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  • Ammonia volatilization  (4)
  • 1
    ISSN: 1432-0789
    Keywords: Denitrification ; Ammonia volatilization ; Wetland rice soils ; Urea ; 15N-balance method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The relative importance of ammonia volatilization and denitrification as loss processes following the application of urea to flooded rice by the traditional method was assessed at four sites with different characteristics in the Philippines. The effect of reducing ammonia loss on denitrification and total N loss was also studied. The total N loss was determined by a 15N-balance method and ammonia volatilization was assessed by a bulk aerodynamic method following the application of urea to small plots (4.8×5.2 m). As run-off was prevented and leaching losses were negligible, the denitrification loss was assessed as the difference between total N loss and ammonia loss. When urea was broadcast into the floodwater at transplanting, the ammonia loss varied from 10% to 56% of the applied N. Loss was smallest at Aguilar where wind speeds were low and the greatest at Mabitac where floodwater pH values and temperatures were high and the winds were strong. The ammonia loss was reduced at all sites by incorporating the urea into the soil by harrowing. However, the reduction achieved varied markedly between sites, with the largest reduction (from 56% to 7% loss of the applied N) being observed at Mabitac. The total N lost from the basal application into the floodwater ranged from 59% to 71% of the applied N. Incorporating the urea by harrowing reduced the total N loss at two sites, increased the total N loss at the third site, and had no effect at the fourth site. The denitrification losses ranged widely (from 3% to 50% of the applied N) when urea was broadcast into the floodwater at the four sites. The denitrification loss was low when the ammonia loss was high (Mabitac) and high when the ammonia loss was low (Aguilar). Reducing ammonia losses by incorporating the urea into the flooded soil resulted in increased denitrification losses at three of the sites and appeared to have no effect on denitrification at the fourth site. The results show that reducing the ammonia loss by incorporating urea into the soil does not necessarily result in reduced total N loss, and suggest that the efficiency of fertilizer N will be improved only when both N-loss processes are controlled simultaneously.
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  • 2
    ISSN: 1432-0789
    Keywords: Key words Denitrification ; Ammonia volatilization ; Phosphoroamides ; Urea hydrolysis ; Acetylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We studied the interacting effects on NH3 loss and grain yield of adding (1) urease inhibitors to retard the hydrolysis of urea (2) the algicide terbutryn to limit floodwater pH increases, and (3) C2H2 (provided by wax-coated calcium carbide) to prevent NH3 oxidation. The algicide treatment maintained the floodwater pH values below 8 for the first 3 days after the urea application and depressed the maximum values below 8.5 on subsequent days. As a consequence, NH3 loss was significantly (P〈0.05) reduced in all treatments containing algicide. The addition of wax-coated calcium carbide effectively inhibited nitrification, as judged by the increased ammoniacal (NH3+NH4) N concentrations in the floodwater. However, these increased ammoniacal-N concentrations resulted in large losses of NH3. The results also showed that the effectiveness of a urease inhibitor cannot be judged solely from the ammoniacal-N concentrations in the floodwater of a single treatment with the inhibitor. Additional treatments with an algicide and a nitrification inhibitor are required to determine whether the low ammoniacal-N concentrations are caused by NH3 losses and nitrification. Thus N-(n-butyl)thiophosphorictriamide (NBPT) appeared to retard urea hydrolysis when judged by the low ammoniacal-N concentrations in the floodwater; however, treatments with NBPT, algicide, and C2H2 showed that the low concentrations were mainly a result of NH3 volatilization and nitrification. Even though NBPT did not completely inhibit urea hydrolysis, some treatments with this compound reduced NH3 losses and increased grain yields by up to 31%.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 20 (1989), S. 59-66 
    ISSN: 1573-0867
    Keywords: Ammonia volatilization ; nitrogen leaching ; denitrification ; time of N application ; wheat ; Triticum aestivum ; Triticale ; irrigation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Grain yield, nitrogen (N) assimilation, ammonia (NH3) volatilization, denitrification and fertilizer N distribution were examined in three commercially grown cereal crops; two were sown into conventionally tilled fields, while the third was direct drilled into an untilled field. The crops were top dressed with urea at establishment, tillering or ear initiation. Crop yield and N assimilation were measured in 16 m by 2.5 m plots receiving 0, 35, 70, 105, 140 or 175 kg N ha−1. A mass balance micrometeorological technique was used to measure NH3 volatilization, and other fertilizer N transformations and transfers were studied using15N labelled urea in microplots. On the conventionally tilled sites application of urea increased the grain yield of wheat from 3.9 to 5.5 t ha−1, when averaged over the five application rates, three application times and two sites. There were no site or application time effects. However, on the direct drilled site, time of application had a significant effect on grain yield. When urea was applied at establishment, grain yield was not significantly increased and the mean yield (2.81 t ha−1) was less than that obtained from treatments fertilized at tillering or ear initiation (4.09 and 4.0 t ha−1, respectively). Much of the variation in grain yield at the no-till site could be ascribed to differences in NH3 volatilization. At the no-till site, NH3 losses were equivalent to 24, 12 and 1% of the N applied at establishment, tillering and ear initiation, respectively. Negligible volatilization of NH3 occurred at the other sites. The surface soil at the no-till site had the highest urease activity and the soil was covered with alkaline ash resulting from stubble burning. Plant recovery of fertilizer N did not vary with application time on conventionally tilled sites (mean 62%). However, plant recovery of15N applied to the no-till site at establishment (35% of the applied N) was significantly less than that from plots where the application was delayed (45% at tillering and 55% at ear initiation, respectively). Leaching of N to below 300 mm depth was minimal (0 to 5% of the applied N). The calculated denitrification losses ranged from 1% to 14% of the applied N. The results show that the relative importance of NH3 volatilization, leaching and denitrification varied with site and fertilization time. The importance of the various N loss mechanisms needs to be taken into account when N fertilization strategies are being developed.
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  • 4
    ISSN: 1432-0789
    Keywords: Denitrification ; Ammonia volatilization ; Phosphoroamides ; Urea hydrolysis ; Acetylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We studied the interacting effects on NH3 loss and grain yield of adding (1) urease inhibitors to retard the hydrolysis of urea (2) the algicide terbutryn to limit floodwater pH increases, and (3) C2H2 (provided by waxcoated calcium carbide) to prevent NH3 oxidation. The algicide treatment maintained the floodwater pH values below 8 for the first 3 days after the urea application and depressed the maximum values below 8.5 on subsequent days. As a consequence, NH3 loss was significantly (P〈0.05) reduced in all treatments containing algicide. The addition of wax-coated calcium carbide effectively inhibited nitrification, as judged by the increased ammoniacal (NH3+NH4) N concentrations in the floodwater, However, these increased ammonical-N concentrations resulted in large losses of NH3. The results also showed that the effectiveness of a urease inhibitor cannot be judged solely from the ammonical-N concentrations in the floodwater of a single treatment with the inhibitor. Additional treatments with an algicide and a nitrification inhibitor are required to determine whether the low ammoniacal-N concentrations are caused by NH3 losses and nitrification. Thus N-(n-butyl)thiophosphorictriamide (NBPT) appeared to retard urea hydrolysis when judged by the low ammoniacal-N concentrations in the floodwater; however, treatments with NBPT, algicide, and C2H2 showed that the low concentrations were mainly a result of NH3 volatilization and nitrification. Even though NBPT did not completely inhibit urea hydrolysis, some treatments with this compound reduced NH3 losses and increased grain yields by up to 31%.
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