ALBERT

Description: The long-chain diol index (LDI) is a new organic sea surface temperature (SST) proxy based on the distribution of long-chain diols. It has been applied in several environments but not yet in subpolar regions. Here, we tested the LDI on surface sediments and a sediment core from the Sea of Okhotsk, which is the southernmost seasonal sea ice covered region in the Northern Hemisphere, and compared it with other organic temperature proxies, i.e. Uk'37 and TEXL86. In the surface sediments, the LDI is correlated with autumn sea surface temperature, similar to the Uk'37 but different from the TEXL86 that correlates best with summer sea subsurface temperature. Remarkably, the obtained local LDI calibration was significantly different from the global core-top calibration. We used the local LDI calibration to reconstruct past SST changes in the central Sea of Okhotsk. The LDI-SST record shows low glacial (Marine Isotope Stage, MIS 2, 4, 6) and high interglacial (MIS 1 and MIS 5) temperatures and follows the same pattern as the Uk'37-SST and a previously published TEXL86 temperature record. Similar to the modern situation, the reconstructed temperatures during the interglacials likely reflect different seasons, i.e. summer for the TEXL86 and autumn for Uk'37 and LDI. During glacials, the reconstructed temperatures of all three proxies are similar to each other, likely reflecting summer temperatures as this was the only season free of sea ice. Our results suggest that the LDI is a suitable proxy to reconstruct subpolar sea water temperatures.

Description: The diatom valves were counted at magnifications of 1000 times; at least 400 valves were counted per sample. Percentages are based on the total diatom sum. The samples with poor diatom preservation (〈100 diatom valves) were only used for estimation of the diatom abundance, while were not used for the discussions of diatom percentages.

Description: The abundance of iron and manganese were detected by using non-destructive X-ray Fluorescence (XRF) scanning technique. Continuous downcore measurements of element variations were performed in the ITRAX XRF Core Scanner Laboratory, Department of Geosciences, National Taiwan University. All U-channels were scanned by using the 3 kW Mo source and were analyzed at 30 kV/24 mA, 2 mm resolution with a exposure time of 30 s. The count value of each element was calculated from element peak areas of original XRF spectra by the Q-Spec software provided by COX Analytical Systems.

Description: Magnetic measurements of U-channel samples were measured by the Bartington MS2 magnetic susceptibility system with an ASC auto-tracking rail and a cryogenic magnetometer (2G 755 SRM) in the shielding room of the paleomagnetic laboratory at the Institute of Earth Sciences, Academia Sinica, Taiwan. The Anhysteretic Remanent Magnetization (ARM) was applied with a DC bias field of 1 Gauss under a 100 mT alternating field. All U-channel measurements are within 1 cm interval.

Description: We provide an integrated stratigraphy for the southern margin of the Indo-Pacific Warm Pool back to 3.2 million years ago (Ma) from ODP Site 1115, Hole B (9o11'S, 151o34'E, water depth 1149 m, 0-217 m below sea floor), the only hole with core recovery beyond 4.4 m. An initial age model based on 14 calcareous nannofossil datums, 5 planktonic foraminiferal biostratigraphic events and 12 magnetic polarity reversals is refined by planktonic foraminiferal Globigerinoides sacculifer (300-355 μm) δ18O stratigraphy. The planktonic δ18O record with an average 3-4 kyr resolution matches the global stack LR04 (Lisiecki and Raymo, 2005). The 41-kyr obliquity and 100-kyr eccentricity patterns show good correlation between the LR04 and the dataset presented herein. The precession amplitude matches eccentricity, supporting the established stratigraphy. Sedimentation rates at Hole 1115B have decreased from 9.3 to 4.5 cm/kyr during the past 3.2 Ma toward present, mainly due to the gradual deepening of the Woodlark Basin. The planktonic δ18O record from Site 1115 matches the global climate evolution well.

Description: Okhotsk Sea connects the high latitude Asian continent and North Pacific which plays an important role in modern and long-term glacial–interglacial climate changes linked to subarctic terrestrial and marine systems. On the basis of the marine sediment core MD01-2414 (53°11.77′N, 149°34.80′E, water depth: 1,123 m) taken in the central Okhotsk Sea, we here improve the pre-existing magnetostratigraphy by proposing a new age model, and reconstruct both the terrigenous transport and paleoceanographic variations during the past 1550 thousand years ago (ka). Seventeen geomagnetic excursions are identified from the paleomagnetic directional record. Close to the bottom of the core, an excursion was observed, which is proposed to be the Gilsa event at ~1550 ka. During glacial periods, our records reveal a wide extension of sea ice coverage and low marine productivity. We observed ice-rafted debris from mountain icebergs composed of coarse and high magnetic terrigenous detritus which were transported from the Kamchatka Peninsula to the central Okhotsk basin. Still during glacial periods, the initiation (i.e., at ~900 ka) of the Mid-Pleistocene Transition marks the change to even lower marine productivity, suggesting that sea-ice coverage became larger after this event. During interglacial periods, the sea-ice was either inexistent or at best seasonal in the central Okhotsk Sea; resulting in high marine productivity. The weaker formation of Okhotsk Sea Intermediate Water, lower ventilation, and microbial degradation of organic matter depleted the oxygen concentration in the bottom water and created a reduced environment condition in the sea basin. The freshwater supplied by snow or glacier melting from Siberia and Kamchatka delivered fine grain sediments to Okhotsk Sea. During the super-interglacial periods after the Mid-Brunhes Transition (i.e., Marine Isotope Stages 1, 5e, 9, and 11), strong freshwater discharged from Amur River drainage area associated with active East Asian Summer Monsoon, this phenomenon enhanced the input of fine-grained terrigenous detritus to the central Okhotsk Sea.