ISSN:
0021-8383
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The proportion of difunctional and monofunctional products with the original carbon skeleton was determined in the oxidates of n-decane, n-tridecane, n-pentadecane, and n-octadecane to about 0.32. This proportion does not significantly depend on the conversion of the starting paraffin. As well as mono- and difunctional products with the original carbon skeleton already at very low conversions of n-tridecane, about 45% of lower oxygen-containing compounds, for example aldehydes, alkan-2-ones, carboxylic acids and γ-lactones, are also obtained. Obviously, a part of the difunctional primary products reacts very fast with scission of the carbon chain, forming lower oxygen-containing compounds.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/prac.19873290402
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