ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • General Chemistry  (16)
  • 36.40  (7)
  • 76.60.Es  (3)
  • 74.70.Vy  (2)
  • ATOMIC AND MOLECULAR PHYSICS  (2)
  • Biochemistry and Biotechnology  (2)
Collection
Keywords
Publisher
Years
  • 1
    facet.materialart.
    Unknown
    Transformation theory and translation factors in inelastic atomic collisions (1977)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: It is shown through the use of transformation theory that unique semiclassical atomic scattering states which obey the asymptotic conditions of formal scattering theory can be derived by transforming 'nontraveling' atomic states, ie., states whose coordinate variables are referred to a stationary origin, to frames at rest with respect to the incoming or outgoing particles. An overview of the problem of properly defining such scattering states is presented. The operator which carries out the necessary transformation from inertial to noninertial frames is derived and its properties are discussed. The relation of this transformation operator to the 'translation factor' discussed in the literature is presented. The application of this operator to transform the time-dependent Schroedinger equation from an inertial to a noninertial frame is presented and shown to introduce new terms in the resulting equation. The implications of these new terms to scattering problems are discussed.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Physical Review A - General Physics; vol. 15
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 2
    facet.materialart.
    Unknown
    Theory of inelastic ion-atom scattering at low and intermediate energies (1977)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: Ab initio calculations are presented of inelastic energy loss and ionization phenomena associated with Ar(+)-Ar collisions at small distances of closest approach and for laboratory collision energies ranging from several keV to several hundred keV. Outer-shell excitations are handled statistically; inner-shell excitations are calculated from the viewpoint of quasidiabatic molecular orbital promotion. Auger electron yield, average state of ionization, and average inelastic energy loss are calculated per collision as a function of distance of closest approach of the collision partners for several laboratory collision energies. Average charge-state probabilities per collision partner are calculated as a function of the average inelastic energy loss per atom. It is shown that the structure in the data is due to the underlying structure in the inner-shell independent-electron quasimolecular promotion probabilities.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Physical Review A - General Physics; vol. 15
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 3
    Electronic Resource
    Electronic Resource
    The relationship of Au55(PPh3)12Cl6 to colloidal gold (1989)
    Springer
    The European physical journal 12 (1989), S. 533-536 
    Details
    ISSN: 1434-6079
    Keywords: 33.20.K ; 35.20.G ; 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The electronic (UV-visible) spectrum of the molecular cluster Au55(PPh3)12Cl6 shows features corresponding to the 520 nm plasma resonance and the shorter-wavelength interband transition of colloidal gold. These absorptions differ qualitatively from the simpler one-electron transitions of lower-nuclearity cluster molecules. Differential scanning calorimetry has been used to measure the enthalpy of decomposition of Au55(PPh3)12Cl6. The Au-Au bonding appears to be substantially stronger than in bulk gold.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01427012
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    The electronic quantum size effect observed by195Pt NMR in the metal cluster compound Pt309Phen 36 * O30 (1993)
    Springer
    The European physical journal 26 (1993), S. 21-23 
    Details
    ISSN: 1434-6079
    Keywords: 74.30.Gn ; 74.70.Vy ; 76.60.Es
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 195Pt NMR on the organic ligand stabilized metal cluster compound Pt309Phen 36 * O30 reveals two separate peaks in the lineshape. Ligand-bonded platinum atoms at the surface of the core are thought to be responsible for the peak that does not show any Knight shift. The corresponding spin-lattice relaxation timeT 1 is of the order of seconds. The second peak is Knight shifted and is attributed to the other Pt atoms, for which metallic behavior is inferred from the temperature dependence ofT 1. The Korringa relation holds down to 65 K. Below 65 K the relaxation of the magnetization becomes increasingly non-exponential with decreasing temperature. The relaxation process can be successfully modelled under the assumption of a Poisson distribution of the energy levels around the Fermi energy (the electronic quantum size effect).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01425605
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    NMR of metal-core bonded31P in polynuclear metal cluster compounds (1989)
    Springer
    The European physical journal 12 (1989), S. 451-452 
    Details
    ISSN: 1434-6079
    Keywords: 76.60 ; 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In this paper we present measurements of nuclear relaxation times of31P in the polynuclear cluster compounds Au55(PPh3)12Cl6 and Ru55(P(t-Bu)3)12Cl20. Above 15 K the data can be described as a Korringa process, while below 15 K the relaxation time appears to be thermally activated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01426994
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Solid state magic angle spinning13C and31P NMR of organic ligand stabilized high nuclearity metal clusters (1993)
    Springer
    The European physical journal 26 (1993), S. 24-26 
    Details
    ISSN: 1434-6079
    Keywords: 74.30.Gn ; 74.70.Vy ; 76.60.Es
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 13C and31P solid state NMR measurements on the organic ligands in ligated Au55, Ni8, Pt309, Cu36 and Cu70 clusters are reported. The ligands behave like diamagnetic organic molecules, giving rise to relatively narrow lines with excellent cross-polarization efficiency. The resonance lines of the nuclei directly bound to the metal core are systematically broadened in the conducting compounds. No pronounced Knight shifts or evidence of metallic-like relaxation were observed. These results support a model for the electrical conduction involving tunneling between metal cores with the ligands playing the role of a tunneling barrier.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01425606
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    The optical extinction of ligand-stabilized Au13- and Au55-clusters: The vanishing of the Mie-resonance (1993)
    Springer
    The European physical journal 26 (1993), S. 1-3 
    Details
    ISSN: 1434-6079
    Keywords: 36.40 ; 33.20K
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present optical extinction spectra of ligand-stabilized Au-clusters AuN with sizes of N=13 and N=55. They are compared to larger, embedded clusters up to N=5·103 (diameter 5nm). The Mie resonance due to excitation of the dipole plasmon polariton vanishes with decreasing cluster size. For N〉55, this effect has recently been interpreted as caused by smearing out of the interband transition edge of Au.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01425599
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Physical properties of high-nuclearity metal cluster compounds (1989)
    Springer
    The European physical journal 12 (1989), S. 445-450 
    Details
    ISSN: 1434-6079
    Keywords: 36.40 ; 75.20
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Metal cluster compounds are composed of large macromolecules, which consist of a metal core (cluster) containing a certain number (n=6–560) of metal atoms, to which core a shell of ligands is coordinated. They provide excellent model systems for an assembly of identical metal clusters, embedded in a dielectric matrix. We discuss a number of physical properties of these materials.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01426993
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Optical properties of systems containing Au55-clusters (1989)
    Springer
    The European physical journal 12 (1989), S. 515-520 
    Details
    ISSN: 1434-6079
    Keywords: 33.20.K ; 36.40 ; 42.20 ; 78.40 ; 82.70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Gold cluster compounds were investigated which contain clusters of 55 gold atoms in each unit. The ligands stabilize these clusters and, hence, many-cluster systems can be prepared which mainly show the properties of the single dressed cluster. Experimental results of optical and electron-microscopical investigations are presented and shortly discussed in view of the question whether the clusters are molecular or solid-state like.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01427009
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Optical plasmon losses in stabilized Au55 clusters (1991)
    Springer
    The European physical journal 20 (1991), S. 297-300 
    Details
    ISSN: 1434-6079
    Keywords: 33.20.K ; 36.40 ; 42.20 ; 78.40 ; 82.70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Au55 cluster compounds are investigated by optical spectroscopy and TEM. The optical spectra appear to be rather structureless, neither showing a collective excitation resonance nor exhibiting distinct absorption bands known from lower nuclearity clusters. We discuss changes of the electronic properties compared to larger Au clusters affecting both, 6sp electrons and5d-6sp interband transitions, the cluster-ligand-interaction being considered as a charge transfer process. We additionally report on a low temperature instability of the cluster compound, which results in changed optical extinction spectra. A characteristic absorption feature at λ=400 nm is attributed to small, ligand-free Au cluster fragments.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01543995
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...