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  • Capillary columns  (2)
  • 05.09. Miscellaneous  (1)
  • 35  (1)
  • 1
    ISSN: 1432-0649
    Keywords: 32 ; 35 ; 42.65 ; 32 ; 33 ; 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Simulated distillation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The characterization of heavy petroleum fractions is essential for the design and improvement of cracking plants converting heavy feedstock into valuable “white” products. Conventional simulated distillation methods using packed columns are unsuitable for this purposes, being limited to boiling points up to about 600°C. The method presented is able to cover a boiling points interval ranging from about 150°C up to around 800°C. It employs a short, nonpolar, highly thermostable capillary column routinely operated at temperatures around 430°C. The analytical system is based on a high temperature versions of a fully automatic, capillary dedicated gas chromatograph. The experimental data demonstrate that cold on-column injection is the sole sampling system suitable for such heavy compounds. The conversion of the retention times into boiling points, based on the use of low molecular weight polyethylenes, is extremely reliable, as demonstrated by the excellent retention time reproducibilities. The lower part (up to 550-600°C TBP) of the boiling point distribution curves of heavy petroleum fractions obtained on capillary columns fits well with the corresponding distribution curves based on packed column data. For the petroleum fractions fully eluted from the column the quantitative results obtained either using internal standards or by direct processing of the elution curves are in excellent agreement (less than 0.3 weight% differences). The method has been applied to the determination of the true boiling points corresponding to short path vacuum distillation (DISTACT) cut points over 300°C.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 484-486 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Capillary columns ; Polyolefins ; Antioxidants ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2024-05-09
    Description: The Cerro Blanco Caldera (CBC) is the youngest collapse caldera system in the Southern Central Andes (Southern Puna, Argentina). The CBC is subsiding with at an average velocity of 0.87 cm/year and hosts an active geothermal system. A geochemical characterization of emitted fluids was carried out based on the chemical and isotopic compositions of fumaroles, and thermal and cold springs discharged in this volcanic area with the aim of constructing the first hydrogeochemical conceptual model and preliminary estimate the geothermal potential. The main hydrothermal reservoir, likely hosted within the pre-caldera basement rocks, has a Na+-Clˉ(HCO3)ˉ composition with estimated temperatures ≥135 °C. The unconsolidated, fine-grained Cerro Blanco ignimbrite likely acts as the cap-rock of the hydrothermal system. The presence of phreatic eruption breccias in the surrounding area of the geothermal fumaroles supports the effectiveness of the pyroclastic deposit as sealing rocks. The isotopic data of water (δ18O and δD) indicate a meteoric recharge of the hydrothermal reservoir, suggesting as recharge areas the sectors surrounding the CBC, mainly towards the W and NW where large outcrops of the pre-caldera basement exist. A fault-controlled hydraulic connection between the hot springs and the hydrothermal reservoir is proposed for the Los Hornitos area. The fumaroles show the typical compositional features of hydrothermal fluids, being dominated by water vapor with significant concentrations of H2S, CH4 and H2. Considering the high geothermal gradient of this area (∼104 °C/km) and the relatively high fraction of mantle He (∼39%) calculated on the basis of the measured R/Ra values, the hydrothermal aquifer likely receives inputs of magmatic fluids from the degassing magma chamber. The preliminary geothermal potential at CBC was evaluated with the Volume Method, calculating up to E = 11.4*1018 J. Both the scarce presence of superficial thermal manifestations and the occurrence of an efficient cap-rock likely contribute to minimize the loss of thermal energy from the reservoir. The results here presented constitute the necessary base of knowledge for further accurate assessment of the geothermal potential and ultimately the implementation of the geothermal resource as a viable energy alternative for small localities or mining facilities isolated from the National Interconnected System due to their remote localization.
    Description: Published
    Description: 102213
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrothermal system ; Fluid geochemistry ; Geothermal prospection ; Quaternary caldera ; Northwestern Argentina ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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