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  • 1
    Publication Date: 2010-12-10
    Description: In this paper, spectral and detrended fluctuation analyses, as well as time reversibility and magnitude-sign decomposition, have been applied to the 10-year time-series data resulting from geochemical monitoring of gas emissions on the flanks of Mt. Etna, and gases from a CO2 exploitation well located tens of kilometers from the volcano. The analysis of the time series which showed main effects of fractionation between gases due to selective dissolution in aquifers (e.g., the CO2 concentration series), revealed the occurrence of random fluctuations in time, typical of systems where several processes combine linearly. In contrast, the series of He isotopic composition exhibited power-law behavior of the second-order fluctuation statistics, with values of the scaling exponent close to 0.9. When related to the spectral exponent, this value indicates that the isotopic series closely resemble fractal flicker-noise signals having persistent long-range correlations. The isotopic signals also displayed asymmetry under time reversal and long-range correlation of the associated magnitude series, therefore it was statistically proved the presence of nonlinearity. Both long-range correlation and nonlinearity in time series have been generally considered as distinctive features of dynamic systems where numerous processes interact by feedback mechanisms, in accordance with the paradigm of self-organized criticality (SOC). Thus, it is here proposed that the system that generated the isotope series worked under conditions of SOC. Since the fluctuations of the isotope series have been related to magma degassing, the previous results place constraints on the dynamics of such process, and suggest that nonequilibrium conditions must be dominant. It remains unclear whether the signature of SOC is directly due to volatile degassing from magma, or if it derives from the interaction between melt and the stress field, which certainly influences magma decompression. The strength of scaling appears to increase after 2002 (α values from 0.8 up to 1.2), focusing on transition of the Etnean system from typical SOC toward conditions of lower criticality. By comparing this transition with those of geophysical observables, it can be suggested that the drop in the rate of magma supply, subsequent to the paroxysms of 2001 and 2002–2003, was the main cause of the scaling change.
    Print ISSN: 1023-5809
    Electronic ISSN: 1607-7946
    Topics: Geosciences , Physics
    Published by Copernicus on behalf of European Geosciences Union.
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  • 2
    Publication Date: 2019-11-04
    Description: Noble gas solubility in silicate melts and glasses has gained a crucial role in Earth Sciences investigations and in the studies of non-crystalline materials on a micro to a macro-scale. Due to their special geochemical features, noble gases are in fact ideal tracers of magma degassing. Their inert nature also allows them to be used to probe the structure of silicate melts. Owing to the development of modern high pressure and temperature technologies, a large number of experimental investigations have been performed on this subject in recent times. This paper reviews the related literature, and tries to define our present state of knowledge, the problems encountered in the experimental procedures and the theoretical questions which remain unresolved. Throughout the manuscript I will also try to show how the thermodynamic and structural interpretations of the growing experimental dataset are greatly improving our understanding of the dissolution mechanisms, although there are still several points under discussion. Our improved capability of predicting noble gas solubilities in conditions closer to those found in magma has allowed scientists to develop quantitative models of magma degassing, which provide constraints on a number of questions of geological impact. Despite these recent improvements, noble gas solubility in more complex systems involving the main volatiles in magmas, is poorly known and a lot of work must be done. Expertise from other fields would be extremely valuable to upcoming research, thus focus should be placed on the structural aspects and the practical and commercial interests of the study of noble gas solubility.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: noble gases ; solubility ; degassing ; silicate melts ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 1001374 bytes
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  • 3
    Publication Date: 2019-11-04
    Description: Long-term geochemical monitoring performed in the seismic area of the Umbria-Marche region of Italy (i.e. Central Apennines) has allowed us to create a model of the circulation of fluids and interpret the temporal chemical and isotopic variations of both the thermal springs as well as the gas vents. Coincident with the last seismic crisis, which struck the region in 1997-1998, an enhanced CO2 degassing on a regional scale caused a pH-drop in all the thermal waters as a consequence of CO2 dissolution. Furthermore, much higher 3He/4He isotope ratios pointed to a slight mantle-derived contribution. Radon activity increased to well above the ±2 sinterval of the earlier seismic period, after which it abruptly decreased to very low levels a few days before the occurrence of the single deep-located shock (March 26, 1998, 51 km deep). The anomalous CO2 discharge was closely related to the extensional movement of the normal faults responsible for the Mw 5.7, 6.0 and 5.6 main shocks that characterized the earlier seismic phase. In contrast, a clear compressive sign is recognizable in the transient disappearance of the deep-originating components related to the Mw 5.3, 51 km-deep event that occurred on March 26, 1998. Anomalies were detected concomitantly with the seismicity, although they also occurred after the seismic crisis had terminated. We argue that the observed geochemical anomalies were driven by rock permeability changes induced by crustal deformations, and we describe how, in the absence of any release of elastic energy, the detection of anomalies reveals that a seismogenic process is developing. Indeed, comprehensive, long-term geochemical monitoring can provide new tools allowing us to better understand the development of seismogenesis.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: geochemical monitoring ; seismicity ; helium ; thermal waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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