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  • 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring  (3)
  • Mercury  (1)
  • 1
    Publication Date: 2021-04-07
    Description: We present the results of a study of volcanic gases at Soufrière Hills Volcano, Montserrat, which includes the first spectroscopic measurements of the major gas species CO2 and H2S at this volcano using a Multisensor Gas Analyzer System (MultiGAS) sensor. The fluxes of CO2 and H2S were 640–2750 t/d and 84–266 t/d, respectively, during July 2008, during a prolonged eruptive pause. The flux of CO2 is similar to estimates for the entire arc from previous geochemical studies, while the measured H2S flux significantly alters our interpretation of the sulphur budget for this volcano. The fluxes of both sulphur and carbon show considerable excesses over that which can be supplied by degassing of erupted magma. We demonstrate, using thermodynamic models and published constraints on preeruptive volatile concentrations, that the gas composition and fluxes are best modeled by mixing between (1) gases derived from isobaric quenching of mafic magma against cooler andesite magma at depth and (2) gases derived from shallower rhyolitic interstitial melt within the porpyritic andesite. The escape of deep‐derived gases requires pervasive permeability or vapor advection extending to several kilometers depth in the conduit and magma storage system. These results provide more compelling evidence for both the contribution of unerupted mafic magma to the volatile budget of this andesitic arc volcano and the importance of the intruding mafic magma in sustaining the eruption. From a broader perspective, this study illustrates the importance and role of underplating mafic magmas in arc settings. These magmas play an important role in triggering and sustaining eruptions and contribute in a highly significant way to the volatile budget of arc volcanoes.
    Description: Published
    Description: Q04005
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: magma degassing ; thermodynamics ; volcanic gases ; Soufriere Hills ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Measuring Hg/SO2 ratios in volcanic emissions is essential for better apportioning the volcanic contribution to the global Hg atmospheric cycle. Here, we report the first real-time simultaneous measurement Hg and SO2 in a volcanic plume, based on Lumex and MultiGAS techniques, respectively. We demonstrate that the use of these novel techniques allows the measurements of Hg/SO2 ratios with a far better time resolution than possible with more conventional methods. The Hg/SO2 ratios in the plume of F0 fumarole on La Fossa Crater, Vulcano Island spanned an order of magnitude over a 30 minute monitoring period, but was on average in qualitative agreement with the Hg/SO2 ratio directly measured in the fumarole (mean plume and fumarole ratios being 1.09 x 10-6 and 2.9 x 10-6, respectively). The factor 2 difference between plume and fumarole compositions provides evidence for fast Hg chemical processing the plume.
    Description: Published
    Description: L21307
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: partially_open
    Keywords: Mercury ; Fumarolic condensates ; Volcanic emissions ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2012-02-03
    Description: We present results from a campaign in March 2009 to assess the current state of emissions from Masaya Volcano, Nicaragua. These results constitute one of the most comprehensive inventories to date of emissions from an active volcano and update the exceptional record of emissions from Masaya. Results from open‐path Fourier transform infrared spectroscopy and filter packs demonstrate that, in terms of H2O, SO2,CO2, HCl,and HF (molar H2O/SO2 = 63, CO2/SO2 = 2.7, SO2/HCl = 1.7, SO2/HF = 8.8), the 2009 gas composition was highly comparable to that from the 1998 to 2000 period,indicating stability of the shallow magma system. This continuity extends to certain aerosol species (molar SO2/SO42−= 190, Na+ /SO4 2−= 0.68, K+/SO4 2−= 0.71, Ca 2+/SO4 2−= 1.6 × 10−2,Mg2+/SO4 2− = 3.6 × 10−3) and, to a lesser extent, the heavy halogens (i.e., molar HCl/HBr = 2.4 × 103 , HCl/HI = 5.0 × 104). In contrast to an arlier study at Masaya, we did not detect HNO3.SO2 fluxes were low (690 Mg d−1 ), suggesting that Masaya was close to the minimum of its degassing cycle. By combining compositional results with the SO2 flux, we estimate a total volatile flux of 14,000 Mg d−1. This rate is consistent with 1−4 wt% volatile loss from a convective magma flux of 17,000–4000 kg s−1. These results will allow for a better understanding of degassing processes at Masaya and other basaltic volcanoes
    Description: NERC project “Magma dynamics at persistently degassing basaltic volcanoes: A novel approach to linking volcanic gases and magmatic volatiles within a physical model” (NE/F004222/1 and NE/F005342/1).
    Description: Published
    Description: B09215
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Masaya Volcano ; Degassing regime ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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