ISSN:
1572-9001
Keywords:
Heptacoordinated vanadium
;
X-ray structure
;
orientational disorder
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The new complex Me3SnV(CO)6 is obtained from TlV(CO)6 and Me3SnI in 1,2-C2H4Cl2. Crystals of this complex are composed of molecules Me3SnV(CO)6 with heptacoordinated vanadium and a Sn-V bond length of 293.90(6) pm. The molecules possess crystallographic mirror symmetry and approximateC 3v symmetry. The crystal structure determination revealed a remarkable end-for-end orientational disorder in the molecular lattice.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00679346
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