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  • Chemistry  (110)
  • negative thermal ionization mass spectrometry  (2)
  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks  (1)
  • 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous  (1)
  • Vereshchagin Long Cores Expedition 2001
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  • 1
    Publication Date: 2021-06-16
    Description: Assessing the residence times of phonolite magmas in the shallow crust contributes to the understanding of explosive volcanic systems. Estimations of that by dating the residence time of a mineral in a melt was difficult in the past, because e.g. of the lack of evidence for the co-genetic character of the crystals dated. Here we present an estimate for the residence time of a phonolite magma feeding the Pomici di Mercato Plinian eruption (8890±90 cal years BP) of Mt. Somma-Vesuvius (Southern Italy), employing U–Th disequilibrium dating of unzoned Ca-rich phenocrystic magmatic garnets. Based on combined textural, geochemical, and Sr- O isotope evidence, these garnets can be identified as co-genetic with their host phonolites. Furthermore, experimental and petrological data suggest that Ca-garnets can be a liquidus phase in highly differentiated phonolite magmas of Mercato. A whole-rock–glass–garnet U–Th isochron gives a crystallisation age for the Ca-rich garnets of 14,400±1100 a (2σ). This implies a Ca-garnet residence time of 5510±1100 years (2σ) in the Mercato phonolite melt prior to eruption and provides one of the first robust estimates of how long explosive phonolite magma has resided in the shallow crust before eruption. Calculations of magma cooling rates and settling velocities of the Ca-garnets confirm that garnet-bearing phonolite can remain liquid and the garnets remain suspended in a magma chamber for as long as 5510 years before the time of eruption. Processes which may have disturbed the U–Th isotope systematic of the samples, such as assimilation, recharge or surface alteration can be ruled out.
    Description: Published
    Description: 293-301
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Uranium ; Thorium ; U–Th isotopes ; Somma-Vesuvius ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: New Sr and Nd isotope data for whole rocks, glasses and minerals are combined to reconstruct the nature and origin of mixing end-members of the 200 km3 trachytic to phonolitic Campanian Ignimbrite (Campi Flegrei, Italy) magmatic system. The least-evolved magmatic end-member shows equilibrium between host glass and the majority of the phenocrysts and is less radiogenic in Sr and Nd than the most-evolved magma. On the contrary, only the Fe-rich pyroxene from the most-evolved erupted magma is in equilibrium with the matrix glass, while all other minerals are in isotopic disequilibrium. These magmas mixed prior to and during the Campanian Ignimbrite eruption and minerals were freely exchanged between the magma batches. Combining the results of the geochemical investigations on magma end-members with geophysical and geological data, we develop the following scenario. In stage 1, a parental, less differentiated magma rose into the middle crust, and evolved through combined crustal assimilation and crystal fractionation. In stage 2, the differentiated magma rose to shallower depth, fed the pre-Campanian Ignimbrite activity and evolved by further open-system processes into the most-evolved and most-radiogenic Campanian Ignimbrite end-member magma. In stage 3, new trachytic magma, isotopically distinct from the pre-Campanian Ignimbrite magmas, rose from ca. 6 km to shallower depth, recharged the most-evolved pre-Campanian Ignimbrite magma chamber, and formed the large and stratified Campanian Ignimbrite magmatic system. During the course of the Campanian Ignimbrite eruption, the two layers were tapped separately and/or simultaneously, and gave rise to the range of chemical and isotopic values displayed by the Campanian Ignimbrite pumices, glasses and minerals.
    Description: Published
    Description: 285-300
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Radiogenic isotopes ; Mixing process ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    International Journal of Mass Spectrometry and Ion Processes 123 (1993), S. 139-147 
    ISSN: 0168-1176
    Keywords: atomic weight ; iridium ; isotope ratio ; negative thermal ionization mass spectrometry ; osmiridium
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    International Journal of Mass Spectrometry and Ion Processes 114 (1992), S. 209-220 
    ISSN: 0168-1176
    Keywords: isotope ratios ; negative thermal ionization mass spectrometry ; selenium ; sulfur ; tellurium.
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 169 (1928), S. 140-150 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die für die Darstellung von gleichteiligen Silberhydrosolen besten Mengenverhältnisse werden zusammengestellt für das Arbeiten mit 0,001% iger Silberoxydlösung.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 209 (1932), S. 325-327 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Der beim Eintauchen von metallischem Cadmium in eine sehr verdünnte Lösung von Goldschlorid entstehende Niederschlag ist nicht nur in seiner Zusammensetzung, sondern auch in seiner röntgenographisch verglichenen Struktur identisch mit der intermetallischen, aus der Schmelze entstandenen Verbindung AuCd3.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 173 (1928), S. 27-44 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bereits früher berichtete Beobachtung, daß die Reduktion von silberhaltigen Reduktionsgemischen ohne Verwendung von Gold-oder Silberkeimen durch Hydrazinhydrat je nach der Menge des dabei anwesenden Natriumcarbonats abgestufte Silbersole zu liefern vermag, wird erweitert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 148 (1925), S. 382-390 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. An Goldhydrosolen, die durch Reduktion gewonnen waren, sind die Beweglichkeiten der Goldteilchen im elektrischen Potentialgefälle unabhängig von dem Zerteilungsgrad und der Art der Darstellung.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 181 (1929), S. 379-384 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Abhängigkeit des elektrokinetischen Potentials des Goldes von der Konzentration wird in sehr verdünnten Lösungen von Elektrolyten (10-8-10-5 n.) verfolgt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 164 (1927), S. 409-419 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Gegensatz zu den bekannten Silberhydrosolen mit vielfarbigen Submikronen kann man auch solche mit gleichfarbigen Teilchen herstellen und damit ähnliche Verhältnisse erreichen, wie bei kolloidem Gold.
    Type of Medium: Electronic Resource
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