ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • INORGANIC AND PHYSICAL CHEMISTRY  (3)
  • Life and Medical Sciences  (2)
  • Polymer and Materials Science  (2)
  • 1
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Enzyme-purified elastin from bovine ligamentum nuchae was digested with elastase in the presence of sodium dodecyl sulfate. Chromatographic fractionation of the digest, after removal of the detergent, resulted in the high-yield isolation of two peptide fractions (F2 and F3) that differed in size and composition. The larger, F2, which accounted for about 55% of the starting material, was subjected to sedimentation-equilibrium analysis in three chaotropic solvents. Comparison of the distribution of point-average molecular weights (Mw and Mz) with protein concentration in the three systems lead to the conclusion that significant self-association of peptides occurred in the absence of 6M guanidinium hydrochloride. In this solvent, the molecular-weight distribution was between 25,000 and 34,000, a range of values in agreement with an intrinisic viscosity of 13.1 cc g-1 determined in the same solvent. Assessment of chain weight by N- and C-terminal analysis was consistent with F2 being a multichain molecule comprising four polypeptide chains linked by three polyfunctional amino acids. Results are interpreted in terms of an anisotropic ultrastructural model of the protein, in which four polypeptide chains constitute the primary filament visualized by electron microscopy in the intact fiber.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 9 (1971), S. 531-541 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Dilatometric and calorimetric studies have been made of the fusion process of linear polyethylene crystallized by stirring xylene solutions at elevated temperatures. It is shown that the melting point of the crystals increases rapidly from 139.5°C to 145°C in the crystallization temperature range of 100-103°C and levels off to 146 ± 0.5°C, provided that very slow heating rates are employed. Stirrer-crystallized samples treated with fuming nitric acid show higher crystalline contents. Comparison of their enthalpies of fusion and melting points indicate that higher molecular order along the fiber axis is associated with higher crystallization temperatures. This is in general agreement with corresponding results of other modes of crystallization. The attack of fuming nitric acid on stirrer crystals is characterized by weight-loss curves similar to those of dilutesolution crystals and bulk polyethylene. The linear molecular weight dependence on time of exposure to nitric acid suggests that the oxidation proceeds mainly from the chain ends at a constant rate for samples stirred in the lower crystallization range, but an increased rate is observed for a sample stirred from xylene at 105°C. It is suggested that the lamellar overgrowths, most evident at low crystallization temperatures, are epitaxially attached to the fiber axis, whereas the smaller crossbandings observed at higher crystallization temperatures are possibly made up of elements of chains that are only partly incorporated in the highly ordered fibrous core.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Molecular Reproduction and Development 33 (1992), S. 210-214 
    ISSN: 1040-452X
    Keywords: Oocytes cryopreservation ; Vitrification ; Mouse ; Minimal cryoprotectant exposure ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: The effects on oocyte viability of varying the duration of exposure to cryoprotectants before rapid cooling to - 196°C were examined, using the vitrification protocol of Nakagata. A very short exposure (15 sec) was found to be optimal, resulting in an overall rate of development from vitrified oocytes to hatching blastocysts of 31.8%. Very high rates of survival (77-89%) of oocytes exposed to the cryoprotectant media, but without the vitrification, together with extreme variability in results between straws in the vitrified groups, suggest that losses in viability during vitrification may result from ice damage during devitrification of the medium. (c) 1992 Wiley-Liss, Inc.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 150 (1992), S. 175-179 
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Membrane water permeability values were measured in individual fresh human pre-ovulatory oocytes using real time microscopy in a microscope diffusion chamber. The cells were exposed to anisosmotic conditions, their volume responses measured, and from these data the Lp values were computed employing the Kedem-Katchalsky analyses of irreversible thermodynamics. Lp values were measured at four temperatures for each oocyte between 37°C and 10°C, and the temperature-related Arrhenius activation energy (Ea) calculated. It was apparent that individual oocytes exhibited a wide range of Lp values; at 37°C Lp values ranged between 0.33 and 1.80 μm/atm/min. However, each oocyte exhibited the expected inverse linear correlation between Lp and temperature, with high linear correlations (R2 values between 0.73 and 0.96). A mean value for Ea of 8.61 ± 5.11 Kcal/mol was computed. It is apparent that pre-ovulatory human oocytes express a range of biological diversity in terms of membrane water transport, and this fact needs to be considered when attempting to formulate cryopreservation protocols for storage of these oocytes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2014-09-25
    Description: Elemental analyses of impactor residues on high purity surface exposed to the low earth orbit (LEO) environment for 5.8 years on Long Duration Exposure Facility (LDEF) has revealed several probable sources for microparticles at this altitude, including natural micrometeorites and manmade debris ranging from paint pigments to bits of stainless steel. A myriad of contamination interferences were identified and their effects on impactor debris identification mitigated during the course of this study. These interferences included pre-, post-, and in-flight deposited particulate surface contaminants, as well as indigenous heterogeneous material contaminants. Non-flight contaminants traced to human origins, including spittle and skin oils, contributed significant levels of alkali-rich carbonaceous interferences. A ubiquitous layer of in-flight deposited silicaceous contamination varied in thickness with location on LDEF and proximity to active electrical fields. In-flight deposited (low velocity) contaminants included urine droplets and bits of metal film from eroded thermal blankets.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: North Carolina State Univ., Analysis of Interplanetary Dust Experiment Detectors and Other Witness Plates; 11 p
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2014-09-25
    Description: The Interplanetary Dust Experiment (IDE) had over 450 electrically active ultra-high purity metal-oxide-silicon impact detectors located on the six primary sides of the Long Duration Exposure Facility (LDEF). Hypervelocity microparticles (approximately 0.2 to approximately 100 micron diameter) that struck the active sensors with enough energy to breakdown the 0.4 or 1.0 micron thick SiO2 insulator layer separating the silicon base (the negative electrode), and the 1000 A thick surface layer of aluminum (the positive electrode) caused electrical discharges that were recorded for the first year of orbit. The high purity Al-SiO2-Si substrates allowed detection of trace (ppm) amounts of hypervelocity impactor residues. After sputtering through a layer of surface contamination, secondary ion mass spectrometry (SIMS) was used to create two-dimensional elemental ion intensity maps of microparticle sites on the IDE sensors. The element intensities in the central craters of the impacts were corrected for relative ion yields and instrumental conditions and then normalized to silicon. The results classification resulted from the particles' origins as 'manmade', 'natural', or 'indeterminate'. The last classification resulted from the presence of too little impactor residue, analytical interference from high background contamination, the lack of information on silicon and aluminum residues, or a combination of these circumstances. Several analytical 'blank' discharges were induced on flight sensors by pressing down on the sensor surface with a pure silicon shard. Analyses of these blank discharges showed that the discharge energy blasts away the layer of surface contamination. Only Si and Al were detected inside the discharge zones, including the central craters, of these features. Thus far, a total of 79 randomly selected microparticle impact sites from the six primary sides of the LDEF were analyzed: 36 from tray C-9 (Leading (ram), or east, side), 18 from tray C-3 (Trailing (wake), or west, side), 12 from tray B-12 (north side), 4 from tray D-6 (south side), 3 from tray H-11 (space end), and 6 from tray G-10 (earth end). Residue from manmade debris was identified in craters on all trays (aluminum oxide particle residues were not detectable on the Al/Si substrates). These results were consistent with the IDE impact record which showed highly variable long term microparticle impact flux rates on the west, space, and Earth sides of the LDEF which could not be ascribed to astronomical variability of micrometeorite density. The IDE record also showed episodic bursts of microparticle impacts on the east, north, and south sides of the satellite, denoting passage through orbital debris clouds or rings.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: North Carolina State Univ., Analysis of Interplanetary Dust Experiment Detectors and Other Witness Plates; 15 p
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2019-06-28
    Description: Two dimensional elemental ion maps have been recorded for hundreds of microparticle impact sites and contamination features on LDEF surfaces. Since the majority of the analyzed surfaces were metal-oxide-silicon (MOS) impact detectors from the Interplanetary Dust Experiment, a series of 'standard' and 'blank' analyses of these surfaces are included. Hypervelocity impacts of forsterite olivine microparticles on activated flight sensors served as standards while stylus and pulsed laser simulated 'impacts' served as analytical blanks. Results showed that despite serious contamination issues, impactor residues can be identified in greater than 1/3 of the impact sites. While aluminum oxide particles could not be detected on aluminum surfaces, they were detected on germanium surfaces from row 12. Remnants of manmade debris impactors consisting of paint chips and bits of metal were identified on surfaces from LDEF Rows 3 (west or trailing side), 6 (south), 9 (ram or leading side), 12 (north) and the space end. Higher than expected ratios of manmade microparticle impacts to total microparticle impacts were found on the space end and the trailing side. These results were consistent with time-tagged and time-segregated microparticle impact data from the IDE and other LDEF experiments. A myriad of contamination interferences were identified and their effects on impactor debris identification mitigated during the course of this study. These interferences include pre-, post and inflight deposited surface contaminants as well as indigenous heterogeneous material contaminants. Non-flight contaminations traced to human origins, including spittle and skin oils, contributed significant levels of alkali-rich carbonaceous interferences. A ubiquitous layer of in-flight deposited silicaceous contamination varied in thickness with location on LDEF, even on a micro scale. In-flight deposited (low velocity) contaminants include urine droplets and bits of metal film from eroded thermal blankets.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: NASA. Langley Research Center, LDEF: 69 Months in Space. Third Post-Retrieval Symposium, Part 1; p 459-460
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...