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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 445-448 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Asymmetrically substituted, liquid-crystalline phthalocyanines were synthesized. They contain one methoxy, six dodecyloxy and one acryloyloxy- or methacryloyloxydodecyloxy groups. The latter functions were polymerized under free radical conditions to give polymers with molecular weights between 9000 and 47000. The aggregation behaviour of the phthalocyanines in the polymer side chains was studied in solution by absorption and fluorescence spectroscopy. An enhanced intramolecular interaction between the phthalocyanines was observed. In the solid state this interaction is reflected in the spontaneous formation of a columnar structure. The polymers, however, do not display liquid-crystalline behaviour. Temperature-dependent luminescence measurements (at 4,2 - 300 K) were performed and the results are explained by the presence of an efficient energy migration process through the stacked phthalocyanine units.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations to Determine and Evaluate Damage Processes of Adhesive Bonds by Means of Acoustic EmissionThe damage process in metal adhesive bonds under quasistatic loads was monitored by means of acoustic emission analysis (AEA). Metallographic investigations allow the correlation between acoustic emission data and microscopic failure processes in the bondline of single lap adhesive joints. The influence of specimen geometry on the initiation of damages is discussed for several types of adhesives. Furthermore the relation between the preparation of the adherent surface and the onset of acoustic emission is as well described as the influence of manufacturing defects on the mechanical behaviour and the acoustic emission activity.
    Notes: Der Schädigungsablauf an einschnittig überlappten Klebverbindungen wurde mit Hilfe der Schallemissionsanalyse bei quasistatischer Belastung untersucht. An verschiedenen Klebstoffsystemen wird der Einfluß der Fügeteilgeometrie auf die Festigkeit und die Initiierung von Schäden in der Klebschicht dargestellt. Licht- und rasterelektronen-mikroskopische Gefügeuntersuchungen ermöglichen die Zuordnung der Schallemissionssignale zu den mikroskopischen Schädigungsvorgängen in der Klebschicht. Weiterhin wird der Zusammenhang zwischen der Fügeteilvorbehandlung und dem Beginn der Schädigungsausbildung sowie der Einfluß von Fertigungsfehlern auf die mechanisch-technologischen Eigenschaften von Metallklebungen diskutiert und Belastungsgrenzen aufgezeigt.
    Additional Material: 22 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 16 (1985), S. 366-372 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Acoustic Emission Investigations on Failure Mechanisms in Carbon Fibre Reinforced PlasticsFor a reliable application of modern high-strength materials such as carbon fibre reinforced plastics the knowledges of failure mechanisms as well as detailed informations about the influence of defects occuring during the manufacturing process are necessary. To study the damage progression in fibrous composites a non destructive manner, a very sensitive test failure processes in the laminate have only microscopic dimensions.In our investigations the damage progression was studied by means of acoustic emission analysis (AEA) for different types of ply orientated containing several artifical defects, as cut-through fibres, disbonded fibres and porous matrix. In a further step internally pressurized tubes were tested to investigate the applicability of AE-results to real components. Additionally, fractographic investigations improve the interpretation of the acoustic emission data.It is shown, that AEA succeeds in monitoring damages already at a very early state of damage. At increasing loads the different types of defect emit characteristic AE, which is correlated with a void-type dependent damage progression in the laminate. These knowledges of the failure mechanisms and their typical acoustic emission allow a classification of the different types of manufacturing defects concerning their influence. So, especially the porous matrix could be shown to be the most significant failure type as it causes the largest decrease of strength. The onset of AE at porous materials, however, was found at very low load levels, so that this type of defect can be detected properly.
    Notes: Die Entwicklung moderner technischer Bauteile und Bauteilkomponenten erfordert den Einsatz hochbeanspruchbarer Leichtbauwerkstoffe, die zunehmend aus kohlenstoffaserverstärkten Epoxidharzen hergestellt werden. Der zuverlässige Einsatz derartiger Werkstoffe setzt neben der Kenntnis des Versagensablaufes auch die Prüfbarkeit der Verbunde auf Fertigungsfehler und Schädigungen infolge Betriebsbeanspruchung voraus. Die Zuverlässigkeit von Faserverbunden ist daher entscheidend von der Qualitätssicherung in der Fertigung und im späteren Betrieb abhängig. Dabei ist nicht das Auffinden jeglicher Fehlstellen von Bedeutung, sondern lediglich solcher Ungänzen, durch die die Einsatzfähigkeit des Bauteils in Frage gestellt wird. Als geeignetes Prüfverfahren hierzu hat sich die Schallemissionsanalyse (SEA) erwiesen, da sich mit ihrer Hilfe bereits in einem frühen Stadium Werkstoffveränderungen nachweisen und interpretieren lassen.Es wurde der Einfluß von fertigungsbedingten Fehlern auf den Versagensablauf und die mechanisch-technologischen Eigenschaften von CFK-Laminaten untersucht. Bei den Fehlern handelt es sich um quasinatürliche Fehler (durchtrennte Faserlage, poröse Matrix, sowie fehlende Haftung der Fasern).Der Einfluß dieser Fehler auf den Beginn und Ablauf der Schädigungen wurde mit Hilfe der SEA abhängig vom Laminataufbau (0, ± 45, 90°) beobachtet. Durch Schliffbilduntersuchungen sowie mit „InSitu“ Belastungen im REM wird die Zuordnung zwischen den Schallemissionsanalysen und den Schädigungen des Laminates ermöglicht. In einem weiteren Schritt wird die Übertragbarkeit der an Laborproben gewonnenen Erkenntnisse auf innendruckbelastete Rohre überprüft.
    Additional Material: 15 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 30 (1990), S. 1289-1290 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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