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  • Articles  (16)
  • General Chemistry  (12)
  • Holocene  (4)
  • SPACECRAFT DESIGN, TESTING AND PERFORMANCE
  • SPACECRAFT PROPULSION AND POWER
  • 11
    ISSN: 0570-0833
    Keywords: photosynthesis ; porphyrins ; porphyrinoids ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 12 (1973), S. 1023-1023 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 13
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA4001, doi:10.1029/2004PA001008.
    Description: Planktonic foraminiferal δ18O time series from three well-dated, high sedimentation rate cores near the Florida Keys (24.4°N, 83.3°W) exhibit repeated centennial to millennial-scale oscillations during the late Holocene. Isotopic shifts of 0.2–0.3‰ over the past 5200 years represent changes in sea-surface temperature (SST) of 1.0–1.5°C or salinity variability of 1–2 psu. The largest significant isotopic events are centered at approximately 200, 2000, 3200, and prior to 4000 calendar years BP. High Florida Current δ18O during the Little Ice Age (LIA) correlates with published records of high δ18O in the Sargasso Sea and low SST off the coast of west Africa. An interval of generally low δ18O in the Florida Straits from 1800 to 500 years BP is synchronous with the Medieval Warm Period off west Africa but leads low δ18O in the Sargasso Sea by several hundred years. Synchronous cooling across the subtropical gyre during the LIA is difficult to explain using interannual North Atlantic Oscillation patterns but may be consistent with the simulated effects of reduced solar irradiance. At frequencies between 1/1000 and 1/300 years during the Late Holocene, Florida Current δ18O is coherent with a published estimate of 14C production rate. Radiocarbon production seems to lead δ18O at these frequencies, but uncertainty in the phase calculation precludes a clear lead-lag relationship. At frequencies lower than 1/300 years, Florida Current δ18O is coherent and in phase with atmospheric Δ14C. The coherence of Δ14C and δ18O at periods 〉1000 years implies oceanic circulation may play a role in modulating atmospheric radiocarbon on millennial timescales.
    Description: This work was supported by NSF grants OCE-9905605 and OCE-0096469.
    Keywords: Holocene ; Florida current ; Density
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 14
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 24 (2009): PA3209, doi:10.1029/2008PA001717.
    Description: The density structure across the Florida Straits is reconstructed for the last 8000 years from oxygen isotope measurements on foraminifera in sediment cores. The oxygen isotope measurements suggest that the density contrast across the Florida Current increased over this time period. The magnitude of this change corresponds to an increase in the geostrophic transport referenced to 800 m water depth of 4 sverdrups (Sv) over the last 8000 years. The spatial and seasonal distribution of incoming solar radiation due to changes in the Earth's orbit has caused systematic changes in the atmospheric circulation, including a southward migration of the Intertropical Convergence Zone over the last 8000 years. These changes in atmospheric circulation and the associated wind-driven currents of the upper ocean could readily account for a 4 Sv increase in the strength of the Florida Current. We see no evidence in our data for dramatic changes in the strength of the Atlantic Meridional Overturning Circulation over this time period.
    Description: This work was supported by NSF grants OCE-9984989/OCE-0428803 and OCE-0096472 to J.L.-S. and NSF grants OCE-0096469 to W.B.C.
    Keywords: Florida Current ; Holocene ; Foraminifera
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/postscript
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  • 15
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Estuarine, Coastal and Shelf Science 88 (2010): 385-394, doi:10.1016/j.ecss.2010.04.019.
    Description: Apalachicola Bay and St. George Sound contain the largest oyster fishery in Florida, and the growth and distribution of the numerous oyster reefs here are the combined product of modern estuarine conditions in the bay and its late Holocene evolution. Sidescan-sonar imagery, bathymetry, high-resolution seismic profiles, and sediment cores show that oyster beds occupy the crests of a series of shoals that range from 1 to 7 km in length, trend roughly north-south perpendicular to the long axes of the bay and sound, and are asymmetrical with steeper sides facing to the west. Surface sediment samples show that the oyster beds consist of shelly sand, while much of the remainder of the bay floor is covered by mud delivered by the Apalachicola River. The present oyster reefs rest on sandy delta systems that advanced southward across the region between 6400 and 4400 yr BP when sea level was 4–6 m lower than present. Oysters started to colonize the region around 5100 yr BP and became extensive by 1200 and 2400 yr BP. Since 1200 yr BP, their aerial extent has decreased due to burial of the edges of the reefs by the prodelta mud that continues to be supplied by the Apalachicola River. Oyster reefs that are still active are narrower than the original beds, have grown vertically, and become asymmetrical in cross-section. Their internal bedding indicates they have migrated westward, suggesting a net westerly transport of sediment in the bay.
    Description: Funding for this research was provided by the NOAA Coastal Services Center.
    Keywords: Oyster reefs ; Substrate preferences ; Brackish water environment ; Holocene ; USA ; Florida ; Apalachicola Bay
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 16
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Costa, K. M., Hayes, C. T., Anderson, R. F., Pavia, F. J., Bausch, A., Deng, F., Dutay, J., Geibert, W., Heinze, C., Henderson, G., Hillaire-Marcel, C., Hoffmann, S., Jaccard, S. L., Jacobel, A. W., Kienast, S. S., Kipp, L., Lerner, P., Lippold, J., Lund, D., Marcantonio, F., McGee, D., McManus, J. F., Mekik, F., Middleton, J. L., Missiaen, L., Not, C., Pichat, S., Robinson, L. F., Rowland, G. H., Roy-Barman, M., Alessandro, Torfstein, A., Winckler, G., & Zhou, Y. 230 Th normalization: new insights on an essential tool for quantifying sedimentary fluxes in the modern and quaternary ocean. Paleoceanography and Paleoclimatology, 35(2), (2020): e2019PA003820, doi:10.1029/2019PA003820.
    Description: 230Th normalization is a valuable paleoceanographic tool for reconstructing high‐resolution sediment fluxes during the late Pleistocene (last ~500,000 years). As its application has expanded to ever more diverse marine environments, the nuances of 230Th systematics, with regard to particle type, particle size, lateral advective/diffusive redistribution, and other processes, have emerged. We synthesized over 1000 sedimentary records of 230Th from across the global ocean at two time slices, the late Holocene (0–5,000 years ago, or 0–5 ka) and the Last Glacial Maximum (18.5–23.5 ka), and investigated the spatial structure of 230Th‐normalized mass fluxes. On a global scale, sedimentary mass fluxes were significantly higher during the Last Glacial Maximum (1.79–2.17 g/cm2kyr, 95% confidence) relative to the Holocene (1.48–1.68 g/cm2kyr, 95% confidence). We then examined the potential confounding influences of boundary scavenging, nepheloid layers, hydrothermal scavenging, size‐dependent sediment fractionation, and carbonate dissolution on the efficacy of 230Th as a constant flux proxy. Anomalous 230Th behavior is sometimes observed proximal to hydrothermal ridges and in continental margins where high particle fluxes and steep continental slopes can lead to the combined effects of boundary scavenging and nepheloid interference. Notwithstanding these limitations, we found that 230Th normalization is a robust tool for determining sediment mass accumulation rates in the majority of pelagic marine settings (〉1,000 m water depth).
    Description: We thank Zanna Chase and one anonymous reviewer for valuable feedback. K. M. C. was supported by a Postdoctoral Scholarship at WHOI. L. M. acknowledges funding from the Australian Research Council grant DP180100048. The contribution of C. T. H., J. F. M., and R. F. A. were supported in part by the U.S. National Science Foundation (US‐NSF). G. H. R. was supported by the Natural Environment Research Council (grant NE/L002434/1). S. L. J. acknowledges support from the Swiss National Science Foundation (grants PP002P2_144811 and PP00P2_172915). This study was supported by the Past Global Changes (PAGES) project, which in turn received support from the Swiss Academy of Sciences and the US‐NSF. This work grew out of a 2018 workshop in Aix‐Marseille, France, funded by PAGES, GEOTRACES, SCOR, US‐NSF, Aix‐Marseille Université, and John Cantle Scientific. All data are publicly available as supporting information to this document and on the National Center for Environmental Information (NCEI) at https://www.ncdc.noaa.gov/paleo/study/28791.
    Keywords: Thorium ; Sediment flux ; Holocene ; LGM ; GEOTRACES
    Repository Name: Woods Hole Open Access Server
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