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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6198-6200 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The correlation is reported between perpendicular anisotropy and in-plane lattice strain in Co/Pt multilayers. (Cox/Pty)n samples, where x, y are the thickness of the individual Co and Pt layers and n is the number of repeats that were prepared by molecular beam epitaxy and studied by means of polar magneto-optic Kerr effect and transmission electron microscopy. Kerr rotation data and electron diffraction experiments show that the largest perpendicular anisotropy and square hysteresis loop occur when x=3 A(ring) while the Pt layers are subjected to about −2% in-plane strain. As Co thickness increases, Co and Pt layers gradually lose coherency and the magnetic anisotropy goes from perpendicular to planar. This is accompanied by a relaxation of lattice strain in both Co and Pt layers. The close relationship between magnetic anisotropy and lattice strain can be explained as magnetoelastic anisotropy or stress anisotropy effect due to lattice mismatch between the adjacent epitaxial layers.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 5799-5807 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Multilayers of (Co3 A(ring), Pt15 A(ring))x, x=15 or 30 repeats, with or without a 200 A(ring) silver buffer layer, were grown on GaAs (111) substrates by molecular-beam epitaxy. Vibrating sample magnetometry measurements confirmed that the samples with the Ag buffer layer show strong uniaxial magnetic anisotropy perpendicular to the surface. The perpendicular anisotropy exhibited by these metallic superlattices is discussed in terms of the microstructure of the overall multilayer stack, as well as the structural characteristics of the Co interface layer. Samples grown on the Ag buffer layer show strong (111) texture with 30–40-nm-size twin-related grains. These grains, correspond to the two possible (111) stacking sequence for an fcc lattice, i.e., double positioning. However, direct growth on GaAs (111) results in randomly oriented 10–20 nm grains. All samples exhibit a repeat period of 1.83 nm in both low-angle reflectivity and high-angle aitch-theta–2aitch-theta x-ray scattering measurements. In addition, transverse scans through the low-angle multilayer Bragg peaks show the interfaces to be diffuse in nature indicative of considerable in-plane inhomogeneity and/or compound formation. High-resolution electron microscopy measurements of cross sections compared with image simulations confirm that the interface layer is diffuse and its stoichiometry is such that the Co occupation is less than 40%. Redistribution of Co should then extend over at least four monolayers. The nanostructure of the samples grown with the Ag buffer layer comprises an eight atomic layer repeat with the Co interface layer diffuse over four monolayers. The microstructure is strongly (111) textured with columns of twin related 30-nm-sized grains. It is suggested that the combination of interdiffusion, highly oriented but twin-related columnar growth, small grain size with a possible nanometer-scale second phase may be the key to the understanding of the perpendicular anisotropy observed in these (111) superlattices.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6647-6649 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The role of magnetic, structural, and chemical roughness on the origin of exchange biasing in polycrystalline Mn52Ni48/Fe92(Mo8) bilayers has been investigated by transmission x-ray magnetic circular dichroism (XMCD), vibrating sample magnetometry (VSM), and transmission electron microscopy (TEM). Three bilayer samples of MnNi(22 nm)/Fe(Mo) (6 nm) were grown by molecular beam epitaxy under ultrahigh vacuum conditions with the MnNi layer at temperatures of 200 °C, 250 °C, and 300 °C. The exchange bias, He was observed to be the largest for the 250 °C growth sample. The angular dependence of He can be well modeled in terms of a cosine series with odd terms confirming the unidirectional nature of the anisotropy energy. However, the coefficients are different for the three samples indicating different microscopic magnetic interactions at the interface. XMCD measurements showed no magnetic moment for Mn and Ni but showed systematic variations of the Fe moment, i.e., a decrease in Fe moment with increase in He was observed. We have interpreted this decrease in Fe moment in terms of antiferromagnetic (AF) ordering of Fe at the interface with the extent of the AF ordering being related to the magnitude of the exchange. Thus, for samples grown at 250 °C, it is found that at least about 4 MLs of Fe appear to be AF. Preliminary energy-filtered imaging of cross-section samples shows that the Fe layer is chemically rough suggesting that the decrease in moment may arise from the intermixing of Fe with the MnNi layer. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 6597-6599 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Epitaxial PdMn/Fe bilayer structures, in both a-axis PdMn(100)/Fe(001)/MgO(001) and c-axis PdMn(001)/Fe(001)/MgO(001) orientations, were grown by ion-beam sputtering. The a-axis samples were grown at low temperatures (T〈280 °C) while the c-axis films were stabilized at a higher temperature range (T〉300 °C). Vibrating sample magnetometry measurements show that the as-grown a-axis samples do not have a measurable exchange bias while c-axis samples have an exchange bias field He∼33 Oe. However, annealing at 230 °C for 40 min results in a measurable exchange (He∼10 Oe) for a-axis samples due to chemical ordering. The possible cause for the difference of He in a-axis and c-axis orientations is also discussed. In addition to the normal structure, inverted structures were obtained epitaxially. The exchange biasing for Fe(001)/PdMn(001)/MgO(001) is as big as 68 Oe. © 2001 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 5311-5314 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The microstructure of melt–spun rapidly quenched NdδFe13.1B (2.05≤δ≤147.6) and NdδFe14B (δ=40.6,151.7) ribbons was tailored by appropriate annealing from strongly interacting to magnetically isolated single domain Nd2Fe14B grains embedded in a nonmagnetic matrix of α-Nd and γ-Nd. This microstructure, as characterized by a variation in the magnetic interaction between Nd2Fe14B grains, was found to have a large impact on coercivity, μ0Hc, i.e., coercivity increases with an increase in the Nd concentration from 1.2 T in Nd2.05Fe13.1B to 2.75 T in Nd147.6Fe13.1B at 290 K. A detailed study of the microstructure of NdδFe13.1B (δ=38.1,148.7), carried out by conventional transmission electron microscopy, energy-filtered imaging, and energy dispersive x-ray microanalysis, showed that the majority of the Nd2Fe14B grains are completely isolated only in Nd147.6Fe13.1B. The Nd2Fe14B grains, in Nd147.6Fe13.1B, are found to be randomly oriented platelets with the c axis normal to the platelet and an average size of 100×40×25 nm. For these randomly oriented, noninteracting, single domain Nd2Fe14B grains, the coercivity was calculated using the Stoner–Wohlfarth model and including the shape anisotropy of the grains. The observed coercivity of Nd2Fe14B in Nd147.6Fe13.1B is ∼83% of this theoretical value and is the largest so far reported for Nd2Fe14B. © 2000 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6376-6378 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Highly c-axis oriented Co95Cr5 films with perpendicular anisotropy were grown epitaxially on Si (111), using an Ag seed layer, by physical vapor deposition. Films were characterized by x-ray diffraction, transmission electron microscopy (TEM), selected area electron diffraction, and Lorentz microscopy in a TEM. The following epitaxial relationship was confirmed: (111)Si(parallel)(111)Ag(parallel)(0001)CoCr;[2¯20]Si(parallel)[2¯20]Ag(parallel)[1¯100]CoCr. Magnetic domain structures of these films were observed as a function of thickness; t, in the range, 200 Å〈t〈700 Å using a wedge-shaped sample, and temperature-dependent measurements were carried out by in situ resistance heating. Thickness was measured locally by electron energy loss spectroscopy. At room temperature, below a critical thickness, tc(approximate)300 Å, the magnetization was found to be effectively in-plane of the film, and above tc a regular, stripe-like domain pattern with a significant, alternating in sign, perpendicular component was observed. The spin reorientation transitions of the stripe domains to the in-plane magnetization were studied dynamically by observing the domains as a function of temperature by in situ heating up to 350 °C. The critical transition thickness, tc, which is a function of Ku and magnetostatic energy, was found to increase with increasing temperature. The stripe-domain period, L observed at room temperature was found to increase gradually with thickness; L=90 nm at t=300 Å, and L=110 nm at t=700 Å. © 2000 American Institute of Physics.
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  • 7
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A detailed study of the microstructure and composition in hot-pressed (MQ-2) and die-upset (MQ-3) magnet alloys based on the Nd2Fe14B composition, utilizing high resolution and analytical transmission electron microscopy, is reported. The initial magnetic properties of the two samples show different behaviors, which are attributed to the difference in the anisotropy of the grain structure and the grain boundaries. The hot-pressed sample shows faceted grains of the 2-14-1 phase, while die-upset sample shows plate-like grains, together with larger equiaxed grains that contain a speckling of precipitates in the grain interior. The grain structure and composition remain rather similar in the two samples. The grain boundary phase averages ∼1–(approximately-greater-than)10 nm in width. The thicker grain boundaries are Nd-rich, while the thinner grain boundaries in the hot-pressed sample exhibit an Fe-rich composition near that of the NdFe3 phase. Nd-rich phases are found at the grain boundary junctions of both samples, with the Nd:Fe ratio near 7:3 in the die-upset sample, and up to 3:2 in the hot-pressed sample. The significance of the microstructure and the grain boundary phases on the magnetic behavior in the two samples is discussed. © 1996 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 7579-7581 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: c-axis oriented, single-crystal, Co films were grown on mica using either Ti or Ru underlayers and exhibited the following crystallographic orientation relationship (00.1)mica (parallel) (00.1)underlayer (parallel) (00.1)Co, and [11.0]mica (parallel) [10.0]underlayer (parallel) [10.0]Co. Fundamental magnetic properties of the films were measured: Hc∼4 kA/m, Bs∼1.95 T, and Ku∼5×105 J/m3. The as-grown magnetization structure of thinner (t≤30 nm) films shows mainly 180° domain walls with a uniform distribution of crossties, while thicker (t=60 nm) samples show stripe domains with a width of 75 nm. In spite of their excellent c-axis orientation (FWHMCo(002)∼1.5°), the effective anisotropy of these films is in-plane but with a small perpendicular magnetization component. These features in the hysteresis behavior are consistent with a simple noninteracting particle model incorporating the shape anisotropy of the small sized grains. For thinner samples the validity of this model has been verified by annealing experiments.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5321-5323 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a crystallographic template for the growth of the range of Fe-N phases on Si(001) by lattice matching on selected underlayers. Epitaxial films of pure α-Fe, γ′-Fe4N, and α′-Fe8N (N martensite) were grown individually by the optimization of reactive N2 sputtering parameters. The orientation relation of the Fe-N phases was Fe-N(001)(parallel)Ag(001)(parallel)Si(001) and Fe-N[100](parallel)Ag[110](parallel)Si[100]. Annealing the α′-Fe8N films resulted in the formation of α′-Fe8N/α″-Fe16N2 mixtures. In addition to the crystallographic and structural analysis, quantification of x-ray diffraction peak intensities confirmed that the α′/α″ mixtures contained as much as 46 vol % α″ (remaining α′). Vibrating sample magnetometry and SQUID magnetometry measurements of the α′ and α′(54%)/α″(46%) mixture, respectively, indicate enhanced magnetic moments for both the α′ and α″ phases with respect to pure Fe. © 1996 American Institute of Physics.
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  • 10
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: La0.8Sr0.2MnO3 thin films were simultaneously deposited by pulsed laser ablation on silicon (Si) and LaAlO3 (LAO) substrates. Films on Si were polycrystalline while those on LAO were (100) epitaxial with an in-plane correlation length of ≈10 nm. The magnetization and magnetoresistance behavior of these two films were significantly different. Both films exhibit antiferromagnetic–ferromagnetic transitions—at different temperatures [180 K (LAO); 230 K (Si)]—and their magnetic moments at 10 K were significantly different (Si—0.0035 emu; LAO—0.0022 emu). However, both films showed significant high field slope in magnetization at 10 K. Significant fractions of both films remain antiferromagnetic at low temperatures and hence net susceptibilities, dependent on the direction of the applied magnetic field, are different for the epitaxial (LAO) and randomly oriented polycrystalline (Si) films. The magnetoresistance peak, corresponding to the semiconductor–metal transition is observed at 170 and 130 K for the epitaxial (LAO) and polycrystalline (Si) films, respectively. Moreover, their resistance values are two orders of magnitude different (Si—MØhms; LAO—KOhms). These properties can be interpreted in terms of the major role of grain boundaries in determining the scattering as well as possible differences in O2 stoichiometry. © 1996 American Institute of Physics.
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