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  • 1
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    The 3He/4He Halo of the Kazbek Volcanic Center, Northern Caucasus (2008)
    Pleiades Publishing
    Details
    Publication Date: 2017-04-04
    Description: Manifestations of recent volcanism in the Greater Caucasus are grouped in the El’brus and Kazbek volcanic areas [1]. The last episodes of activity in the majority of their eruptive centers date back to the Late Holocene or even first centuries of the recent era (El’brus Volcano) [2]. This implies potential volcanic hazards in the Greater Caucasus. Therefore, it is important to outline contours of this potentially hazardous region with the maximal possible accuracy. The region is characterized by indications of geodynamic stress, such as recent eruptions, crustal deformations, seismic activity, geothermal anomalies, and others. The 3He/4He value in natural gases can serve as one of such indications.
    Description: Published
    Description: 605–608
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: helium isotopes ; Kazbek ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Changes in fluid geochemistry and physico-chemical conditions of geothermal systems caused by magmatic input: The recent abrupt outgassing off the island of Panarea (Aeolian Islands, Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Hydrothermal systems and related vents can exhibit dramatic changes in their physico-chemical conditions over time as a response to varying activity in the feeding magmatic systems. Massive steam condensation and gas scrubbing processes of thermal fluids during their ascent and cooling cause further compositional changes that mask information regarding the conditions evolving at depth in the hydrothermal system. Here we propose a new stability diagram based on the CO2-CH4-CO-H2 concentrations in vapor, which aims at calculating the temperatures and pressures in hydrothermal reservoirs. To filter gas scrubbing effects, we have also developed a model for selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air-saturated seawater. This methodology has been applied to the recent (November 2002) crisis that affected the geothermal field off the island of Panarea (Italy), where the fluid composition and fluxes have been monitored for the past two decades. The chemical and isotopic compositions of the gases suggest that the volatile elements originate from an active magma, which feeds a boiling saline solution having temperatures of up to 350 C and containing 12 mol CO2 in vapor. The thermal fluids undergo cooling and re-equilibration processes on account of gas-water-rock interactions during their ascent along fracture networks. Furthermore, steam condensation and removal of acidic species, partial dissolution in cold air-saturated seawater and stripping of atmospheric components, affect the composition of the geothermal gases at shallow levels. The observed geochemical variations are consistent with a new input of magmatic fluids that perturbed the geothermal system and caused the unrest event. The present-state evolution shows that this dramatic input of fluids is probably over, and that the system is now tending towards steady-state conditions on a time scale of months.
    Description: Published
    Description: 3045-3059
    Description: partially_open
    Keywords: Submarine degassing ; geothermal system ; gas-water interaction ; gas geothermometry ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 627284 bytes
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  • 3
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    CO2 Degassing over Seismic Areas: The Role of Mechanochemical Production at the Study Case of Central Apennines (2008)
    Birkhauser Verlag
    Details
    Publication Date: 2017-04-03
    Description: Field observations coupled with experimental results show that CO2 can be produced by mechanical energy applied to carbonate rocks becoming an unexpected additional gas source besides that degassed from the mantle or produced by thermometamorphism. The evidence that a large amount of carbon dioxide associated with radiogenic-type helium (R/Ra as low as 0.01–0.08) is released through continental areas, denotes the absence of a contribution from the mantle or from mantle-derived fluids. Data collected during the seismic crisis which struck the Central Apennines in 1997–98 have shown an enhanced CO2 flux not associated with the presence of mantle or thermometamorphic-derived fluids. On the other hand, new experimental results highlight the possibility of producing CO2 by mechanical energy that acts on the calcite crystalline lattice. While the CO2 released over the geothermal areas (e.g., Larderello Geothermal Field) is obviously derived by mantlederived activities, this is not the case of the huge amount of CO2 released over the seismically active areas where the presence mantle-derived products is ruled out. We propose that mechanical energy, e.g., released during seismic events, microseismicity or creeping processes is a possible additional energy source able to produce CO2 and thus could explain the presence of CO2 degassing over tectonic areas where the influence of the mantle is low. 1. Introduction Apart from the water va
    Description: Published
    Description: 75–94
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Isotope ; Geochemistry ; seismicity ; CO2 production ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Geochemical evidence of seismogenic-induced anomalies in the dissolved gases of thermal waters: A case study of Umbria (Central Apennines, Italy) both during and after the 1997-1998 seismic swarm (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: In this paper we present the first geochemical data set regarding long-term monitoring of dissolved gases in thermal waters from a seismic area. Three sites in Umbria (Central Apennines, Italy) were studied both for the chemical and for the helium isotopic composition of the dissolved gases. Data were collected during and after the seismic crisis that struck the region in 1997â 1998. The chemical composition of the dissolved gases revealed that a CO2-rich gas phase was always mixed with an atmospheric-derived component dominated by N2. A normal faulting marked the beginning of the seismic activity enhancing the release of CO2 on a regional scale. Variations in both the chemical and isotopic compositions of the dissolved gases were also observed as preseismic, synseismic, and postseismic phenomena related to the seismic shock of March 1998. Those geochemical modifications were interpreted as being the consequence of a drop in the CO2 degassing rate, in good agreement with the compressive focal mechanism of that seismic event. Furthermore, this interpretation was also consistent with the geologic and tectonic setting of the study area and induced us to postulate that changes in the local rock permeability, due to crustal deformations (i.e., coseismic deformation and postseismic release), were responsible for the geochemical modifications observed. On the basis of the foregoing, we have concluded that the geochemistry of dissolved gases in groundwaters represents a useful tool for the investigation of the relationships between circulating fluids and seismic activity.
    Description: Published
    Description: partially_open
    Keywords: dissolved gases ; geochemistry ; seismic areas ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 503 bytes
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  • 5
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    Gas flow anomalies in seismogenic zones in the Upper Tiber Valley, Central Italy (2007)
    Details
    Publication Date: 2017-04-04
    Description: Cold CO2 gas emission sites in rainwater-filled pools, so called mofettes, are widely distributed all over Italy. Their gas reservoirs, mostly having a high CO2 content, have a magmatic and/or metamorphic origin. Temporal variations in fluid expulsions were observed at the mofettes of Caprese Michelangelo during the period from 2002 to 2005. These observations were made possible by using a new approach: photographic time-series. A first interpretation of these fluid expulsionswas based on meteorological/hydrogeological explanations.However, our long-term observations show that these processes may merely be a side effect. The probable main reason for the anomalous emissions is the long-term variation in the long-distance fluid transport process from the reservoir induced by the local tectonic settings. In the northern part of the Alto Tiberina Fault, a fault intersection was reactivated by a seismic sequence which started on 2001 November 26, and continued for approximately four months. The magnitude of the main shock was MW = 4.6. As revealed by the drilling of a deep borehole, dug in the direct vicinity, overpressurized fluids trapped at a depth of 3700 m could be activated as a consequence of the improved transport conditions, that is, the fracture apertures that materialized as a result of the rupture process. A migration of the hypocentres towards the surface provides hints of a possible pore pressure diffusion process. The consequence is an increased fluid transport to the mofettes. The first indications of anomalous fluid expulsions at the mofettes of Caprese Michelangelo were detected 18 months after the seismic events.
    Description: Published
    Description: 794-806
    Description: JCR Journal
    Description: reserved
    Keywords: earthquakes ; fluid dynamics ; hydrodynamics ; microearthquakes ; pore pressure diffusion ; seismotectonics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Evidence of a recent input of magmatic gases into the quiescent volcanic edifice of Panarea, Aeolian Islands, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 503 bytes
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  • 7
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    Insights into mantle-type volatiles contribution from dissolved gases in artesian waters of the Great Artesian Basin, Australia (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The geochemical features of the volatiles dissolved in artesian thermal waters discharged over three basins (Millungera, Galilee and Cooper basin) of the Australian Great Artesian Basin (GAB) consistently indicate the presence of fluids from multiple gas sources located in the crust (e.g. sediments, oil reservoirs, granites) as well as minor but detectable contributions of mantle/magma-derived fluids. The gases extracted from 19 water samples and analyzed for their chemical and isotopic composition exhibit amounts of CO2 up to about 340 mlSTP/LH2O marked by a δ13CTDC (Total Dissolved Carbon) ranging from −16.9 to +0.18‰ vs PDB, while CH4 concentrations vary from 4.4 × 10−5 to 4.9 mlSTP/LH2O. Helium contents were between 9 and N2800 times higher than equilibrium with Air Saturated Water (ASW), with a maximum value of 0.12 mlSTP/LH2O. Helium isotopic composition was in the 0.02–0.21 Ra range (Ra = air-normalized 3He/4He ratio). The three investigated basins differ from each other in terms of both chemical composition and isotopic signatures of the dissolved gases whose origin is attributed to both mantle and crustal volatiles. Mantle He is present in the west-central and hottest part of the GAB despite no evidence of recent volcanism.Wefound that the partial pressure of helium, significantly higher in crustal fluids than in mantle-type volatiles, enhances the crustal He signature in the dissolved gases, thus masking the original mantle contribution. Neotectonic activity involving deep lithospheric structures and magma intrusions, highlighted by recent geophysical investigations, is considered to be the drivers of mantle/magmatic volatiles towards the surface. The results, although pertaining to artesian waters froma vast area of N542,000 km2, provide newconstraints on volatile injection, and showthat fluids' geochemistry can provide additional and independent information on the geo-tectonic settings of the Great Artesian Basin and its geothermal potential.
    Description: Published
    Description: 75-88
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: dissolved gases ; great artesian basin ; mantle fluids ; tectonic structures ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    The Benthic Boundary Layer: geochemical and oceanographic data from the GEOSTAR-2 observatory (2006)
    Details
    Publication Date: 2019-11-04
    Description: Geochemical and oceanographic data, acquired throughout 6 months by the GEOSTAR-2 benthic observatory in southern Tyrrhenian Sea, evidenced ocean-lithosphere interactions in the 1900-m deep Benthic Boundary Layer (BBL), distinguishing two water masses with different origin and, possibly, benthic residence time. Gas concentration, helium isotopic ratios, radioactivity, temperature, salinity and vertical component of the current converged towards the indication of a BBL characterised by a colder and fresher western water (WW), which is episodically displaced by the cascading of the warmer and saltier Eastern Overflow Water (EOW). The benthic WW has higher concentration of geochemical tracers diffusing from the seafloor sediments. The data set shows the potential of long-term, continuous and multiparametric monitoring in providing unique information which cannot be acquired by traditional, short-term or single-sensor investigations.
    Description: JCR Journal
    Description: open
    Keywords: geochemical data ; oceanographic data ; Benthic Boundary Layer ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 287653 bytes
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