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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 11 (1998), S. 563-567 
    ISSN: 1572-9605
    Keywords: Y(Ba2 − y Sr y )Cu3O6 + δ ; high-T c superconductor ; X-ray-absorption near-edge-structure spectra ; hole concentration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The chemical control of underdoped and overdoped states in the Y(Ba2 − y Sr y )Cu3O6 + δ (δ∼0.1 and 0.9) compounds has been observed by high-resolution O K-edge X-ray-absorption near-edge-structure spectra. The chemical substitution of Sr for Ba in the fully-oxygenated Y(Ba2−y Sr y )Cu3O6 + δ (δ∼0.9) compounds gives rise to high hole concentrations within both the CuO2 planes and the out-of-plane sites, leading to the overdoped state and the decrease in the superconducting transition temperature from 92 K for y=0 to 84 K for y=0.8. In contrast, an increase in the Sr content in the oxygen-deficient Y(Ba2 − y Sr y )Cu3O6 + δ (δ∼0.1) compounds did not indicate superconductivity. The oxygen-deficient compounds exhibit the underdoped state due to the low hole concentration.
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of medicinal chemistry 18 (1975), S. 1077-1088 
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Co(11¯00)/Cr(211) and Co(112¯0)/Cr(100) multilayers have been simultaneously prepared on MgO(110) and MgO(100) substrates, respectively, by molecular beam epitaxy. They show however distinct magnetic anisotropic behavior which coincides with their magneto–crystalline anisotropy. Magneto–optical Kerr effect shows the existence of a unique easy axis and strong in-plane uniaxial magnetic anisotropy in Co(11¯00)/Cr(211) multilayers, which is induced by the well-defined hexagonal crystalline of the Co(11¯00) layers. For Co(112¯0)/Cr(100) multilayers, on the other hand, an in-plane biaxial magnetic anisotropy is found due to the bicrystalline structure of the Co(112¯0) layers. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 9105-9110 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: High-resolution Si L23-edge x-ray absorption near-edge structure (XANES) total electron yield (TEY) spectrum and photon stimulated ion desorption (PSID) spectra of condensed Si(CH3)2Cl2 have been measured in the energy range of 102–115 eV using synchrotron radiation. Excitation from Si 2p to a Si–C antibonding orbital enhances the CH3+ formation, while excitation to the Si–Cl antibonding orbital gives rise to a pronounced Cl+ production. This indicates that the character of the bound terminating orbital has a significant influence on the fragmentation processes. The selective enhancement of H+ yield at a peak of ∼106.0 eV is interpreted in terms of the excited electron in the bound orbital with strong C–H antibonding character. Applying resonant photoemission spectroscopy, the spectator Auger process was found to be the dominant decay channel for the resonantly excited Si(2p) core hole of condensed Si(CH3)2Cl2. The close resemblance of the TEY and PSID spectra of solid Si(CH3)2Cl2 was attributable to spectator Auger decay of core excited states and subsequent Coulomb repulsion of multivalence hole final states as proposed by the Knotek and Fiebelman mechanism. © 1997 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 7849-7854 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Photon-stimulated ion desorption (PSID) from solid Si(CH3)2Cl2 following Cl 2p core-level excitation has been investigated along with the resonant photoemission spectra using synchrotron radiation. The Cl L23-edge total-electron yield spectrum of solid Si(CH3)2Cl2 mainly exhibits the Cl 2p→15a1*, Cl 2p→10b1* and shape resonance peaks. A significant dissimilarity between the Cl L23-edge total-electron yield spectrum and Cl+ PSID spectrum of solid Si(CH3)2Cl2 is observed. The desorption of atomic Cl+ ions is detected predominantly at the Cl 2p→15a1* excitation, while scarcely any Cl+ ions are observed following the Cl 2p→10b1* excitation and Cl 2p→shape resonance excitation. This indicates that the character of bound terminating orbital has a significant influence on the desorption processes. The enhanced Cl+ desorption yield at the Cl 2p→15a1* resonance is attributed to the the fast desorption process originating from the localization of the spectator electron in the strong antibonding orbital. © 1998 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 1990-1999 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Leakage mechanisms for shallow, silicided, n+/p junctions have been investigated. This study consists of two parts: (a) the isolation of the processing steps that cause junction leakage, and (b) the study of the mechanism for a particular process that causes leakage. Reactive ion etching, improper junction, silicide formation procedures, ion mixing, and mechanical stress are found responsible for junction leakage, although through different mechanisms. Two mechanisms have been identified for junction leakage: (a) generation centers in the depletion region caused by deep levels from damage, or from impurities, and (b) Fowler–Nordheim tunneling caused by irregularities at the silicide/silicon interface at high reverse bias. Junction leakage can be avoided by carefully designing the details of silicide and junction formation and by carefully fine-tuning the processing steps to prevent damage of the Si substrate after forming the junction. The best junctions are made by implanting As into CoSi2 and by driving the As into Si from the silicide at 800 °C. The lower temperature drive is possible since all ion damage is contained within the silicide, leaving no damage in the Si substrate to anneal out. Very shallow, silicided, n+/p junctions can be fabricated reproducibly. These junctions demonstrate the same electrical characteristics as deeper, nonsilicided junctions, indicating that there is no fundamental barrier prohibiting fabrication of low-leakage, silicided junctions.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 69 (1998), S. 3002-3005 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A new method for investigation of diffusion processes in liquid metals with solid/liquid–liquid/solid trilayer systems is described. The design of this kind of trilayers enables diffusion processes with no effects from gravity-induced convection and Maragoni-convection conditions. The Ta/Zn–Sn/Si trilayers were prepared and the interdiffusion of liquid zinc and tin at 500 °C was investigated. The interdiffusion coefficients range from 1.0×10−4 to 2.8×10−4 mm2/s, which are less than previous values measured by capillary reservoir technique under 1 g environment where various kinds of convection exist. It is the removing of disturbances of these kinds of convection that brings about the precise interdiffusion coefficients in liquid metals. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 5928-5934 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ferroelectric SrBi2Ta2O9 (SBT) thin films were deposited on Pt/TiOx/SiO2/Si substrates using the off-axis radio frequency magnetron sputtering technique. X-ray diffraction and atomic force microscopy experiments showed that the crystallization of SBT thin films at 〉700 °C correlated with the formation of rod-like grains. Cross-sectional field emission scanning electron microscopy images revealed that the apparent thickness of SBT decreased while the thickness of Pt increased as the annealing temperature was increased. The apparent decrease in the thickness of SBT was attributed to crystallization and densification in the film whereas the apparent increase in Pt thickness was due to diffusion of Ti and Bi into the Pt layer. This diffusion at high annealing temperatures (800 °C and above) alters the Pt purity and degrades the Pt as the bottom electrode for the ferroelectric capacitor. Good insulating properties were obtained when the SBT film was annealed at 700 and 750 °C whereas higher leakage currents were observed at annealing temperatures 〉800 °C. A remnant polarization (Pr) of 4.35 μC/cm2 and coercive field (Ec) of 31.5 kV/cm were obtained for the SBT thin film annealed at 750 °C with a leakage current density of 〈10−7 A/cm2. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 2178-2184 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of structural, electrical and magnetic properties with the isovalent chemical substitution of Ca2+ into the Sr2+ sites in La1.2(Sr1.8−xCax)Mn2O7 (x=0–0.8) are investigated. The highest magnetoresistance ratio [ρ(0)/ρ(H)] of 208% (H=1.5 T) at a temperature of 102 K was observed for the x=0.4 sample. The Curie temperatures decreased from 135 to 102 K for x=0–0.4, respectively. Moreover, the Weiss constants θ were varied from the positive to negative value with increasing Ca concentration. The antiferromagnetic behavior with Néel temperature around 30 K was found in the x=0.8 sample. The magnetization measurements show that the hysteresis phenomenon appeared at the temperatures below the Curie or Néel temperatures. © 1999 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 2523-2526 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A chemical spray pyrolysis method has been applied to grow epitaxial films of a high Tc Y-Ba-Cu-O compound (YBCO) on (001)MgO. Films as thin as 0.6 μm in thickness was found to exhibit excellent superconducting transition behavior. For films up to 2 μm in thickness, typical values of Tc onset, Tc zero and transition width (90%–10%) were measured to be 82, 76, and 1.5 K, respectively. Both plan-view and cross-sectional transmission electron microscopy revealed that the orientation relationships between the epitaxial films and the substrate are [001]YBCO//[001]MgO and (110)YBCO//(200)MgO. Twins, which may be perceived as domains that are rotated 90° along the c axis of the thin films with respect to the substrate, were found to be copiously present. The influences of the configuration of the oriented growth of overlayer thin films on the superconducting properties are addressed. The advantages of the chemical spray pyrolysis in producing superconducting thin films are outlined.
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