ALBERT

Description: Populations of fishes provide valuable services for billions of people, but face diverse and interacting threats that jeopardize their sustainability. Human population growth and intensifying resource use for food, water, energy and goods are compromising fish populations through a variety of mechanisms, including overfishing, habitat degradation and declines in water quality. The important challenges raised by these issues have been recognized and have led to considerable advances over past decades in managing and mitigating threats to fishes worldwide. In this review, we identify the major threats faced by fish populations alongside recent advances that are helping to address these issues. There are very significant efforts worldwide directed towards ensuring a sustainable future for the world's fishes and fisheries and those who rely on them. Although considerable challenges remain, by drawing attention to successful mitigation of threats to fish and fisheries we hope to provide the encouragement and direction that will allow these challenges to be overcome in the future.

Description: A compilation of δ44/40Ca (δ44/40Ca) data sets of different calcium reference materials is presented, based on measurements in three different laboratories (Institute of Geological Sciences, Bern; Centre de Géochimie de la Surface, Strasbourg; GEOMAR, Kiel) to support the establishment of a calcium isotope reference standard. Samples include a series of international and internal Ca reference materials, including NIST SRM 915a, seawater, two calcium carbonates and a CaF2 reference sample. The deviations in δ44/40Ca for selected pairs of reference samples have been defined and are consistent within statistical uncertainties in all three laboratories. Emphasis has been placed on characterising both NIST SRM 915a as an internationally available high purity Ca reference sample and seawater as representative of an important and widely available geological reservoir. The difference between δ44/40Ca of NIST SRM 915a and seawater is defined as -1.88 O.O4%o (δ44/42CaNISTSRM915a/Sw= -0.94 0.07%o). The conversion of values referenced to NIST SRM 915a to seawater can be described by the simplified equation δ44/40CaSa/Sw=δ44/40CaSa/NIST SRM 915a - 1.88 (δ44/42CaSa/Sw=δ44/42CaSa/NIST SRM 915a - 0.94). We propose the use of NIST SRM 915a as general Ca isotope reference standard, with seawater being defined as the major reservoir with respect to oceanographic studies.

Description: Molybdenum isotopes are increasingly widely applied in Earth Sciences. They are primarily used to investigate the oxygenation of Earth's ocean and atmosphere. However, more and more fields of application are being developed, such as magmatic and hydrothermal processes, planetary sciences or the tracking of environmental pollution. Here, we present a proposal for a unifying presentation of Mo isotope ratios in the studies of mass-dependent isotope fractionation. We suggest that the Mo-98/95 of the NIST SRM 3134 be defined as +0.25. The rationale is that the vast majority of published data are presented relative to reference materials that are similar, but not identical, and that are all slightly lighter than NIST SRM 3134. Our proposed data presentation allows a direct first-order comparison of almost all old data with future work while referring to an international measurement standard. In particular, canonical Mo-98/95 values such as +2.3 parts per thousand for seawater and -0.7 parts per thousand for marine Fe-Mn precipitates can be kept for discussion. As recent publications show that the ocean molybdenum isotope signature is homogeneous, the IAPSO ocean water standard or any other open ocean water sample is suggested as a secondary measurement standard, with a defined Mo-98/95 value of +2.34 +/- 0.10 parts per thousand (2s).

Description: The southern section of the Agulhas western boundary current system exhibits unique characteristics as regards ocean/atmosphere heat flux processes. The Agulhas Retroflection region's high heat flux core from 37°S to 41°S, 16°E to 22°E does not demonstrate a distinct annual cycle of turbulent heat fluxes (latent and sensible) as is characteristic of its northern hemisphere counterparts. Rather, a weak semiannual heat flux cycle is found with maximum average losses during winter and summer (200 and 211 W/m2 ) and minimum losses during spring and autumn (185 and 162 W/m2 ). Upstream where the Agulhas Current is closer to land, winter heat losses exceed those of summer, but the differences are small. This behavior contrasts with that encountered at the poleward ends of northern hemisphere western boundary currents where winter heat fluxes are several times those of summer. The main reason for this difference is persistent westerly and southwesterly wind flow over the Agulhas Retroflection region throughout the year which ensures that cold, unsaturated maritime air repeatedly forces loss of heat from the ocean's surface. Spatial heat flux gradients associated with the Agulhas‐Subtropical Convergence surface temperature front are more pronounced in summer than in winter, indicating that cyclogenesis locally may be less seasonally dependent than in the northern hemisphere situation. Average oceanic cooling rates in the core region of the Retroflection, based on net heat flux calculations and a mixed surface layer of 75 m, range from 1.35°C/month during winter to 0.25°C/month during summer. Interannual variability in ocean/atmosphere heat fluxes within the Agulhas Retroflection region often exceeds the variability illustrated by the annual cycle. West of the Agulhas Retroflection core region, interannual sea surface temperature (SST) anomalies are more influential in the generation of heat flux anomalies by virtue of their large temporal variability. This high SST variability is primarily attributed to interannual changes in flux of Agulhas Current water into the southeast Atlantic Ocean. Oceanic heat loss within this warm water zone is an important modifying influence to both ocean and atmosphere, thus meriting further research.