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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 210 (1933), S. 93-99 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1309-1328 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We examine the simplest homogeneous azeotropic distillation sequence of industrial relevance, where an entrainer is added to a binary azeotrope to recover both azeotropic constituents as pure products. Despite its apparent simplicity, such distillation columns can exhibit an unusual behavior not observed in zeotropic distillation: For some mixtures, separation as a function of reflux goes through a maximum. At infinite reflux, no separation is achieved.In some cases, achieving the same specifications with a larger number of trays requires a larger reflux.Sometimes the only feasible separation yields the intermediate component as a pure distillate, while the bottom product contains the light and heavy components.Sometimes the only feasible separation yields the intermediate component as a pure bottom product while the distillate contains the light and heavy components.While these unusual features can be regarded as curiosities, they are essential for proper entrainer selection and design. For a minimum boiling azeotrope, the existing and conflicting entrainer selection rules state that one should use a component that introduces no distillation boundary between the azeotropic constituents (Doherty and Caldarola, 1985), and either a low or high boiling component that introduces no additional azeotrope or a component which introduces new minimum boiling azeotropes (Stichlmair et al., 1989). By taking advantage of the curious aforementioned features, as well as our experience involving more than 400 mixtures, we have been able to analyze the assumptions behind these criteria, show when those assumptions break down, and therefore understand the limitations of the criteria.
    Additional Material: 61 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In einem mit nur zwei Parametern zu beschreibenden Gefäß wurde der Einfluß verschiedener Blattrührer auf Wärmeübergang und Rührerleistung ermittelt. Dazu wurde in einem vollgefüllten, zylindrischen Rührgefäß von 175 mm Dmr. und 175 mm Höhe mit ebenen Stirnflächen das Drehmoment von Grenzschicht- und Blattrührern an drei Flüssigkeiten verschiedener Zähigkeit optisch gemessen. Außerdem wurde das Drehmoment theoretisch berechnet unter der Annahme, daß der Flüssigkeitswiderstand nur durch die Grenzschichtreibung an der ruhenden Gefäßwand verursacht wird und daß vom Profilwiderstand der Rührer abgesehen werden kann. Dabei konnte die Grenzschichtreibung der zylindrischen Wand auf das Widerstandsgesetz der ebenen Platte und die Grenzschichtreibung der Stirnseiten auf das Gesetz der Drehströmung über festem Grund sowohl bei laminarer wie bei turbulenter Strömung zurückgeführt werden. Sodann wurde der Wärmeübergang von dem beheizten Zylindermantel auf die Flüssigkeit gemessen. Für die theoretische Berechnung des Wärmeübergangs wurde auch hier der Gefäßmantel als längs angeströmte ebene Platte betrachtet und der Wärmeübergang mit Hilfe der Ähnlichkeitsbeziehungen aus den Widerstandsgesetzen abgeleitet. Die Messungen des Drehmomentbeiwertes CM und der Nußelt-Zahl Nu lassen sich für alle untersuchten Rührer für laminare und turbulente Strömung durch die Beziehung \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm Nu/c}_{\rm M} = 0,025\,\sqrt[3]{{\Pr }} \cdot \,{\mathop{\rm Re}\nolimits} $\end{document} wiedergeben. Die gemessenen Werte stimmen mit den Berechnungen im wesentlichen überein.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 3 (1965), S. 2343-2366 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Inhibition kinetics were used to study the peroxydisulfate-iron-sulfoxylate redox initiation system. Onset of polymerization was detected by a thermometric technique permitting accurate measurement of short inhibition periods. Rate constants were derived from the inhibition periods by using an analog simulation. A good fit of calculated to observed results was obtained, based on a simple model, for experiments in ammonia buffer (pH ca 10). In bicarbonate buffer (pH ca 8.5), however, the same simple model was inadequate; additional involvement of iron is indicated. Evidence was found that the reduction of ferric versenate by sulfoxylate yields a free radical, tentatively (HCHO)SO2·. Absolute rates of radical generation were calculated.
    Additional Material: 16 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 2889-2896 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: By means of isothermal kinetic calorimetry, an automatic instantaneous record of polymerization rate can be obtained, independent of conversion. A large improvement in resolving kinetic events is thereby realized. Certain abrupt changes in rate due to electrolyte level have been observed.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 4 (1966), S. 783-791 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method for the direct measurement, by means of the heat of reaction, of essentially instantaneous polymerization rates is described. The polymerization is carried out isothermally, and the evolved heat is measured electrically over short time intervals. Applied to emulsion polymerization, the technique reveals several previously unobserved features.
    Additional Material: 6 Ill.
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  • 7
    Publication Date: 2004-08-31
    Description: This paper describes nitrogen losses from, and the characteristics of, 35 selected catchments (12 to 2000 ha) in the Nordic and Baltic countries. Average annual losses of N in 1994–1997 ranged from 5 to 75 kg ha-1, generally highest and characterised by significant within-country and interannual variations, in Norway and the lowest losses were observed in the Baltic countries. An important finding of the study is that the average nutrient losses varied greatly among the studied catchments. The main explanations for this variability were water runoff, fertiliser use (especially the amount of manure), soil type and erosion (including stream bank erosion). However, there were several exceptions, and it was difficult to find general relationships between the individual factors. For example, there was poor correlation between nitrogen losses and surpluses. Therefore, the results suggest that the observed variability in N losses cannot have been due solely to differences in farm management practices, although the studied catchments do include a wide range of nutrient application levels, animal densities and other relevant elements. There is considerable spatial variation in the physical properties (soil, climate, hydrology, and topography) and the agricultural management of the basins, and the interaction between and relative effects of these factors has an important impact on erosion and nutrient losses. In particular, hydrological processes may have a marked effect on N losses measured in the catchment stream water. The results indicate that significant differences in hydrological pathways (e.g. the relationship between fast- and slow-flow processes) lead to major regional differences in N inputs to surface waters and therefore also in the response to changes in field management practices. Agricultural practices such as crop rotation systems, nutrient inputs and soil conservation measures obviously play a significant role in the site-specific effects, although they cannot explain the large regional differences observed in this study. The interactions between agricultural practices and basic catchment characteristics, including hydrological processes, determine the final losses of nitrogen to surface waters, hence it is necessary to understand these interactions to manage diffuse losses of agricultural nutrients efficiently. Keywords: agriculture, catchments, diffuse sources, nitrogen, losses, Baltic, Nordic
    Print ISSN: 1027-5606
    Electronic ISSN: 1607-7938
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2015-02-23
    Description: In this paper, we estimate the surface water retention of nitrogen (N) in all the 117 drainage basins to the Baltic Sea with the use of a statistical model (MESAW) for source apportionment of riverine loads of pollutants. Our results show that the MESAW model was able to estimate the N load at the river mouth of 88 Baltic Sea rivers, for which we had observed data, with a sufficient degree of precision and accuracy. The estimated retention parameters were also statistically significant. Our results show that around 380 000 t of N are annually retained in surface waters draining to the Baltic Sea. The total annual riverine load from the 117 basins to the Baltic Sea was estimated at 570 000 t of N, giving a total surface water N retention of around 40%. In terms of absolute retention values, three major river basins account for 50% of the total retention in the 117 basins; i.e. around 104 000 t of N are retained in Neva, 55 000 t in Vistula and 32 000 t in Oder. The largest retention was found in river basins with a high percentage of lakes as indicated by a strong relationship between N retention (%) and share of lake area in the river drainage areas. For example in Göta älv, we estimated a total N retention of 72%, whereof 67% of the retention occurred in the lakes of that drainage area (Lake Vänern primarily). The obtained results will hopefully enable the Helsinki Commission (HELCOM) to refine the nutrient load targets in the Baltic Sea Action Plan (BSAP), as well as to better identify cost-efficient measures to reduce nutrient loadings to the Baltic Sea.
    Print ISSN: 1027-5606
    Electronic ISSN: 1607-7938
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2014-09-26
    Description: In this paper, we estimate the surface water retention of nitrogen (N) in all the 117 drainage basins to the Baltic Sea with the use of a statistical model (MESAW) for source apportionment of riverine loads of pollutants. Our results show that the MESAW model was able to estimate the N load at the river mouth of 88 Baltic Sea rivers, for which we had observed data, with a sufficient degree of precision and accuracy. The estimated retention parameters were also statistically significant. Our results show that around 380 000 t of N are annually retained in surface waters draining to the Baltic Sea. The total annual riverine load from the 117 basins to the Baltic Sea was estimated to 570 000 t of N, giving a total surface water N retention of around 40%. In terms of absolute retention values, three major river basins account for 50% of the total retention in the 117 basins; i.e. around 104 000 t of N is retained in Neva, 55 000 t in Vistula and 32 000 t in Oder. The largest retention was found in river basins with a high percentage of lakes as indicated by a strong relationship between N retention (%) and share of lake area in the river drainage areas. For example in Göta älv, we estimated a total N retention of 72%, whereof 67% of the retention occurred in the lakes of that drainage area (Lake Vänern primarily). The obtained results will hopefully enable the Helsinki Commission (HELCOM) to refine the nutrient load targets in the Baltic Sea Action Plan (BSAP), as well as to better identify cost-efficient measures to reduce nutrient loadings to the Baltic Sea.
    Print ISSN: 1812-2108
    Electronic ISSN: 1812-2116
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2012-02-07
    Description: A local-scale Gaussian dispersion-deposition model (OML-DEP) has been coupled to a regional chemistry-transport model (DEHM) in the Danish Ammonia Modelling System, DAMOS. Thereby it has been possible to model the distribution of ammonia concentrations and depositions on a spatial resolution down to 400 m × 400 m for selected areas in Denmark. DAMOS has been validated against measured concentrations from the dense measuring network covering Denmark. Here measured data from 21 sites are included and the validation period covers 2–5 yr within the period 2005–2009. A standard time-series analysis (using statistic parameters like correlation and bias) show that the coupled model system captures the measured time-series better than the regional scale model alone. However, our study also shows that about 50% of the modelled concentration level at a given location originates from non-local emission sources. The local-scale model covers a domain of 16 km × 16 km and of the locally released ammonia (NH3) within this domain, our simulations at five sites, show that 14–27% of the locally emitted NH3 also deposit locally. These results underline the importance of including both high-resolution locale-scale modelling of NH3 as well as the regional scale component described by the regional model. The DAMOS system can be used as a tool in environmental management in relation to assessments of total nitrogen load of sensitive nature areas in intense agricultural regions. However, high spatio-temporal resolution in input parameters like NH3 emissions and land-use data are required.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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