ISSN:
0009-2940
Keywords:
Cycloadditions, dipolar
;
Electron-transmission spectroscopy
;
Norbornane systems
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of six 7-substituted norbornadienes with seven sulfonyl azides has been investigated. The products consist of either the novel azatetracyclic system 1 or the stereoisomeric bicycles 2 or of a mixture of them. The chemical behaviour of 1 has been studied. Mechanistically the results may be rationalized within the frame of the Mazzocchi-Houk model. The theoretical predictions of this model, concerning the π*and σ* energies, were confirmed experimentally by using electron-transmission spectroscopy.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241232
Permalink