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  • Chemistry  (6)
  • 523  (2)
  • Analytical Chemistry and Spectroscopy  (2)
  • Column liquid chromatography  (2)
  • 1
    Publication Date: 2021-07-03
    Description: We mapped the distribution of the 365‐nm albedo of the Venus atmosphere over the years 2006–2014, using images acquired by the Venus Monitoring Camera (VMC) on board Venus Express. We selected all images with a global view of Venus to investigate how the albedo depends on longitude. Bertaux et al. (2016, https://doi.org/10.1002/2015JE004958) reported a peak in albedo around 100° longitude and speculated on an association with the Aphrodite Terra mountains. We show that this peak is most likely an artifact, resulting from long‐term albedo variations coupled with considerable temporal gaps in data sampling over longitude. We also used a subset of images to investigate how the albedo depends on local time, selecting only south pole viewing images of the dayside (local times 7–17 hr). Akatsuki observed mountain‐induced waves in the late afternoon at 283 nm and 10 μm (Fukuhara et al., 2017, https://doi.org/10.1038/ngeo2873). We expect that the presence of such waves may introduce 365‐nm albedo variations with a periodicity of one solar day (116.75 Earth days). We searched for such a periodicity peak at 15:30–16:00 local time and low latitudes but did not find it. In conclusion, we find that temporal albedo variations, both short and long term, dominate any systematic variations with longitude and local time. The nature of VMC dayside observations limits regular data sampling along longitudes, so longitudinal variations, if they exist, are difficult to extract. We conclude that any influence by the Venus surface on 365‐nm albedo is negligible within this data set.
    Description: Plain Language Summary: Recently, it was reported that mountains on the surface of Venus can affect the atmosphere at the altitude of the cloud tops (70 km). For example, the brightness of the clouds (albedo) in images made by the Venus Express spacecraft at ultraviolet wavelengths (365 nm) was suspected to peak over a high mountain, Aphrodite Terra. We searched for such surface effects using the Venus Express images taken at 365 nm over the years 2006–2014. We found that the albedo was strongly variable over this period and that different longitudes were systematically imaged at different times. It is therefore not possible to uncover the influence of mountains on the albedo, and we believe that the reported albedo peak near Aphrodite Terra is most likely not real. Another spacecraft, Akatsuki, observed global‐scale atmospheric waves in the late afternoon that are originated by mountains. We also searched for albedo changes at the same latitude with a period of one solar day (116.75 Earth days) that might be linked with these atmospheric waves but did not find any period above the noise level. We conclude that the influence of mountains on the 365‐nm albedo is too weak to be recognized in Venus Express images.
    Description: Key Points: Temporal variations of the 365‐nm albedo of Venus dominate over any systematic variations along longitude or over local time. We found no systematic influence by mountains on the 365‐nm albedo distribution, in contrast to a previous report.
    Description: EU Horizon 2020 MSCA-IF
    Description: JAXA ITYF
    Description: JPSP International Research Fellow program
    Keywords: 523 ; Venus ; UV ; image analysis ; observations ; clouds
    Type: article
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  • 2
    Publication Date: 2021-07-21
    Description: The so‐called unknown absorber in the clouds of Venus is an important absorber of solar energy, but its vertical distribution remains poorly quantified. We analyze the 283 and 365 nm phase curves of the disk‐integrated albedo measured by Akatsuki. Based on our models, we find that the unknown absorber can exist either well mixed over the entire upper cloud or within a thin layer. The necessary condition to explain the 365 nm phase curve is that the unknown absorber must absorb efficiently within the cloud scale height immediately below the cloud top. Using this constraint, we attempt to extract the SO2 abundance from the 283 nm phase curve. However, we cannot disentangle the absorption by SO2 and by the unknown absorber. Considering previous SO2 abundance measurements at midinfrared wavelengths, the required absorption coefficient of the unknown absorber at 283 nm must be more than twice that at 365 nm.
    Description: Plain Language Summary: There is an unknown absorber in the clouds of Venus. It absorbs solar energy effectively at ultraviolet (UV) and blue wavelengths, but its vertical location, either above or below the cloud top level (about 70 km altitude), remains unclear. This uncertainty affects our understanding of the vertical deposition of solar energy in the atmosphere. We investigate the vertical distribution of the unknown absorber using the dependence of the full‐disk brightness on the scattering direction (the Sun‐Venus‐spacecraft angle) at 365 nm, with data from JAXA's Akatsuki spacecraft over 3 years. We find that the unknown absorber could exist in the entire cloud, or as a thin layer near but below the cloud top. Using these constraints on the vertical distribution of the unknown absorber, we analyze the 283 nm full‐disk brightness. At this shorter wavelength, the SO2 gas and the unknown absorber are both effective absorbers. We attempt to quantify the SO2 abundance, and find that the brightness dependence on the scattering direction alone is insufficient to separate the contribution from the two absorbers at 283 nm. Further analysis with spectral phase curve observations will better define the SO2 abundance.
    Description: Key Points: The vertical distribution of the unknown absorber is investigated with the aid of full‐disk phase curves at wavelengths of 283 and 365 nm First time the 283 nm full‐disk brightness phase curve of Venus is analyzed over a broad phase angle range The unknown absorber must result in sufficient absorption within the cloud scale height immediately below the cloud top
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 Marie Skłodowska‐Curie Actions (MSCA) http://dx.doi.org/10.13039/100010665
    Keywords: 523 ; atmosphere ; phase curve ; simulation ; UV image ; Venus
    Type: article
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  • 3
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Indirect detection of non-electrolytes ; Simulation of induced peaks ; RP systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Induced peaks observed in indirect detection of nonelectrolytes in high-performance liquid chromatography are simulated. The equation representing the signal intensity of the induced peaks is derived, and it is verified by the experimental results. The peak area is proportional to (K b ′ +1) k a ′ /| a ′ —k b ′ |, where k a ′ ad k b ′ are the capacity factors of the visualization agent and the analyte, respectively.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fast atom bombardment mass spectrometry ; Nonionic detergents
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Microcolumn liquid chromatography (LC) combined with fast-atom-bombardment mass spectrometry (FABMS) was applied to the analysis of nonionic detergents. The porous silver filter attached to the top of the capillary fused-silica tubing worked as the interface for coupling of micro LC and FABMS.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 26 (1987), S. 625-632 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of LiCl, NaCl, and CsCl as univalent salts, and of CaCl2, ZnCl2, and MgCl2 as divalent salts, on the α and antiparallel β-sheet, and random conformations of poly(L-lysine) (PLL), in water at room temperature were examined by means of CD and compared quantitatively on the basis of elliptical strength at the maximal peak. Changes in the α-helical and antiparallel β-sheet helical conformations of PLL were markedly dependent on the salt concentrations of LiCl, NaCl, and CsCl, which induced decreases in negative intensity in that order. The CD spectrum of the random conformation, the most disordered form, displayed positive cotton effect in concentrations of these salts up to 3.0M and a negative peak in concentrations of 6.0M. The effect of these salts on the random conformation of PLL was stronger than that on the α- and β-conformations in higher concentrations. The CD spectrum of the random conformation in the presence of CaCl2, ZnCl2, and MgCl2, on the other hand, showed negative cotton effect in salt concentrations as low as 3.0M. It was impossible, however, to measure the effect on α- and β-conformations of ZnCl2 and MgCl2 above concentrations of 10 mM because of a solubility problem with salts in alkaline solution.
    Additional Material: 5 Ill.
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  • 6
    ISSN: 1075-4261
    Keywords: brain microsomal membranes ; fatty acids ; learning behavior ; FTIR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: We measured the Fourier transform infrared spectra of brain microsomal membranes prepared from rats fed under two dietary oil conditions with and without brightness-discrimination learning tasks: one group fed α-linolenate deficient oil (safflower oil) and the other group fed the sufficient oil (perilla oil) from mothers to offspring. The infrared spectra of microsomes under the two dietary conditions without the learning task showed no significant difference in the range 1000-3000 cm-1. Only after the learning task were the infrared spectral differences noted between the microsomal membranes from both groups. Spectral differences were observed mainly in the absorption bands of fatty acid ester at around 1730 cm-1 (sn-2 position), those of phosphate and oligosaccharides in the range of 1050-1100 cm-1, and a band at around 1145 cm-1. The infrared band of fatty acid ester at the sn-2 position in the microsomal membrane shifted to a longer wavenumber position in the perilla oil group than in the safflower oil group, suggesting a difference between both groups in hydrogen bonding of the fatty acid ester with water. A band observed at 1055 cm-1 and a small band at around 1145 cm-1 in the second derivative spectrum decreased in intensity in the perilla oil group after learning task. These bands were assigned mainly to the oligosaccharide C - O bond in hydroxyl groups that might interact with some other membrane components. These results suggest changes in hydration of membrane surface and modification in oligosaccharide environment (removal or modification) of microsomes, which may be correlated in part with dietary oil-induced changes in learning performance. © 1997 John Wiley & Sons, Inc. Biospectroscopy 3: 281-290, 1997
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 15 (1981), S. 553-563 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: With a view to developing biomaterials for semipermanent substitution, we have studied a composite material constituted with collagen and a synthetic polymer which possesses high tissue compatibility. This collagen - synthetic polymer composite was applied as a support for immobilization of enzymes for the purpose of providing a material surface with biological function. The enzymes, urokinase and trypsin, were successfully bound to the collagen membrane layer which had been activated by acyl azide formation of its carboxyl groups. The enzyme-bearing composite material showed excellent catalytic activity toward a protein substrate as well as a low-molecular-weight synthetic substrate. The immobilized urokinase was characterized enzymatically and compared with native urokinase. The apparent affinity of immobilized urokinase for the substrate was slightly decreased, but its intrinsic kinetic properties were not significantly affected. No decrease in its esterase activity was observed both on repeated use and on long-term storage, and its fibrinolytic activity was stable on heat or disinfection treatment. When this urokinase-bearing composite material was applied into rabbit blood vessels, its in vivo fibrinolytic activity was maintained. Thus, enzyme - collagen - synthetic polymer composites may find wide application for biomaterials and artificial organs as functional biomaterials.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 23 (1989), S. 1115-1130 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: In order to study the effects of factors governing the bioabsorption rate of polylactides, implantation tests were carried out in rabbits using various samples (20 × 10 × 2 mm3) differing in their chemical composition, residual monomer content, and molecular orientation. Copolymer samples with a higher lactic acid content showed a lower rate of absorption, whereas those with a higher unreacted monomer content were absorbed faster and showed a more drastic decrease in molecular weight. In contrast, degradation of the purified polymers was slow; the purified poly-L-lactide showed no weight change and a 50% reduction in molecular weight after 6 months of implantation. Scanning electron microscopy of the samples containing monomers showed a microporous structure extending from the surface to the inner region a few days after implantation, whereas the purified poly-L-lactide did not exhibit a microporous structural change even after 10 months of implantation.
    Additional Material: 14 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 14 (1980), S. 92-97 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sum-over-states perturbation and finite perturbation calculations, within the ‘Solvaton’ model, are presented for the variation of some 17O and 19F chemical shifts as a function of the dielectric constant of the medium. In general, the nuclear screening and charge are predicted to increase as the dielectric constant increases. The effects of hydrogen bonding are included by means of minimum energy dimer models in some of the sum-over-states calculations.
    Additional Material: 3 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 12 (1974), S. 221-224 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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