ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Molecular core binding energies have been measured by ESCA for series of surface-fluorinated high-density polyethylene films. Detailed analysis of the results shows that the technique can be used to establish a comprehensive picture of the early stages of the surface fluorination process. Both the depth of fluorination, and stoichiometry and molecular structure as a function of depth, in the range 0-50 Å have been established. In addition, minor features such as oxidation, hydration, and hydrocarbon contamination at the surface are clearly revealed. Detailed consideration of the results allows a discussion of the dynamics of the overall fluorination process.
Additional Material:
15 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1975.170130408
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