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  • 2021 Tajogaite eruption  (1)
  • Canary Islands  (1)
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  • 1
    Publication Date: 2023-11-16
    Description: The Canary Islands, in the eastern Atlantic, are among the most enigmatic Oceanic Island provinces on Earth, as the mantle source feeding its volcanism exhibits wide spatial heterogeneity and a multiplicity of sources. Multiisotope whole-rock studies have long revealed the presence of a recycled oceanic crust/lithosphere component in the mantle source. However, noble gas systematics have been more challenging to interpret, and the available carbon isotope data is limited and cannot support/dismiss this interpretation. Here, we present the very first isotopic characterisation of CO2 and noble gases (He-Ne-Ar) in fluid inclusions (FI) in minerals hosted in mantle xenoliths from El Hierro, the youngest and westernmost island of the Canary volcanic archipelago. Six fresh xenoliths from El Julan cliff valley were analysed (3 spinel lherzolites and 3 spinel harzburgites). We find carbon isotopic compositions of CO2 in FI (δ13C) ranging from 􀀀 2.38 to 􀀀 1.23‰ in pyroxenes and from 􀀀 0.19 to +0.96‰ in olivines. These unusually positive δ13C values, well above the typical mantle range (􀀀 8‰ 〈 δ13C 〈 􀀀 4‰), prove, for the first time, the presence of a recycled crustal carbon component in the local source mantle. We interpret this 13C-rich component as inherited from a mantle metasomatism event driven by fluids carrying carbon from C. In contrast, our El Hierro xenoliths identify a depleted mantle-like He signature, with an average Rc/Ra ratio (3He/4He normalised to air ratio and corrected for atmospheric contamination) of 7.45 ± 0.26 Ra. The involvement of depleted mantle-like fluids, variably admixed with air-derived components (possibly recycled via paleo-subduction event(s)), is corroborated by Ne-Ar isotopic compositions. The depleted mantle-like He signature suggests instead the involvement of a primordial He source in the local lithospheric mantle and indicates a marginal role played by past subduction events in modifying the local mantle He budget. When put in the context of previous 3He/4He measurements in FI and surface gases along the Canary archipelago, our results confirm an overall west-to-east decrease of Rc/Ra ratios, which may be interpreted as due to increasing contributions from the African sub-continental mantle, the addition of radiogenic 4He during magma migration in the oceanic crust (whose thickness increases eastward) and/or magma ageing.
    Description: Published
    Description: 106414
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Canary Islands ; El Hierro ; Mantle xenoliths ; Fluid inclusions ; Recycled carbon ; noble gases ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-05-06
    Description: Here, we characterize the temporal evolution of volatiles during the Tajogaite eruption by analyzing the elemental (He-Ar-CO2-N2) and isotopic (He-Ar-Ne) composition of fluid inclusions (FI) in phenocrysts (olivine+ pyroxene) identified in erupted lavas. Our 2021 lava samples identify substantial temporal variations in volatile composition. We show that, during the 2021 Tajogaite eruption, the He-CO2-N2 concentrations in FI increased since October 15th; this increase was accompanied by increasing 40Ar/36Ar ratios (from ~300 to 〉500), and paralleled a major shift in bulk lava chemistry, with increasing Mg contents (Mg#, from 47 to 52 to 55–59), CaO/Al2O3 (from 0.65 to 0.74 to 0.75–0.90), Ni and Cr, and decreasing TiO2, P2O5 and incompatible elements. The olivine core composition also became more forsteritic (from Mg# = 80–81 to Mg# = 84–86). Mineral thermobarometry and FI barometry results indicate that the eruption was sustained by magmas previously stored in at least two magma accumulation zones, at respectively ~6–12 km and 15–30 km, corroborating previous seismic and FI evidence. We therefore propose that the compositional changes seen throughout the eruption can be explained by an increased contribution - since early/mid-October - of more primitive, less degassed magma from the deeper (mantle) reservoir. Conversely, Rc/Ra values (3He/4He ratios corrected for atmospheric contamination) remained constant throughout the whole eruption at MORB-like values (7.38 ± 0.22 Ra, 1σ), suggesting an isotopically homogeneous magma feeding source. The Tajogaite He isotope signature is within the range of values observed for the 1677 San Antonio lavas (7.37 ± 0.17Ra, 1σ), but is more radiogenic than the 3He/4He values (〉9 Rc/Ra) observed in the Caldera de Taburiente to the north. The 3He/4He ratios (6.75 ± 0.20 Ra, 1σ) measured in mantle xenoliths from the San Antonio volcano indicate a relatively radiogenic nature of the mantle beneath the Cumbre Vieja ridge. Based on these results and mixing modeling calculations, we propose that the homogeneous He isotopic signatures observed in volatiles from the Tajogaite/San Antonio lavas reflect three component mixing between a MORB-like source, a radiogenic component and small additions (6–15%) of a high 3He/4He reservoir-derived (〉9Ra) fluid components. The simultaneous occurrence of high 3He/4He (〉9Ra)- and MORB-like He signatures in northern and southern La Palma is interpreted to reflect small-scale heterogeneities in the local mantle, arising from spatially variable proportions of MORB, radiogenic, and high 3He/4He components.
    Description: Published
    Description: 107928
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: La Palma ; 2021 Tajogaite eruption ; Fluid inclusions ; Noble gas ; Magma feeding system ; Mantle source heterogeneity ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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