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  • Chemistry  (8)
  • Superfluidity and superconductivity  (3)
  • fertilizer N  (3)
  • Engineering  (2)
  • 1
    ISSN: 1075-4261
    Keywords: black pigment gallstone ; FTIR ; EPR ; nonlinear phenomena ; vibrational mode ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: Further spectroscopic studies of gallstones are reviewed with an emphasis on the formation of black pigment gallstones. This type of gallstone appears mainly in Western countries, with only 3% of the cholelithiasis patients in China having black gallstones. Fourier transform infrared absorption and electron paramagnetic resonance are used as spectroscopic probes of gallstones and their metal bilirubinate components. Nonlinear phenomena in gallstone formation were investigated through the appearance of ring structure in gallstones and fractal patterns in the formation in the precipitates of bile salt systems. Although a complete understanding of gallstone formation has not yet been achieved, interesting progress toward this goal has been made recently. © 1997 John Wiley & Sons, Inc. Biospectroscopy 3: 381-391, 1997
    Additional Material: 12 Ill.
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  • 2
    ISSN: 1573-5036
    Keywords: alley cropping ; C/N ratio ; decomposition ; fertilizer N ; leucaena N ; leucaena residues ; lignin ; maize ; N mineralization ; 15N recovery ; N uptake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The success of alley cropping depends to a large extent on the efficiency of transfer of nitrogen (N) from the legume hedgerow plants to the non-legume crop. Here the idea is examined that leucaena prunings (residues) can supply enough N to maize plants to significantly reduce the degree of N deficiency. Two experiments on decomposition of leucaena leaf, stem, and petiole and mineralization of N from leucaena residues were conducted in field microplots which received application of either15N-labelled leucaena materials or ammonium sulphate fertilizer. The microplots were installed in alleys formed by leucaena hedgerows spaced 4.5 metres apart and cropped with maize. The decomposition of leucaena leaves, stems and petioles was estimated by several methods. The decomposition ranged from 50–58% with leaves, 25–67% with stems and 38–51% with petioles 20 days after addition. More than 55% of the N was released in 52 days during decomposition of leucaena residues. By 20 days after application of15N-labelled leucaena 3.3–9.4% of the added15N was found in the maize plants, 32.7–49.0% was in the leucaena residues, 36.0–48.0% in the soil and 0.3–21.9% lost (deficit). By 52 days 4.8% of the15N applied in leucaena prunings was taken up by maize, 45.1% was detected in the residues, 24.9% in the soil and 25.2% lost. However, when N fertilizer was applied, 50.2% of the fertilizer N was recovered by maize, 35.5% was retained in the soil and 14.3% apparently lost. There was a marked increase in maize plant dry matter and N uptake in the microplots with addition of leucaena prunings compared with those in the microplots without leucaena added. Most of the15N remaining in the soil profile, derived from leucaena residues, was detected in the top 25 cm soil with less than 2% found below 25 cm. ei]H Lambers
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  • 3
    ISSN: 1573-0867
    Keywords: alley cropping ; fertilizer N ; Leucaena leucocephala ; leucaena prunings ; maize residues ; 15N recovery
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Field microplot experiments were conducted in the semi-arid tropics of northern Australia to evaluate the response of maize (Zea mays L.) growth to addition of N fertilizer and plant residues and to examine the fate of fertilizer15N in a leucaena (Leucaena leucocephala) alley cropping system, in which supplemental irrigation was used. Leucaena prunings, maize residues and N fertilizer were applied to alley-cropped maize grown in microplots which were installed in the alleys formed by leucaena hedgerows spaced 4.5 metres apart. The15N-labelled fertilizer was used to examine the fate of fertilizer N applied in the presence of mulched leucaena prunings and maize residues. Application of leucaena prunings increased maize yield while addition of N fertilizer in the presence of the prunings produced a further increase in maize production. There was a significant positive interaction between N fertilizer and leucaena prunings in increasing maize production. The addition of maize residues in the presence of N fertilizer and leucaena prunings decreased maize yield and N uptake and increased fertilizer15N loss from 38% to 47%. Maize recovered 24–79% of fertilizer15N in one cropping season, depending on application rate of N fertilizer and field management of plant residues. About 20–34% of fertilizer15N remained in the soil. More than 37% of fertilizer15N was apparently lost from the soil and plant system largely through denitrification when N fertilizer was applied at 40 kg N ha−1 or more in the presence or absence of plant residues. Application of N fertilizer improved maize yield and increased the contribution of mulched leucaena prunings to crop production in the alley cropping system.
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  • 4
    ISSN: 1573-5036
    Keywords: decomposition ; fertilizer N ; leucaena residues ; maize residues ; N loss ; N uptake ; 15N recovery ; residue incorporation ; residue N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In an alley cropping system, prunings from the hedgerow legume are expected to supply nitrogen (N) to the associated cereal. However, this may not be sufficient to achieve maximum crop yield. Three field experiments with alley-cropped maize were conducted in a semi-arid environment in northern Australia to determine: (1) the effect of N fertilizer on maize growth in the presence of fresh leucaena prunings; (2) the effect of incorporation of leucaena and maize residues on maize yield and the fate of plant residue15N in the alley cropping system; and (3) the15N recovery by maize from15N-labelled leucaena, maize residues and ammonium sulphate fertilizer. Leucaena residues increased maize crop yield and N uptake although they did not entirely satisfy the N requirement of the alley crop. Additional N fertilizer further increased the maize yield and N uptake in the presence of leucaena residues. Placement of leucaena residues had little effect on the availability of N to maize plants over a 2 month period. The incorporation of leucaena residues in the soil did not increase the recovery of leucaena15N by maize compared with placement of the residues on the soil surface. After 2 months, similar proportions of the residue15N were recovered by maize from mulched leucaena (6.3%), incorporated leucaena (6.1%) and incorporated maize (7.6%). By the end of one cropping season (3 months after application) about 9% of the added15N was taken up by maize from either15N-labelled leucaena as mulch or15N-labelled maize residues applied together with unlabelled fresh leucaena prunings as mulch. The recovery of the added15N was much higher (42.7%) from the15N-labelled ammonium sulphate fertilizer at 40 kg N ha-1 in the presence of unlabelled leucaena prunings. Most of the added15N recovered in the 200 cm soil profile was distributed in the top 25 cm soil with little leached below that. About 27–41% of the leucaena15N was apparently lost, largely through denitrification from the soil and plant system, in one cropping season. This compared with 35% of the fertilizer15N lost when the N fertilizer was applied in the presence of prunings. ei]H Lambers
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 397-400 
    ISSN: 0887-624X
    Keywords: molecular composites ; rigid polymers ; sulfonated poly(p-phenylene terephthalamide) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 170-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 7
    ISSN: 1075-4261
    Keywords: brown pigment stone ; PAGE ; mid-IR spectroscopy ; far IR spectroscopy ; FT-Raman ; bezoar ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: Spectroscopic studies of various types of gallstones carried out in China are reviewed. Three basic classes of gallstones are surveyed: cholesterol stones, brown pigment stones, and black pigment stones. The emphasis of this review is on brown gallstones. The primary spectroscopic methods used in the studies surveyed are Fourier transform infrared absorption and Fourier transform Raman scattering. Chemical components studied in gallstones include cholesterol, bile pigments, glycoproteins, proteins, bilirubin metal complexes, and salts of calcium and other metals. Further studies are needed characterize the relationship of these components to more complex features of gallstones. © 1997 John Wiley & Sons, Inc. Biospectroscopy 3: 371-380, 1997
    Additional Material: 13 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 27 (1989), S. 355-368 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Fourier-transform infrared measurements on atactic and amorphous isotactic polystyrenes have been made during application of strain. On passing through the yield point, spectra indicate an increase of the amount of higher-energy conformation. In atactic polystyrene it corresponds to an increase of gauche conformations whatever the state may be: pure or plasticized samples, blend with another compatible polymer, or styrene-acrylonitrile copolymer. In amorphous isotactic polystyrene an increase of higher-energy trans conformation is observed. These results strongly support the theory developed by Robertson to explain plastic deformation of polymers.
    Additional Material: 10 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 71-75 
    ISSN: 0887-6266
    Keywords: rigid polymer ; sulfonated poly(p-phenylene terephthalamide) ; polymer aggregation ; solution viscosity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The viscosities of dilute solutions of poly(p-phenylene terephthalamide), PPTS, in dimethylacetamide, water, and their mixtures were determined. The reduced viscosity plot in dimethylacetamide shows a negative slope. When the water content in the mixed solvent in 90% or higher, there is an upswing in the reduced viscosity values at concentrations below 0.1 g/dL. The latter behavior suggests a “polyelectrolyte” effect. However, an association model was found to be able to explain the viscosity behaviors in both solvents. ©1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 2351-2357 
    ISSN: 0887-6266
    Keywords: segregation ; interfacial tension ; polymer microemulsion ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: We have studied the segregation of a block copolymer of poly(d8-styrene-b-2-vinylpyridine) (dPS-PVP) at the interface between polystyrene and a random copolymer of poly(styreneran-4-hydroxystyrene) (PS-r-PPHS). Forward recoil spectrometry (FRES) was used to measure the equilibrium excess (z*) of the dPS-PVP chains at the interface as a function of its volume fraction in the bulk PS phase (φ∞). It was found that there is a sharp increase in z* at a critical value of φ∞. This upturn indicates the formation of a microemulsion of PS and the random copolymer PS-r-PPHS due to a vanishing of the interfacial tension caused by the strong adsorption of the block copolymer. Cross-sectional transmission electron microscopy (TEM) of the interface shows that this microemulsion starts to form at the interface by forming a deeply corrugated structure where the “wavelength” of the corrugations is of the order of 50 nm. © 1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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