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Heptacoordinated vanadium: Preparation and structure of hexacarbonyl(trimethylstannio)vanadium (Sn—V)

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Abstract

The new complex Me3SnV(CO)6 is obtained from TlV(CO)6 and Me3SnI in 1,2-C2H4Cl2. Crystals of this complex are composed of molecules Me3SnV(CO)6 with heptacoordinated vanadium and a Sn-V bond length of 293.90(6) pm. The molecules possess crystallographic mirror symmetry and approximateC 3v symmetry. The crystal structure determination revealed a remarkable end-for-end orientational disorder in the molecular lattice.

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Authors and Affiliations

  1. Institut für Anorganische Chemie der Technischen Hochschule Aachen, Professor-Pirlet-Str. 1, D-5100, Aachen, Bundesrepublik Deutschland

    Gerhard E. Herberich, Lars Wesemann & Ulli Englert

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  1. Gerhard E. Herberich
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  2. Lars Wesemann
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  3. Ulli Englert
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Dedicated to Professor Dr. W. Bronger at the occasion of his 60th birthday on July 2nd, 1992.

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Herberich, G.E., Wesemann, L. & Englert, U. Heptacoordinated vanadium: Preparation and structure of hexacarbonyl(trimethylstannio)vanadium (Sn—V). Struct Chem 4, 199–202 (1993). https://doi.org/10.1007/BF00679346

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  • DOI: https://doi.org/10.1007/BF00679346

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