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  • 1
    Electronic Resource
    Electronic Resource
    Injection moulding of thermoplastics: Freezing during mould filling (1983)
    Springer
    Rheologica acta 22 (1983), S. 223-236 
    Details
    ISSN: 1435-1528
    Keywords: Injection moulding ; thermoplastic ; freezing ; polymer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The injection moulding of thermoplastic polymers involves, during mould filling, flows of hot melts into mould networks, the walls of which are so cold that frozen layers form on them. Theoretical analyses of such flows are presented here.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01332374
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  • 2
    Electronic Resource
    Electronic Resource
    Rotary injection reaction injection molding (RI-RIM). Part II: Interfacial segregation of release systems (1990)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 175-186 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes the shear imposed interfacial segregation of release systems for the facilitated attenuation of polyurethane (PU) adhesion to metal coun-terfaces using a RI-RIM system. It is shown that the migration rate of the dispersed release additives due to a shear imposed stress in the resin fluid is much greater than that arising from Fickian diffusion, thereby removing a vital constraint from conventional practice. The novel rotary injection RIM system is presented to simulate the on-line injection and shear induced interfacial segregation in model PU/abherent systems. A wide range of recipes comprising single (liquids or solids) and multicomponent (liquid-liquid and solid-liquid) release materials were injected into the polymerizing resin mixture to provide cohesively weak and friable “particle” boundary layer assemblies at the PU/metal interface. An instrumented Blister Test was employed to evaluate the quality of the molded interfaces in terms of adhesion and the concentration distribution of the injected species in the final cured moldings was determined through high pressure liquid chromatography (HPLC). A comparison of the results on the shear modified and the compounded interfaces confirm an accentuated lateral migration of the additives to the interface resulting in an appreciable diminution in the adhesion of the system. Finally, transport models are suggested to account for the observed augmented transport.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760300307
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  • 3
    Electronic Resource
    Electronic Resource
    Rotary injection reaction injection molding (RI-RIM). Part I: Basic design features (1990)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 162-174 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes the basic design features of a new reaction injection molding (RIM) processing device, Rotary Injection RIM (RI-RIM). The new design includes a novel mixing concept which furnishes high intermaterial contact area upon shear imposed rotary injection of the RIM components for effective in situ polymerization. This system operates in low pressure and laminar flow conditions, as opposed to the high pressure and turbulent flow, found in conventional RIM systems. The mixing process is described and quantified in terms of the various forces which govern the injection process. A progressive diminution in the average size of the dispersions generated is found with increasing rate of shear, continuous-phase viscosity, and injection rate. These results are compared with those expected from traditional shear mixing (bulk convective shearing) under comparable conditions and the current system found to be more efficacious. Reaction molding experiments with RI-RIM using a model polyurethane system are described and the influence of operating conditions on the mechanical properties of the finished moldings are elucidated. A detectable change in the morphology of the system is observed following increase in the total shear strain imparted to the initial mix of the multiphase reactants. It is suggested that the observed change is affected by a segregation between the components of the segmented polymer.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760300306
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  • 4
    Electronic Resource
    Electronic Resource
    Simulation of reacting flow during filling in reaction injection molding (RIM) (1986)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1264-1275 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper deals with computer simulation of the filling stage of the Reaction Injection Molding (RIM) process for cavities of rectangular, cylindrical, and disc shapes. The computer model is in two parts: the main flow and the flow by the moving front. In the main flow part, the transient equations of axial momentum, energy and species conservation and also the continuity equation are solved numerically by finite-difference methods using a moving, changing mesh. In the flow front part, which is quite novel, the transient (parabolic) vorticity, energy and species conservation equations and the elliptic streamfunction equation are again solved by finite-difference methods. An important feature of both parts is that convection along and across the flow is included in all the transient equations. Results are presented for all three cavity shapes and those for rectangular cavities are compared with the experimental results of previous investigators.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760261806
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