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  • Industrial Chemistry  (3)
  • Fermentation broth  (1)
  • enantioselective transport  (1)
  • viscoelasticity  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 25 (1986), S. 433-439 
    ISSN: 1435-1528
    Keywords: Fermentation broth ; apparent viscosity ; viscoelasticity ; microbial pellet
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Abstract The flow behavior of microbial suspensions, otherwise referred to as fermentation broths, is strongly influenced by both the concentration and morphology of the suspended microorganisms. This work investigates the relationship between these parameters. The microorganism used was Streptomyces tendae, which is a pellet-building, filamentous organism. Rheological measurements of these broths were carried out in a Couette geometry. The morphology of the suspensions was characterized by the microbial pellet size distribution. The suspensions showed themselves to be both shear thinning (steady flow curve) and very elastic (dynamic flow curve).
    Notes: Zusammenfassung Das Fließverhalten suspendierter Mikroorganismen, hier kurz Biosuspensionen genannt, ist unter anderem stark abhängig von der Konzentration und der Morphologie der Mikroorganismen. Hier wird über Untersuchungen zu diesen Abhängigkeiten berichtet. Als Biosuspension wurde Streptomyces tendae, ein pelletbildendes Bakterium verwendet. Die rheometrischen Untersuchungen wurden in einem Couette-System (3 mm Spaltweite) mit einem konventionellen Rotationsrheometer durchgeführt. Zur Kennzeichnung der Morphologie wurden Pelettgrößenverteilungen und zur Beschreibung des Fließverhaltens die stationäre Fließkurve und die Parameter der linearen Viskoelastizität bestimmt. Es zeigt sich, daß bei kleinen Scherbelastungen die Pellets zu unter Umständen den gesamten Meßspalt überbrückenden Netzwerken agglomerieren, die bei höheren Schergeschwindigkeiten schließlich bis zu Einzelpellets abgebaut werden. Noch weitere Steigerung der Schergeschwindigkeit führt zur Verformung der Pellets, was sich als sehr langsam ablaufender Vorgang darstellt. Abschließend werden Betrachtungen zur Modellierung des Fließverhaltens angestellt.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0899-0042
    Keywords: enantioselective transport ; single two-phase liquid-liquid extraction ; N-protected α-amino acid derivatives ; quinine carbamate-type chiral selectors ; chiral anion-exchange carrier ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two-phase liquid-liquid extraction experiments were undertaken to study the enantioselective transport of the chiral N-protected α-amino acid derivatives from an aqueous buffer solution into an organic phase employing highly lipophilic carbamoylated quinine as chiral selector and phase transfer carrier, respectively. The chiral separation, derived from enantioselective ion-pair formation and differential solubility in the aqueous and organic phases of diastereomeric associates thus formed has been shown to be primarily dependent on the structure of the selectand, the nature of the organic solvent, the molar ratio of a given chiral selector to selectand in the two phases, and the pH of the aqueous phase. Extracted enantiomers were recovered by back-extraction using a relatively polar acidic medium in which the selector is barely insoluble. Thus, the enantiomeric purity of N-(3,5-dinitrobenzoyl)-leucine exceeded 95% enantiomeric excess with 70% overall yield with a single extraction and back-extraction step. Chirality 9:268-273, 1997. © 1997 Wiley-Liss, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 71 (1999), S. 1046-1046 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 68 (1996), S. 1153-1154 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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