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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 63-67 
    ISSN: 0009-2940
    Keywords: Dinuclear gold complex ; Silyl complex ; Gold-gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 361).  -  On the Question of Gold-Gold Interactions in Ph2P[CH2]t(2)PPh2-Bridged Dinuclear Gold Silyl ComplexesDinuclear silyl gold complexes of the type dppm(AuSiR3)2 (1) or dppe(AuSiR3)2 (2) are prepared by the reaction of dppm-(AuCl)2 or dppe(AuCl)2 with two equivalents of LiSi(aryl)3 or LiSi(SiMe3)3 The complex dppe[AuSi(SiMe3)3]2 (2 c) exhibits crystallographic inversion symmetry, and therefore the distance between both gold atoms is a maximum. In dppm-(AuSiPh3)2 (1b) a gold-gold interaction between both gold atoms is observed [Au  -  Au 316.80(3) pm].
    Additional Material: 3 Ill.
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  • 2
    ISSN: 0009-2940
    Keywords: Gold complex, dinuclear / Silyl complex / Gold - gold interaction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Silyl Complexes, 34. - A Dinuclear Gold Silyl Complex with Gold- Gold Interaction Between an (R3P)2Au and an (R′3,Si)ClAu UnitPh2MeP-Au-Cl reacts with Ph2MeP-Au-SiPh3 to form the dinuclear complex (Ph2MeP)2Au2(Cl)SiPh3, which is in equilibrium with its starting compounds. An X-ray structure analysis reveals that it consists of a (Ph2MeP)2Au and a (Ph3Si)ClAu unit, which are held together by Au-Au interaction [298.07(4) Pm]. The approximately linear AuL2 units are orthogonal to each other.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 743-751 
    ISSN: 0009-2940
    Keywords: Stannyl complexes ; Hydride complexes ; Three-center bonds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal Stannyl Complexes, 3. - Metal, Hydrogen, Tin Three-Center Bonding in Group VI Hydrido Stannyl ComplexesThe hydrido stannyl complex (π-1,3,5-Me3C6H3)(CO)2Cr(H)-SnPh3 (1) is prepared by photochemical reaction of (π-1,3,5-Me3C6H3)(CO)3Cr with HSnPh3. The 119SnHCr coupling constant (327.6 Hz) and an X-ray structure analysis [Sn - H 202(4), Cr - H 159(4), Cr - Sn 270.16(6) pm] show that the Sn - H bond is coordinated in an η2 fashion. The complexes (CO)4(R3P)-W(H)SnPh3 (R3P=Ph3P, MePh2P) (2) and (CO)3(dppe)M(H)-SnR3 (M=Cr, SnR3=SnPh3; M=Mo, SnR3=SnMe3, SnPh3; M=W, SnR3=SnMe3, SnPh2Me, SnPh3) (4 - 6) are obtained either by thermal reaction of (CO)4(R3P)W(THF) or (CO)3(dppe)ML (L=THF, acetone) with HSiR3, or by photochemical reaction of (CO)4(dppe)M with HSnPh3. Reaction of (CO)4(Ph3P)W(THF) with HSnMe3 yields (CO)4(Ph3P)W(Sn-Me3)2 (3). The Sn,M,H coupling constants in the complexes 2 and (CO)3(dppe)M(H)SnR3 (M=Cr, Mo) are in the range of 250 - 315 Hz and therefore these complexes seem to contain an η2-coordinated stannane. Contrary to this, the SnWH coupling constants in (CO)3(dppe)W(H)SnR3 are considerably lower (70 - 90 Hz), suggesting complete oxidative addition of the H - Sn bond. The complexes (CO)3(dppe)M(H)SnPh3 decompose in benzene solution at room temperature to give, inter alia, hexaphenyldistannane. Ph6Sn2 · 2 C6H6 crystallizes in the space group \documentclass{article}\pagestyle{empty}\begin{document}$ R\bar 3 $\end{document} (Z=1); in the crystal lattice the benzene molecules are perpendicular to the three-fold axis of symmetry of the distannane molecule.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Cell Biochemistry and Function 2 (1984), S. 23-25 
    ISSN: 0263-6484
    Keywords: Blood ; fatty acids ; platelet ; membrane ; myeloproliferative disorders ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The fatty acid composition of platelet membranes has been analysed in patients with thrombocytosis due to myeloproliferative disorders, who had not taken any drugs. A significant increase in palmitic and oleic acid, together with a decrease in stearic, linoleic and arachidonic acids was observed. The fatty acid pattern of platelet membranes was also analysed in patients during treatment with ASA (acetylsalicylic acid). ASA ingestion completely normalizes the platelet content of palmitic acid and partially that of stearic and arachidonic acid, whereas it has no effect on the level of linoleic acid and raises that of oleic acid. The altered pattern of fatty acids observed in patients may interfere with platelet function by decreasing membrane fluidity. Treatment of patients with ASA seems to act on platelet membranes by partially normalizing the fatty acid composition.
    Additional Material: 2 Tab.
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  • 5
    Publication Date: 2017-04-04
    Description: Field geology, well data and seismic imaging have illuminated the upper crustal structure of the Southern Apennines. However, lack of control of the deep structure allows viable competing thin-skin and thick-skin models of the orogen. In thin-skin models the detachment decouples a stack of rootless nappes from the basement. In thick-skin models, basement is involved in the most recent phase of thrusting. To examine the deep crustal structure, we use the teleseismic recordings from the CAT/SCAN array, deployed in southern Italy from Dec. 2003-Oct. 2005. We use receiver functions processed into a Common Conversion Point stack to generate images of the crust. We image three main westward-dipping seismic-velocity discontinuities where P-to-S conversions occur. They correspond to velocity jumps at the Moho, the upper-lower crust boundary and sedimentary interfaces resulting from the contrast between clastic and carbonate strata with basement. The CCP image matches features from both thin-skin and thick skin model. The lateral continuity of the converters favors thin skin, but consistent interpretation across the image favors the thick skin. Overall, the results provide a better fit to the thick-skin interpretation. This suggests a change in structural style as the collision with Apulia halted motion. This model also implies considerably less Plio-Pleistocene shortening across the Apennines and a SE motion of the Calabrian Arc subparallel to the southern Apennines rather than a radial expansion of the Arc.
    Description: Published
    Description: AGU General Assembly, S. Francisco
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Continental Crust ; Suduction zone processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 6
    Publication Date: 2017-04-04
    Description: La definizione di un modello crostale per l’area dello Ionio è di fondamentale importanza per la comprensione dell’evoluzione geodinamica del Mediterraneo. Anche se quasi tutti gli autori concordano nel ritenere la crosta del Mar Ionio assimilabile a una crosta oceanica matura (De Voogd et al., 1992, Catalano et al., 2001; Finetti e Del Ben, 2005; Argnani, 2005), esistono tuttavia ipotesi alternative (Farrugia and Panza, 1981; Ismail-Zadeh et al., 1998..) e rimangono da chiarire alcuni aspetti di questa struttura litosferica. L’area ionica è una delle regioni del Mediterraneo con maggiore attività sismica, in passato interessata da numerosi eventi di elevata intensità seguiti a volte da tsunami (Vannucci et al., 2004; Tinti et al. 2004). L’attività sismica è in gran parte localizzata lungo gli archi Ellenico, Egeo e Calabro, la Sicilia orientale e la scarpata Ibleo-Maltese. La sismicità del bacino ionico è in parte sconosciuta a causa della mancanza di stazioni sismiche sottomarine offshore. Per lo stesso motivo attualmente non esiste per l’area in esame alcuna tomografia sismica passiva con adeguata risoluzione. Per meglio caratterizzare la sismicità dello Ionio e raccogliere una quantità di dati sufficiente a costruire un robusto modello di velocità, nel maggio 2007, nell’ambito delle attività di monitoraggio realizzate in collaborazione con il Dipartimento di Protezione Civile (DPC) e in seno al progetto europeo NERIES (attività NA6), l’OBS Lab di Gibilmanna del Centro Nazionale Terremoti dell’INGV, ha deposto tre Ocean Bottom Seismometers (OBS) nello Ionio meridionale a profondità comprese tra 3500- 4000m. Gli strumenti deposti sono stati realizzati presso l’Osservatorio di Gibilmanna e sono stati equipaggiati con sismometri Nanometrics Trillium 120P installati su basi autolivellanti della Nautilus e con sensori di pressione differenziali (DPG) con banda passante compresa tra 200s e 2Hz. I segnali provenienti dai due sensori sono sti acquisiti da un data logger a 21 bit (SEND Geolon MLS) ad una frequenza di campionamento di 100Hz Gli OBS A1 e A3 sono stati recuperati con successo il 2 febbraio 2008 mentre l’OBS A2 è stato recuperato il 15 marzo 2008 ed è stato sostituito da un altro OBS per completare il monitoraggio di lunga durata (sino a maggio 2010) previsto dal progetto NERIES. L’array di OBS ha registrato per nove mesi i segnali sismici dal fondo dello Ionio. Mentre per l’OBS A1 sia il DPG che il sismometro hanno funzionato correttamente, per gli OBS A2 e A3, a causa di problemi nel livellamento dei sensori sismici e alla loro bassa tolleranza del tilt dinamico di appena +- 0.2°, i dati provenienti dai sismometri sono risultati inutilizzabili. Durante l’esperimento l’array di OBS ha registrato oltre 450 eventi: sono stati individuati circa 90 telesismi, 250 eventi regionali registrati anche dalle reti sismiche a terra e oltre 100 eventi non localizzati. La Fig. 2 mostra la distribuzione degli epicentri dei telesismi e degli eventi regionali. Gli eventi sono stati localizzati dall’INGV, dall’EMSC, dall’USGS e dalla rete sismica nazionale greca e riportati nei rispettivi bollettini sismici. La Fig. 3 mostra l’evento sismico del 12 settembre 2007 con epicentro a Sumatra di Ms = 8.5. Sui sismogrammi sono facilmente individuabili diverse fasi di onde di volume e di superficie sia sul segnale di pressione che sui segnali di velocità. Per un’accurata localizzazione degli eventi locali è necessaria la conoscenza di un modello ottimale di velocità delle onde P ed S per l’area in esame. Per definire un modello 1D di velocità delle onde P per l’area ionica, abbiamo invertito i tempi di arrivo delle prime fasi P degli eventi regionali registrati. Dell’intero dataset sono stati scelti solamente gli eventi con RMS di residuo inferiore a 0.3s e errore di localizzazione standard minore di 3.0 km. Sulla base delle informazioni attualmente disponibili per l’area del bacino ionico e delle aree circostanti, sono stati inoltre scartati gli eventi con ipocentro superficiale in aree intensamente deformate; per queste aree sono state selezionati solo gli eventi con profondità ipocentrale superiore a 20 km. Il dataset finale è composto da 67 eventi regionali con un totale di 175 fasi P individuate. Il problema diretto di tracciamento del raggio dalla sorgente alla stazione è stato risolto in maniera analitica per i raggi rifratti e tramite il metodo dello “shooting” per le onde dirette. Nella soluzione del problema diretto è stata considerata anche la profondità delle stazioni. Generalmente nell’identificazione di un modello 1D di velocità ottimale sono invertiti simultaneamente sia i parametri ipocentrali che i parametri del modello crostale utilizzando un “misfit” globale come misura della bontà dell’inversione. Tuttavia, poiché gli eventi regionali sono stati localizzati da stazioni a terra, sono stati invertiti solo i parametri del modello di velocità. Dato che il problema inverso è di natura non lineare, la soluzione è stata ottenuta iterativamente. Fattore critico nel processo di inversione è la scelta di un adeguato modello iniziale di velocità. Il modello iniziale utilizzato nell’inversione è quello proposto da Finetti e Del Ben (2005). Questo modello crostale è costituto da 6 strati su crosta oceanica a profondità di 13.7 km. Nella procedura di inversione abbiamo fissato solamente il numero di strati e invertito la velocità e gli spessori. Il modello 1D di velocità delle onde S è stato ottenuto applicando due metodologie di indagine geofisica complementari: l'inversione delle curve di dispersione delle onde di superficie e delle receiver function. Le curve di dispersione sono state ottenute tramite l’analisi FTAN (Dziewonski et al., 1969) e invertite imponendo lo stesso numero di strati del modello di velocità delle onde P. I risultati ottenuti sono stati comparati con i modelli ricavati da un'inversione indipendente delle Receiver Function telesismiche ottenute per la stazione A1. L’inversione congiunta dei tempi di viaggio e delle curve di dispersione ha permesso di definire un unico modello 1D di velocità. Tale modello sarà utilizzato per localizzare gli eventi locali. Il modello ottenuto e i risultati della localizzazione saranno esposti durante il convegno.
    Description: Published
    Description: Trieste
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: open
    Keywords: OBS ; OBS/H ; Ionian Sea ; NERIES ; MOHO ; Modello di velocità ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 7
    Publication Date: 2017-04-04
    Description: We analyze the seismicity of a small sector of the Northern Apennines merging data from the Italian seismic bulletin with original data collected by temporary seismic networks. Our attention is focused on the region enclosed between the Apenninic watershed and the Adriatic Sea. This portion of belt is interested by the occurrence of diffuse crustal seismicity and small-to-moderate earthquakes. In this paper we study the five small sequences with mainshock having Mw 〈 4.7 that in the past 15 years hit the area. Our interest is addressed to better understand the relationship between these events and the regional seismotectonic setting in terms of seismicity distribution and stress field. Two regions with different behavior in the seismic release can be distinguished: (i) along the watershed where seismicity is clustered at shallow depths (〈 15 km) and where strong earthquakes occurred in the past, (ii) an eastern portion where the seismicity is distributed across all of the crustal volume, locally reaching depths down to 30 km. The focal mechanism of the seismic sequences shows mainly normal fault kinematics coherent with the regional stress field. Detailed stress field analysis suggests a rotation of the principal stress axis moving from the axial part of the chain toward the Adriatic Sea to the east.
    Description: Published
    Description: 136-144
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Northern Apennines ; Stress field ; Focal mechanisms ; Seismicity ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: Receiver functions (RFs) analyzed at two permanent broadband seismic stations operating in the epicentral area of theMw 6.3, 2009 L’Aquila earthquake (central Italy) yield insight on crustal structure along the fault rupture. The harmonic decomposition of RFs highlights a subsurface structure in which both isotropic and anisotropic features are present. We model the waveforms using recently developed Monte Carlo methods. The retrieved models display a common depth structure, between 10 and 40 km depth, consistent with the under‐thrusting of the Adria lithosphere underneath the Apennines belt. Along the fault, in the uppermost crust, the S wave velocity structure is laterally heterogeneous. Right above the hypocenter, we find a 4–6 km thick, very high S wave velocity body (Vs as high as 4.2 km/s) that is absent in the SE portion of the fault, where the earthquake propagated. The high‐Vs body is coincident with the area of fewer aftershocks and is anticorrelated with the maximum slip patches of the earthquake, as modeled by differential interferometric synthetic aperture radar (DInSAR) and strong motion data. We interpret this high‐Vs body as a high‐strength barrier responsible for the high peak ground motion in the near field, observed in the L’Aquila city and surroundings, and for the complexity in the rupture evolution. The retrieved seismic S wave velocity of this body far exceeds common Vs values in the upper crust and it is more compatible with values observed in mafic basement rocks.
    Description: Published
    Description: B12326
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: L'Aquila earthquake ; receiver function ; S-velocity model ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: Global crustal model, from gravity studies, imaged a thick crust (〉40 km) under Eastern Antartic craton (EAC). This global trend ends abruptly west of the Transantarctic Mountains (TAM), which border EAC along its western margins. There, the crust raises up to about 20 km. While this model points out the difference between EAC and the Ross sea crustal structures, its intrinsic spatial resolution gives little help to solve some regional geophysical issues, like the TAM orogenesis and the formation and nature of the Wilkes Basin. In this study, teleseismic Receiver Functions (RFs) are used to image the S-velocity crustal structure in finer details. We computed RFs from teleseismic events recorded during three different austral summer compaigns: BackTAM, WIBEM and WISE. Broadband seismic stations were deployed along a transect which spans from the coast of Northern Victoria land (NVL) to the far interior of the EAC plateau. The transect, almost perpendicular to the regional TAM axis, came across four different geological/geophysical settings: the alloctonhous terranes of the NVL, the TAM sector, the Wilkes Basin and the EAC plateau. Each area shows peculiar crustal structures and we propose both finer local S-velocity models and a regional crustal model.
    Description: Published
    Description: AGU General Assembly, S. Francisco
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Antarctica ; Receiver Functions ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 10
    Publication Date: 2017-04-04
    Description: In May 2007, within the monitoring activities carried out in cooperation with the Italian National Civil Protection Department (DPC), and within the European project NERIES (activity NA6), the Gibilmanna OBS Lab of the INGV has deployed three Broad Band Ocean Bottom Seismometers (BBOBS) in the southern Ionian Sea at 3500-4000 meters of depth. The BBOBS deployed were equipped with a Nanometrics Trillium 120P seismometer and a Cox-Webb 500s-2 Hz Differential Pressure Gauge (DPG). A 21 bits four channel digitizer (SEND Geolon MLS) recorded data at 100 sps. During the nine months of the experiment, the OBS’s array recorded more than 400 events: about 90 are teleseismic events, more than 200 are regional events also recorded by the seismic networks onshore, finally more than 100 events were not recorded by any seismic networks on land. We used both the regional and teleseismic events recorded by seismometer and DPG to construct a simple velocity model for the Ionian crust. Teleseismic receiver function were computed from high s/n teleseismic records and dispersion curves were extracted for Rayleigh wave recorded. We inverted both the receiver function and Rayleigh dispersion curves data-set to constrain a 1D S-velocity model for the Ionian crust. Moreover a minimum 1‐D velocity P‐wave model is estimated by inversion of the first P-wave arrivals time of the regional events.
    Description: Published
    Description: Crete, Greece
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: open
    Keywords: BBOBS ; OBS ; Ionian Sea ; Moho ; Receiver function ; P-wave model ; S-wave model ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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