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  • Emulsion polymerization  (1)
  • SAXS  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Influence of Cd content and Se doping on the formation of CdSe nanocrystals in silica xerogels: A SAXS study (1997)
    Springer
    Journal of sol gel science and technology 8 (1997), S. 285-291 
    Details
    ISSN: 1573-4846
    Keywords: CdSe nanocrystals ; silica xerogels ; sonogels ; SAXS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Small-angle X-ray scattering (SAXS) experiments were carried out to characterize the structure of the composite formed by CdSe nanocrystals embedded in a popous silica matrix (silica xerogels containing Cd with formamide addition and ultrasound treatment). SAXS results from samples before Se diffusion indicate the presence of heterogeneities with a bimodal size distribution which was associated to the existence of mesopores (pores of several hundred Å) immersed in a nanoporous matrix (characteristic pore radii of 20–30 Å). The diffusion of Se induces the nucleation and growth of CdSe nanocrystals. The average size of the nanocrystals increases with Cd content. Higher Se doses promote the formation of larger nanocrystals (radius of gyration of ∼30 to 50 Å). Anomalous scattering results confirm the existence of Se aggregation associated with CdSe nanocrystal formation and suggest that only partial segregation of Cd and Se occurs.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02436853
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  • 2
    Electronic Resource
    Electronic Resource
    Emulsion Polymerization of Vinyl Monomers under the Influence of Ionizing Radiation (1963)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 295-308 
    Details
    ISSN: 0570-0833
    Keywords: Emulsion polymerization ; Polymerization ; Polymerization ; Alkenes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ionizing radiation induces the polymerization of some vinyl monomers in aqueous emulsion with high radiation yields. With identical emulsion compositions, the kinetics of this reaction and the kinetics of emulsion polymerization induced by water-soluble initiators are very similar. The rate of reaction in emulsion polymerization is about one hundred times greater than in bulk polymerization. The initiation of emulsion polymerization by means of ionizing radiation permits uniform “illumination” of the reacting volume, as well as almost any desired variation in the frequency of initiation during the reaction. The sharp decrease in the overall rate of reaction when initiation is interrupted during emulsion polymerization of styrene induced by γ-rays contradicts the earlier concept of sharply separated reaction zones.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196302951
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