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  • 1
    Publication Date: 2024-01-08
    Description: This study is focused on fluids characterization and circulations through the crust of the Irpinia region, an active seismic zone in Southern Italy, that has experienced several high-magnitude earthquakes, including a catastrophic one in 1980 (M = 6.9 Ms). Using isotopic geochemistry and the carbon‑helium system in free and dissolved volatiles in water, this study aims to explore the processes at depth that can alter pristine chemistry of these natural fluids. Gas-rock-water interactions and their impact on CO2 emissions and isotopic composition are evaluated using a multidisciplinary model that integrates geochemistry and regional geological data. By analyzing the He isotopic signature in the natural fluids, the release of mantle-derived He on a regional scale in Southern Italy is verified, along with significant emissions of deep-sourced CO2. The proposed model, supported by geological and geophysical constraints, is based on the interactions between gas, rock, and water within the crust and the degassing of deep-sourced CO2. Furthermore, this study reveals that the Total Dissolved Inorganic Carbon (TDIC) in cold waters results from mixing between a shallow and a deeper carbon endmember that is equilibrated with carbonate lithology. In addition, the geochemical signature of TDIC in thermal carbon-rich water is explained by supplementary secondary processes, including equilibrium fractionation between solid, gas, and aqueous phases, as well as sinks such as mineral precipitation and CO2 degassing. These findings have important implications for developing effective monitoring strategies for crustal fluids in different geological contexts and highlight the critical need to understand gas-water-rock interaction processes that control fluid chemistry at depths that can affect the assessment of the CO2 flux in atmosphere. Finally, this study highlights that the emissions of natural CO2 from the seismically active Irpinia area are up to 4.08·10+9 mol·y-1, which amounts is in the range of worldwide volcanic systems.
    Description: Published
    Description: 165367
    Description: OST3 Vicino alla faglia
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: CO(2) output; Carbon isotopes; Degassing; Earthquakes; Noble gases; Precipitation ; 04.04 Solid Earth ; 01.01. Atmosphere ; 03.01. General ; 03.02. Hydrology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2022-12-01
    Description: An accurate survey of old and new datasets allowed us to probe the nature and role of fluids in the seismogenic processes of the Apennines mountain range in Italy. New datasets include the 1985–2021 instrumented seismicity catalog, the computed seismogenic thickness, and geodetic velocities and strains, whereas data from the literature comprise focal mechanism solutions, CO2 release, Moho depth, tomographic seismic velocities, heat flow and Bouguer gravity anomalies. Most of the inspected datasets highlight differences between the western and eastern domains of the Apennines, while the transition zone is marked by high geodetic strain, prevailing uplift at the surface and high seismic release, and spatially corresponds with the overlapping Tyrrhenian and Adriatic Mohos. Published tomographic models suggest the presence of a large hot asthenospheric mantle wedge which intrudes beneath the western side of the Apennines and disappears at the southern tip of the southern Apennines. This wedge modulates the thermal structure and rheology of the overlying crust as well as the melting of carbonate-rich sediments of the subducting Adriatic lithosphere. As a result, CO2-rich fluids of mantle-origin have been recognized in association with the occurrence of destructive seismic sequences in the Apennines. The stretched western domain of the Apennines is characterized by a broad pattern of emissions from CO2-rich fluids that vanishes beneath the axial belt of the chain, where fluids are instead trapped within crustal overpressurized reservoirs, favoring their involvement in the evolution of destructive seismic sequences in that region. In the Apennines, areas with high mantle He are associated with different degrees of metasomatism of the mantle wedge from north to south. Beneath the chain, the thickness and permeability of the crust control the formation of overpressurized fluid zones at depth and the seismicity is favored by extensional faults that act as high permeability pathways. This multidisciplinary study aims to contribute to our understanding of the fluid-related mechanisms of earthquake preparation, nucleation and evolution encouraging a multiparametric monitoring system of different geophysical and geochemical observables that could lead the creation of a data-constrained and reliable conceptual model of the role of fluids in the preparatory phase of earthquakes in the Apennines.
    Description: The INGV Earthquake Department Strategic Project FURTHER “The role of FlUids in the pReparaTory pHase of EaRthquakes in Southern Apennines”
    Description: Published
    Description: 104236
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: 4T. Sismicità dell'Italia
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: CO2 Earth degassing ; Earthquakes ; Mantle wedge ; Subduction ; Apennines ; 04.06. Seismology ; Geochemistry ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-03-01
    Description: Minimum 1D velocity models and station corrections have been computed for the central Mediterranean area using two main data sets. The first one consists of accurate first arrival‐time readings from 103 seismic events with magnitude (ML)≥3.5 recorded by the Italian National Seismic Network (RSN) and the AlpArray Seismic Network (AASN) in the period 2014–2021. Earthquakes were selected on the basis of their spatial distribution, epicentral distance to the nearest seismic station, and maximum distance traveled by Pn and Sn phases. This fine selection of high‐quality data combined with the spatial density of the AlpArray seismic stations was decisive in obtaining high resolution for upper mantle velocity, especially in the Alpine belt. To obtain a denser coverage of crustal rays, we extended the first data set with P and S arrivals of local earthquakes from Istituto Nazionale di Geofisica e Vulcanologia (INGV) bulletin data (2016–2018). A total of 75,807 seismic phases (47,183 P phases and 28,264 S phases) have been inverted to calculate best‐fit 1D velocity models, at regional and local scales. We then test the performance of the optimized velocity models by relocating the last four years of seismicity recorded by INGV (period 2017–2020). The computed velocity models are very effective for routine earthquake location, seismic monitoring, source parameter modeling, and future 3D seismic tomography.
    Description: Published
    Description: 2670--2685
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: geophysics ; velocity models ; Italian seismicity ; central mediterranean area ; 04. Solid Earth ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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