ALBERT

Description: Contourites in the Gulf of Cádiz preserve a unique archive of Mediterranean Outflow Water (MOW) variability over the past 5.3 Ma. In our study we investigate the potential of geochemical data obtained by XRF scanning to decipher bottom current processes and paleoclimatic evolution at two different sites drilled through contourite deposits in the northern Gulf of Cadiz: Site U1387, which is bathed by the upper MOW core, and Site U1389, located more proximal to the Straits of Gibraltar. The lack of major downslope transport at both locations during the Pleistocene makes them ideal locations for the purpose of our study. The results indicate that the Zr/Al ratio, representing the relative enrichment of heavy minerals (zircon) over less dense alumosilicates under strong bottom current flow, is the most useful indicator for a semi-quantitative assessment of current strength. While most elements are biased by current-related processes, the bromine record, representing organic content, preserves the most pristine climate signal rather independent of grain size changes. Hence, Br can be used for chronostratigraphy and site-to-site correlation in addition to stable isotope stratigraphy. Based on these findings we reconstructed MOW variability for Marine Isotope Stages 1-5 using the Zr/Al ratio from Site U1387. The results reveal abrupt, millennial-scale variations of MOW strength during Greenland Stadials (GS) and Interstadials (GI) with strong MOW during GS and glacial Terminations and a complex behavior during Heinrich Stadials. Millennial-scale variability persisting during periods of poorly expressed GS/GI cyclicities implies a strong internal oscillation of the Mediterranean/North Atlantic climate system.

Description: We produced a composite depth scale and chronology for Site U1385 on the SW Iberian Margin. Using log(Ca/Ti) measured by core scanning XRF at 1-cm resolution in all holes, a composite section was constructed to 166.5 meter composite depth (mcd) that corrects for stretching and squeezing in each core. Oxygen isotopes of benthic foraminifera were correlated to a stacked d18O reference signal (LR04) to produce an oxygen isotope stratigraphy and age model. Variations in sediment color contain very strong precession signals at Site U1385, and the amplitude modulation of these cycles provides a powerful tool for developing an orbitally-tuned age model. We tuned the U1385 record by correlating peaks in L* to the local summer insolation maxima at 37°N. The benthic d18O record of Site U1385, when placed on the tuned age model, generally agrees with other time scales within their respective chronologic uncertainties. The age model is transferred to down-core data to produce a continuous time series of log(Ca/Ti) that reflect relative changes of biogenic carbonate and detrital sediment. Biogenic carbonate increases during interglacial and interstadial climate states and decreases during glacial and stadial periods. Much of the variance in the log(Ca/Ti) is explained by a linear combination of orbital frequencies (precession, tilt and eccentricity), whereas the residual signal reflects suborbital climate variability. The strong correlation between suborbital log(Ca/Ti) variability and Greenland temperature over the last glacial cycle at Site U1385 suggests that this signal can be used as a proxy for millennial-scale climate variability over the past 1.5 Ma. Millennial climate variability, as expressed by log(Ca/Ti) at Site U1385, was a persistent feature of glacial climates over the past 1.5 Ma, including glacial periods of the early Pleistocene ('41-kyr world') when boundary conditions differed significantly from those of the late Pleistocene ('100-kyr world'). Suborbital variability was suppressed during interglacial stages and enhanced during glacial periods, especially when benthic d18O surpassed ~ 3.3?3.5?. Each glacial inception was marked by appearance of strong millennial variability and each deglaciation was preceded by a terminal stadial event. Suborbital variability may be a symptomatic feature of glacial climate or, alternatively, may play a more active role in the inception and/or termination of glacial cycles.

Description: During the latest Messinian, hemipelagic sediments exhibiting precession-induced climate variability were deposited. These are overlain by Pliocene sediments deposited at a much higher sedimentation rate, with much higher and more variable XRF-scanning Zr/Al ratios than the underlying sediment, and that show evidence of winnowing, particle sorting and increasing grain size, which we interpret to be related to the increasing flow of MOW. Pliocene sedimentary cyclicity is clearly visible in both the benthic d18O record and the Zr/Al data and is probably also precessionally controlled. On the basis of these results, we conclude that contouritic sedimentation, associated with weak Mediterranean-Atlantic exchange, began in the Gulf of Cadiz virtually at or shortly after the Miocene-Pliocene boundary, with two contouritic bigradational sandy-beds within the fourth precession cycle after the Miocene-Pliocene boundary.

Description: Listed are edited, spliced, and in situ corrected data vs. various depth scales, the shipboard age scale and two-way-traveltime (TWT). The shipboard age model for Site U1475 was derived from time estimates based on a combination of major planktonic foraminifer, calcareous nanno-plankton, diatom, and paleomagnetic datums. K (wt.%) is derived from measurements of natural gamma radiation (NGR) according to De Vleeschouwer, D., Dunlea, A. G., Auer, G., Anderson, C. H., Brumsack, H., de Loach, A., et al. (2017). Quantifying K, U, and Th contents of marine sediments using shipboard natural gamma radiation spectra measured on DVJOIDESResolution. Geochemistry, Geophysics, Geosystems, 18(3), 1053-1064, doi:10.1002/2016GC006715. Description of the depth scales: The CSF-A scale (here DEPTH, sediment/rock) is specific to each hole of a site and combines the drilling depth below seafloor of the core top depth and the curated depth within a core after retrieval. The CSF-A depth scale is equivalent to the meters below seafloor (mbsf) scale known from, e.g., the Ocean Drilling Program (ODP). For the construction of the most representative single continuous sedimentary section, intervals from multiple holes need to be spliced together. This requires a common, composite depth scale (CCSF, formerly known as mcd) for a given IODP Site which is based on the correlation of coeval, laterally continuous features seen in the physical properties in all drilled holes (which will generally occur at different depths on the CSF-A depth scales for each hole). Once such correlative features (tie-points) were identified at Site U1475 the depth of individual cores was offset relative to CSF-A in that hole, resulting in the Composite Curated depth below Sea Floor (CCSF-A) depth scale (here Depth composite) for each hole. By combining selected intervals from Holes U1475B, C, E and F between the previously established tie points a complete stratigraphic section (splice) was constructed. The designated depth scale of the splice is the CCSF-D scale. CCSF-D applies only to intervals included in the splice and intervals not included in the primary splice retain the CCSF-A scale. The CCSF-A scale does not result in alignment of all coeval features because of the differing effects of coring-induced stretching and squeezing among cores, as well as sedimentological differences between holes. For our study it was desirable to map into the splice those intervals not included in the splice itself. We accomplished this by simultaneously comparing color reflectance (b*) and NGR for all holes with subsequent identification of correlative tie points at the highest possible resolution and linear adjustments of depths between ties. This adjusted depth is designated as the CCSF-C depth scale (here Depth composite revised), and to the extent that the correlations are accurate, the CCSF-C and CCSF-D scales are equivalent. CCSF-C and -D typically exceed the in situ depth (core depth below sea floor CSF-A) by ~10%. The growth rate of the CCSF-D depth scale, relative to CSF-A is on average 9.5% for all holes. Thus to correct for the depth offset a linear compression - Depth (m CCSF-B) = Depth (m CCSF-C)/1.095 - was applied to the entire depth so that the compressed core length was equal to the interval cored. The CCSF-B scale (here Depth composite corrected) hence indicates the in situ depth in meters below the seafloor (mbsf).

Description: Centennial-to-millennial scale records from IODP Site U1387, drilled during IODP Expedition 339 into the Faro Drift at 558 m water depth, now allow evaluating the climatic history of the upper core of the Mediterranean Outflow (MOW) and of the surface waters in the northern Gulf of Cadiz during the early Pleistocene. This study focuses on the period from Marine Isotope Stage (MIS) 29 to 34, i.e. the interval surrounding extreme interglacial MIS 31. Conditions in the upper MOW reflect obliquity, precession and millennial-scale variations. The benthic d18O signal follows obliquity with the exception of an additional, smaller d18O peak that marks the MIS 32/31 transition. Insolation maxima (precession minima) led to poor ventilation and a sluggish upper MOW core, whereas insolation minima were associated with enhanced ventilation and often also increased bottom current velocity. Millennial-scale periods of colder sea-surface temperatures (SST) were associated with short-term maxima in flow velocity and better ventilation, reminiscent of conditions known from MIS 3. A prominent contourite layer, coinciding with insolation cycle 100, was formed during MIS 31 and represents one of the few contourites developing within an interglacial period. MIS 31 surface water conditions were characterized by an extended period (1065-1091 ka) of warm SST, but SST were not much warmer than during MIS 33. Interglacial to glacial transitions experienced 2 to 3 stadial/interstadial cycles, just like their mid-to-late Pleistocene counterparts. Glacial MIS 30 and 32 recorded periods of extremely cold (〈 12°C) SST that in their climatic impact were comparable to the Heinrich events of the mid and late Pleistocene. Glacial MIS 34, on the other hand, was a relative warm glacial period off southern Portugal. Overall, surface water and MOW conditions at Site U1387 show strong congruence with Mediterranean climate, whereas millennial-scale variations are closely linked to North Atlantic circulation changes.

Description: Warm intervals within the Pliocene epoch (5.33-2.58 million years ago) were characterized by global temperatures comparable to those predicted for the end of this century (Haywood and Valdes, doi:10.1016/S0012-821X(03)00685-X) and atmospheric CO2 concentrations similar to today (Seki et al., 2010, doi:10.1016/j.epsl.2010.01.037; Bartoli et al., 2011, doi:10.1029/2010PA002055; Pagani et al., 2010, doi:10.1038/ngeo724). Estimates for global sea level highstands during these times (Miller et al., 2012, doi:10.1130/G32869.1) imply possible retreat of the East Antarctic ice sheet, but ice-proximal evidence from the Antarctic margin is scarce. Here we present new data from Pliocene marine sediments recovered offshore of Adélie Land, East Antarctica, that reveal dynamic behaviour of the East Antarctic ice sheet in the vicinity of the low-lying Wilkes Subglacial Basin during times of past climatic warmth. Sedimentary sequences deposited between 5.3 and 3.3 million years ago indicate increases in Southern Ocean surface water productivity, associated with elevated circum-Antarctic temperatures. The geochemical provenance of detrital material deposited during these warm intervals suggests active erosion of continental bedrock from within the Wilkes Subglacial Basin, an area today buried beneath the East Antarctic ice sheet. We interpret this erosion to be associated with retreat of the ice sheet margin several hundreds of kilometres inland and conclude that the East Antarctic ice sheet was sensitive to climatic warmth during the Pliocene.

Description: The Integrated Ocean Drilling Program Expedition 318 to the Wilkes Land margin of Antarctica recovered a sedimentary succession ranging in age from lower Eocene to the Holocene. Excellent stratigraphic control is key to understanding the timing of paleoceanographic events through critical climate intervals. Drill sites recovered the lower and middle Eocene, nearly the entire Oligocene, the Miocene from about 17 Ma, the entire Pliocene and much of the Pleistocene. The paleomagnetic properties are generally suitable for magnetostratigraphic interpretation, with well-behaved demagnetization diagrams, uniform distribution of declinations, and a clear separation into two inclination modes. Although the sequences were discontinuously recovered with many gaps due to coring, and there are hiatuses from sedimentary and tectonic processes, the magnetostratigraphic patterns are in general readily interpretable. Our interpretations are integrated with the diatom, radiolarian, calcareous nannofossils and dinoflagellate cyst (dinocyst) biostratigraphy. The magnetostratigraphy significantly improves the resolution of the chronostratigraphy, particularly in intervals with poor biostratigraphic control. However, Southern Ocean records with reliable magnetostratigraphies are notably scarce, and the data reported here provide an opportunity for improved calibration of the biostratigraphic records. In particular, we provide a rare magnetostratigraphic calibration for dinocyst biostratigraphy in the Paleogene and a substantially improved diatom calibration for the Pliocene. This paper presents the stratigraphic framework for future paleoceanographic proxy records which are being developed for the Wilkes Land margin cores. It further provides tight constraints on the duration of regional hiatuses inferred from seismic surveys of the region.

Description: Marine sediments from the western Indian Ocean are potentially an ideal archive for monitoring local changes in the Southern African Monsoon (SAFM) as riverine discharge fluctuations are controlled by monsoon precipitation linked to the Intertropical Convergence Zone movement. Regarding the pottential role played by the SAFM in climate systems from latest Miocene to early Pliocene, we reconstructed this monsoonal system based on elemental geochemistry (Ca/Ti and Si/K ratios), stable isotope geochemistry (δ18O and δ13C recorded in the planktonic foraminifera Orbulina universa), and marine sediment grain size data from the International Ocean Discovery Program Site U1476. Here we demonstrated that precession cycles governed precipitation from 7.4 to ~6.9 Ma and during the early Pliocene. From ~6.9 to 5.9 Ma, the precession and long eccentricity cycles drove the SAFM. The major Antarctic ice sheet expansion across this interval appear to influence the isotopic records of Orbulina universa imprinting its long-term variability signal as a response to the ocean and atmospheric reorganization. Precession cycles markedly weakened from 5.9 to 5.3 Ma, almost the same period when the Mediterranean Outflow Water ceased. These findings highlight important teleconnections among the SAFM, Mediterranean Sea, and other tropical regions.