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  • Articles  (13)
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (8)
  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (5)
  • Elsevier Science Limited  (12)
  • Elsevier - Procedia Earth and Planetary Science vol. 17  (1)
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  • Articles  (13)
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  • 1
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    Origin and interactions of fluids circulating over the Amik Basin (Hatay, Turkey) and relationships with the hydrologic, geologic and tectonic settings (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Geochemistry of REE, Zr and Hf in a wide range of pH and water composition: The Nevado del Ruiz volcano-hydrothermal system (Colombia) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2021-07-14
    Description: The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y–Ho and Zr–Hf (twin pairs) have a different behaviour in strong acidic waterswith respect to the water with pH near-neutral. Yttrium and Ho behave as Zr and Hf in waters with pH near neutral-to-neutral, showing superchondritic ratios. The twin pairs showed to be sensitive to the co-precipitation and/or adsorption onto the surface of authigenic particulate (Fe-, Al-oxyhydroxides), suggesting an enhanced scavenging of Ho and Hf with respect to Y and Zr, leading to superchondritic values. In acidic waters, a different behaviour of twin pairs occurs with chondritic Y/Ho ratios and sub-chondritic Zr/Hf ratios. For the first time, Zr and Hf were investigated in natural acidic fluids to understand the behaviour of these elements in extreme acidic conditions and different major anion chemistry. Zr/Hf molar ratio changes from 4.75 to 49.29 in water with pH b 3.6. In strong acidic waters the fractionation of Zr and Hf was recognized as function of major anion contents (Cl and SO4), suggesting the formation of complexes leading to sub-chondritic Zr/Hf molar ratios.
    Description: Published
    Description: 125–133
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Zirconium ; Hafnium ; Rare earth elements ; Ionic complexes ; Acidic waters ; Fe–Al oxyhydroxides ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Isotopic composition of precipitation in Sicily, Italy (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The isotopic composition of meteoric water inSicily,Italy was investigated from May 2004 until June 2006. Samples were sampled monthly from anetwork of50rain gauges.During the same period 580 groundwater samples were collected from springs and wells toobtain insight into the isotopic composi- tion ofthe water circulati nginthe main aquifers ofthe area.The mean weighted precipitation values were used to definethe weighted local meteoric water line for fivedifferent sectors ofSicily.The use of Geographical Information System tools,coupled with isotopic vertical gradients,allowed designing an isotopic contour map ofprecipitation inSicily.The definedmeteoric compositions were highly consis- tent with most ofthe groundwater samples ineach sector.However,insome areas fractionation pro- cesses occurring during and after rainfall slightly modify the isotopic composition ofthe groundwater. The obtained data set definesthe present day isotopic composition ofmeteoric water inthe central Med- iterranean area and provides baseline values for future climatic and/or isotope-based hydrology studies.
    Description: Published
    Description: 199-206
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry, meteoric water ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Fluorine adsorption by volcanic soils at Mt. Etna, Italy (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-03
    Description: Fluorine adsorption experiments were performed on 28 samples of the first 5 cm of topsoil collected on the flanks of Mt. Etna. The soil samples were equilibrated with F-rich rainwater (3.25 mg/L) at a soil/water weight ratio of 1/25. Aliquots of the supernatant were collected after 1, 7, 72, 720 and 5640 h and analysed for F content. The soil samples could be subdivided into three groups based on their F-adsorption behaviours after 1 h and at the end of the experiment: (1) negative adsorption (F released from the soil to the solution) after 1 h and negative or moderately positive adsorption at the end, (2) from negative after 1 h to strongly positive adsorption at the end, and (3) always strong positive adsorption. The adsorption capacity of the soils was positively correlated with the soil pH, the contents of finer granulometric fractions (clay and silt) and the weathering stage (as quantified by the chemical alteration index). The most F adsorbing soils are found at the periphery of the volcano where aquifers are more vulnerable to contamination due to the shallower depth of the water table. This study further evidences the importance of the Etnean soils in protecting groundwater from an excessive magmatic F input.
    Description: Published
    Description: 1179–1188
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic soils ; fluoride adsorption ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Geochemical survey of Levante Bay, Vulcano Island (Italy), a natural laboratory for the study of ocean acidification (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Shallow submarine gas vents in Levante Bay, Vulcano Island (Italy), emit around 3.6t CO2 per day providing a natural laboratory for the study of biogeochemical processes related to seabed CO2 leaks and ocean acidification. The main physico-chemical parameters (T, pH and Eh) were measured at more than 70 stations with 40 seawater samples were collected for chemical analyses. The main gas vent area had high concentrations of dissolved hydrothermal gases, low pH and negative redox values all of which returned to normal seawater values at distances of about 400 m from the main vents. Much of the bay around the vents is corrosive to calcium carbonate; the north shore has a gradient in seawater carbonate chemistry that is well suited to studies of the effects of long-term increases in CO2 levels. This shoreline lacks toxic compounds (such as H2S) and has a gradient in carbonate saturation states.
    Description: Published
    Description: 485–494
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: ocean acidification ; carbon capture and storage ; marine geochemistry ; carbonate saturation state ; volcanic vents ; carbon dioxide ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Active moss monitoring allows to identify and track distribution of metal(loid)s emitted from fumaroles on Vulcano Island, Italy (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Volatile metal(loid)s are known to be emitted from volcanoes worldwide.We tested the suitability of active moss monitoring for tracking volatilemetal(loid)s released fromthe fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil.Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS.While for most elements both extraction methods yielded similar concentrations, higher concentrations were observed e.g. for Pb in the stronger HNO3/H2O2 extracts, indicating the presence of particles, which were not digested and removed by filtration in deionized water extracts. Due to their ubiquitous detection in comparable concentrations at all 23 moss monitoring stations all over the island, Li, Mg and Sr were attributed to sea spray origin. Iron, Co, W, V, Pb, Cr, Mo, and Ba occurred predominantly at the crater, where the soil was not covered by vegetation, and thus likely represent soil-borne particulate transport. Arsenic, Sb, S, Se, Tl, Bi, and I showed a clear concentration maximum within the fumarolic field. Concentrations gradually decreased along a transect in wind direction fromthe fumaroles, which confirms their volcanic origin. Activemossmonitoring thus proved to be an inexpensive and easy-to-apply tool for investigations of volcanic metal(loid) emissions and distributions enabling differentiation of trapped elements by their source of origin.
    Description: Published
    Description: 30–39
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: La Fossa crater ; particle transport ; biomonitoring ; volatilization ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    SO2 flux monitoring at Stromboli with the new permanent INGV SO2 camera system: A comparison with the FLAME network and seismological data (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We installed a permanent SO2 camera system on Stromboli, Italy, in May 2013, in order to improve our capacity to monitor the SO2 emissions from this volcano. The camera collects images of SO2 concentrations with a period of ~ 10 s, allowing quantification of short-term processes, such as the gas released during the frequent explosions which are synonymous with Stromboli. It also allows quantification of the quiescent gas flux, and therefore comparison with the FLAME network of scanning ultraviolet spectrometers previously installed on the island. Analysis of results from the SO2 camera demonstrated a good agreement with the FLAME network when the plume was blown fully into the field of view of the camera. Permanent volcano monitoring with SO2 cameras is still very much in its infancy, and therefore this finding is a significant step in the use of such cameras for monitoring, whilst also highlighting the requirement of a favourable wind direction and strength. We found that the explosion gas emissions are correlated with seismic events which have a very long period component. There is a variable time lag between event onset time and the increase in gas flux observed by the camera as the explosion gas advects into the field of view of the camera. This variable lag is related to the plume direction, as shown by comparison with the plume location detected with the FLAME network. The correlation between explosion gas emissions and seismic signal amplitude show is consistent with a gas slug-driven mechanism for seismic event production. Comparison of the SO2 camera measurements of the quiescent gas flux shows a fair quantitative agreement with the SO2 flux measured with the FLAME network. Overall, the SO2 camera complements the FLAME network well, as it allows frequent quantification of the explosion gas flux produced by Stromboli, whose signal is in general too brief to be measured with the FLAME network. Further work is required, however, to fully automate the calculation of SO2 flux from the SO2 images captured with the camera, and to adequately account for scattering effects.
    Description: Published
    Description: 95-102
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Stromboli ; SO2 flux ; VLP ; Explosion ; SO2 camera ; volcano monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Sulphur-gas concentrations in volcanic and geothermal areas in Italy and Greece: Characterising potential human exposures and risks (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    The impact of natural and anthropogenic factors on groundwater quality in an active volcanic/geothermal system under semi-arid climatic conditions: The case study of Methana peninsula (Greece) (2017)
    Elsevier Science Limited
    Details
    Publication Date: 2019-01-09
    Description: A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system at Methana was undertaken that involved collecting 71 natural water samples. Methana is a peninsula in Peloponnesus, Greece whose arid climate and hydrological situation is similar to that of the nearby small islands of the Aegean Sea. Similarly, the chemical and isotopic compositions of its water are dominated by the mixing of seawaterwith meteoric water both through direct intrusion and meteoric recharge. However, the simple mixing trends at Methana are modified by water–rock interaction processes, enhanced by the dissolution of endogenous CO2, which lead to strong enrichments in alkalinity, Ca, Ba, Fe and Mn. The thermal waters show very high salinity that is sometimes close to that of seawater [total dissolved solids (TDS)=8.5–40 g/l]. Although the cold groundwaters sometimes also show elevated TDS values (up to 6.3 g/l), their overall quality is acceptable due to the trace metal and nitrate contents mostly being below acceptable limits. While the saltiest groundwaters are not acceptable for human consumption, they are used for irrigation without exerting toxic effects on plants, which is probably due to the high permeability of the soils not supporting salt accumulation and salinity-resistant crops being cultivated.
    Description: Published
    Description: 110-119
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogeochemistry ; volcanic aquifers ; Salinization ; stable isotopes ; Trace elements ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Geochemical characterisation of gases along the dead sea rift: Evidences of mantle-CO2 degassing (2016)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The Dead Sea Transform (DST) fault system,where a lateral displacement between the African and Arabian plates occurs, is characterised by anomalous heat flux in the Israeli area close to the border with Syria and Jordan. The concentration of He and CO2, and isotopic composition of He and total dissolved inorganic carbon were studied in cold and thermalwaters collected along the DST, in order to investigate the source of volatiles and their relationship with the tectonic framework of the DST. The waters with higher temperature (up to 57.2 °C) are characterised by higher amounts of CO2 and helium (up to 55.72 and 1.91 ∗ 10−2 cc l−1, respectively). Helium isotopic data (R/Ra from 0.11 to 2.14) and 4He/20Ne ratios (0.41–106.86) show the presence of deep-deriving fluids consisting of a variable mixture ofmantle and crust end-members,with the former reaching up to 35%. Carbon isotope signature of total dissolved carbon from hot waters falls within the range of magmatic values, suggesting the delivery of deep-seated CO2. The geographical distribution of helium isotopic data and isotopic carbon (CO2) values coupled with (CO2/3He ratios) indicate a larger contribution of mantle-derived fluids affecting the northern part of the investigated area, where the waters reach the highest temperature. These evidences suggest the occurrence of a favourable tectonic framework, including a Moho discontinuity up-rise and/or the presence of a deep fault system coupled with the recent magmatic activity recognised in the northern part of Israel.
    Description: Published
    Description: 50–57
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Fluid geochemistry ; Dissolved gases ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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