ISSN:
1572-8927
Keywords:
Excess molar volume
;
diethyl carbonate
;
n-heptane
;
n-decane
;
n-tetradecane
;
2,2,4-trimethylpentane
;
cyclohexane
;
benzene
;
toluene
;
tetrachloromethane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The excess molar volumes V m E at atmospheric pressure and at 25°C for binary mixtures of diethyl carbonate with n-heptane, n-decane, n-tetradecane, 2,2,4-trimethylpentane, cyclohexane, benzene, toluene, or tetrachloromethane have been obtained over the whole mole-fraction range from densities measured with a vibrating-tube densimeter. The V m E are positive for all the systems investigated, except for the mixture with toluene which is negative. The results for V m E together with data previously published on excess molar enthalpies H m E and excess molar Gibbs energies G m E , suggest interactions between carbonate and hydrocarbons which are stronger with aromatic than with aliphatic hydrocarbons.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01131047
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