactive than massive aluminium while there is no difference with zinc.
    Notes: Das seit etwa 1922 praktisch angewandte Metallspritzen finden zur Zeit eine vielseitige Verwendung, insbesondere zum Korrosionsschutz von Stahl, wobei vorwiegend die niedrigschmelzenden Metalle Zink und Aluminium als Spritzmetalle verwendet werden. Beide Metalle lassen sich sowohl im Pulver-, als auch im Drahtverfahren verarbeiten, doch sind die so erzielten Überzüge in ihren physikalischen Merkmalen deutlich verschieden. Unter Berücksichtigung der bisherigen Erfahrungen werden die Eigenschaflen der aufgespritzten Zink- und Aluminiumüberzüge eingehend behandelt. Zusammenfassend wird hierbei festgestellt, daß unter geeigneten Bedingungen Zink- und Aluminium-Spritz-Überzüge unter Wasser und in der Atmosphäre einen wirksamen Schutz für Weichstahl bieten. Für deren Schutzwirkung dürfte neben einem kathodischen Schutz des Grundmetalls vorwiegend die Blockierung der Poren im Metallüberzug durch Korrosionsprodukte maßgebend sein. Bei Aluminium dürfte auch der absorbierende amphotere Hydroxydfilm auf dem Metall an chemischen Reaktionen teilnehmen. Bei der Wahl des Schutzmetalls bleibt zu berücksichtigen, daß gespritztes Aluminium reaktionsfähiger ist als massives Aluminium, während sich gespritztes Zink wie massives Zink verhält.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 27 (1989), S. 1419-1424 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 395-409 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A process has been developed by which very high-modulus semicrystalline polymer films can be extruded continuously from a melt. This is accomplished by controlled cooling of the melt in a two-stage flow channel. A temperature gradient along the flow channel quenches the melt prior to an area reduction in which the polymer undergoes solid-state orientation. Analysis of high-density polyethylene tapes extruded by this process shows that they have properties similar to samples hydrostatically extruded at 120°C. Infrared analysis was used to determine both the degree of crystallinity and degree of orientation in these tapes as well as previously prepared hydrostatically extruded samples.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 4 (1982), S. 18-22 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Inelastic electron tunnelling spectroscopy has been applied to the study of sodium dodecanoate (laurate) adsorption, from aqueous solution, upon an aluminium oxide surface. Al—Al2O3—Pb tunnel junctions, whose oxides have been exposed to aqueous solutions of sodium dodecanoate are found to exhibit a maximum in resistance with increasing solution concentration. Spectral quality is dependent upon solution concentration, and optimum spectra are only obtained when junction resistance is near this maximum. The resistance maximum and decline in spectral quality with increasing solution concentration, are explained in terms of surfactant aggregation at a critical concentration. An optimum IET spectrum of sodium dodecanoate is presented and compared with the bulk infra-red and Raman spectra of aluminium dodecanoate. A chemisorption mechanism is proposed. Other surfactants have also been investigated. These were sodium octadecanoate (stearate), sodium dodecyl sulphate and sodium hexadecyl sulphate. Problems specific to the application of inelastic electron tunnelling spectroscopy to these surfactants are reported.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 179-179 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 5 (1950), S. 169-178 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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