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  • 1
    Publication Date: 2017-04-04
    Description: Despite its impact in understanding oceanic crust formation and eruptive styles of related volcanism, magma dynamics at midocean ridges are poorly known. Here, we propose a new method to assess ascent rates of mid-ocean ridge basalt (MORB) magmas,as well as their pre- and sin-eruptive dynamics. It is based on the idea that a rising magma can reach a variable degree of both CO2 supersaturation in melt and kinetic fractionation among noble gases in vesicles in relation to its ascent rate through the crust. To quantify the relationship, we have used a model of multicomponent bubble growth in MORB melts, developed by extending the single-component model of Proussevitch and Sahagian [A.A. Proussevitch, D.L. Sahagian, Dynamics and energetics of bubble growth in magmas: analytical formulation and numerical modeling, J. Geophys. Res. 103 (1998), 18223–18251.] to CO2–He–Ar gas mixtures. After proper parameterization, we have applied it to published suites of data having the required features (glasses from Pito Seamount and mid-Atlantic ridges). Our results highlight that the investigated MORB magmas display very different ranges of ascent rates: slow rises of popping rock forming-magmas that cross the crust (0.01–0.5 m/s), slightly faster rates of energetic effusions (0.1–1 m/s), up to rates of 1–10 m/s which fall on the edge between lava effusion and Hawaiian activity. Inside a single plumbing system, very dissimilar magma dynamics highlight the large differences in compressive stress of the oceanic crust on a small scale. Constraints on how the systems of ridges work, as well as the characteristics of the magmatic source, can also be obtained. Our model shows how measurements of both the dissolved gas concentration in melt and the volatile composition of vesicles in the same sample are crucial in recognizing the kinetic effects and definitively assessing magma dynamics. An effort should be made to correctly set the studied samples in the sequence of volcanic submarine deposits where they are collected. Enhanced knowledge of a number of physical properties of gas-bearing MOR magmas is also required, mainly noble gas diffusivities, to describe multicomponent bubble growth at a higher confidence level.
    Description: Published
    Description: 138-158
    Description: partially_open
    Keywords: Bubble growth ; MORB ; Noble gas ; Kinetic fractionation ; Modeling ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 695380 bytes
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  • 2
    Publication Date: 2017-04-04
    Description: We analyzed major and trace elements, Sr and Nd isotopes in ultramafic xenoliths in Miocenic age Hyblean diatremes, along with noble gases of CO2-rich fluid inclusions hosted in the same products. The xenoliths consist of peridotites and pyroxenites, which are considered to be derived from the upper mantle. Although the mineral assemblage of peridotites and their whole-rock abundance of major elements (e.g., Al2O3 = 0.8–1.5 wt.%, TiO2 = 0.03–0.08 wt.%) suggest a residual character of the mantle, a moderate enrichment in some incompatible elements (e.g., LaN/YbN = 9–14) highlights the presence of cryptic metasomatic events. In this context a deep silicate liquid is considered the metasomatizing agent, which is consistent with the occurrence of pyroxenites as veins in peridotites. Both the Zr/Nb and 143Nd/144Nd ratios of the investigated samples reveal two distinct compositional groups: (1) peridotites with Zr/Nb ≈ 4 and 143Nd/144Nd ≈ 0.5129, and (2) pyroxenites with Zr/Nb ≈ 20 and 143Nd/144Nd ≈ 0.5130. The results of noble-gas analyses also highlight the difference between the peridotite and pyroxenite domains. Indeed, the 3He/4He and 4He/40Ar* ratios measured in the fluid inclusions of peridotites (respectively 7.0–7.4 ± 0.1 Ra and 0.5–8.2, where Ra is the atmospheric 3He/4He ratio of 1.38 × 10− 6) were on average lower than those for the pyroxenites (respectively 7.2–7.6 Ra and 0.62–15). This mantle heterogeneity is interpreted as resulting from a mixing between two end-members: (1) a peridotitic layer with 3He/4He ≈ 7 Ra and 4He/40Ar* ≈ 0.4, which is lower than the typical mantle ratio (~ 1–4) probably due to melt extraction events, and (2) metasomatizing mafic silicate melts that gave rise to pyroxenites characterized by 3He/4He ≈ 7.6 Ra, with a variable 4He/40Ar* due to degassing processes connected with the ascent of magma at different levels in the peridotite wall rock. The complete geochemical data set also suggests two distinct mantle sources for the xenolithic groups highlighted above: (1) a HIMU (high-μ)-type source for the peridotites and (2) a DM (depleted mantle)-type source for the pyroxenites.
    Description: Published
    Description: 70-81
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: noble gases ; mantle ; xenoliths ; fluid inclusions ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: We have analyzed by single-step crushing helium and argon isotopes in olivine and orthopyroxene from mantle xenoliths of Calatrava (CLV) in central Spain and Tallante (TL) in southeast Spain. The investigation focused on carefully selected samples previously characterized in terms of major and trace elements on both bulk rock and constituent minerals, and Sr and Nd isotopes on clinopyroxene separates. Six analyses were performed on protogranular spinel lherzolites from CLV, and 17 were performed on spinel harzburgites, lherzolites, and orthopyroxenites from TL. The 40Ar/36Ar ratio was between 296 and 622, indicating atmospheric contamination, which probably occurred during exposure to the surface. The helium-isotope ratio (3He/4He) ranged between 3.6 and 6.5 Ra in CLV samples and between 1.4 and 5.7 Ra in TL samples. There was a positive correlation between the 3He/4He and 4He/40Ar* ratios, possibly reflecting diffusive fractionation between 3He, 4He, and 40Ar within mantle sections interacting with ascending melts. However, the difference between the maximum 3He/4He ratios measured in CLV and TL appears to be related to significant differences in the metasomatic melts that affected the two sectors of the lithospheric mantle. In agreement with the findings of previous studies, the helium isotopes at CLV are compatible with metasomatism due to ascending HIMU-type asthenospheric melts. In contrast, the lower 3He/4He values recorded at TL suggest subduction-related metasomatic components that are possibly related to the Cenozoic subduction of the Betic system. Such event plausibly introduced crust-derived fluids that metasomatized the mantle wedge, slightly decreasing its 3He/4He value. Noble gases appear decoupled from other elements during these mantle processes, since comparatively low 3He/4He values have been recorded also in samples that are relatively unmetasomatized in terms of incompatible lithophile elements. We hypothesize a role for volatile-dominated, CO2-rich fluids progressively decoupling from the ascending metasomatic melts and migrating in the surrounding peridotite matrix to form a diffuse aureola enriched in noble gases.
    Description: Published
    Description: 18-26
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: noble gas ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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