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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 8757-8760 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The absorption ("scattering depletion'') and Raman spectra of tantalum dimers in an argon matrix have been measured for the first time. The principal absorption band of the dimer (maximum at 480 nm) shows a vibrational progression with ω'0 =260 (15) cm−1 and T0≤21,330 (20) cm−1. Weaker absorptions are observed between 200 and 350 nm and in the region 550–700 nm. Raman spectra (obtained by exciting into the 480 nm band) give ω‘e =300.2 (12) cm−1 with ωex‘e =1.2(2) cm−1.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 8811-8812 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 5701-5718 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Significant improvements have been obtained on measurements of the NO2 jet cooled excitation spectrum in the 16 300–18 502 cm−1 range, previously obtained by Smalley et al. [J. Chem. Phys. 63, 4977 (1975)], Persch et al. [Ber. Bunsenges. Phys. Chem. 92, 312 (1988)], and Hiraoka et al. [J. Mol. Spectrosc. 126, 427 (1987)]. The improvements concern first the rotational analysis, owing to a better resolution (150 MHz) and absolute precision (500 MHz), and second the completeness and purity of the resulting vibronic sequence, owing to a better sensitivity. As a result, 159 vibronic energy levels have been observed in the 16 500–18 500 cm−1 energy range, where 210±10 are expected. A detailed comparison with previous results is presented. The statistical analysis of the corresponding energy spacings shows that long range correlations up to 50 mean levels spacings are present, confirming the chaotic behavior of this set of vibronic levels. Furthermore, we analyze the observed rovibronic interactions (or rotational perturbations) that are responsible for the very irregular rotational behavior of the visible absorption spectrum of NO2 at room temperature.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 2206-2209 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the first Raman measurements on a matrix sample prepared by the mass-selected ion deposition technique. Vanadium dimer ions, produced by sputtering, were mass selected with a Wien filter and codeposited with Ar and electrons. Raman spectra gave ωe″= 536.9(1.1) and ωexe″ = 4.1(0.1) cm−1, in good agreement with previous measurements.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 3479-3490 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Rydberg spectrum of Na2 has been shown previously to alternate when increasing energy between "stroboscopic fringes'' which correspond to a well known separable Hund's coupling case (a), and a complex, unidentifiable intermediate coupling. We use this system as a prototypic example to test some current ideas on the correspondence between classical chaos and properties of quantum spectra. We first determine the phase space structure and transition to chaos in classical mechanics. We then determine the change in line intensities and level spacing statistics in quantum mechanics. We show that this system has the expected behavior in the semiclassical limit in the presence of classical chaos, except for a peculiarity in level spacing statistics, but that this behavior is not a signature of chaos, since the same system shows similar behavior for some values of the parameters which correspond to a nonchaotic situation in classical mechanics. We discuss also some problems related to the nonvalidity of the semiclassical limit.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 68 (1997), S. 4043-4050 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This article describes the use of Langmuir probes to measure plasma parameters in low density, low temperature plasmas with a strong applied magnetic field. The experiment has been performed at the Physics Department of Milan's University on the steady-state toroidal machine "Thorello." Results have been analyzed by taking into account instrumental and ionic sheath effects. Finally, experimental results have been compared with direct measurements of the electron distribution function in Thorello. © 1997 American Institute of Physics.
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  • 7
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The high current, high charge-state ion beam which can be extracted from a laser produced plasma is well suited, after initial acceleration, for injection into synchrotrons. At CERN, the production of a heavy ion beam using a CO2 laser ion source is studied. The latest results of experiments with a tantalum ion beam with charge states up to 23+ and accelerated by a radio frequency quadrupole from 6.9 to 100 keV/u, are presented along with simulations of the low energy beam transport. The ion yield at the desired charge state, the pulse to pulse stability of the ion beam, and the system reliability are all of major interest. Work is under way to replace the low repetition rate free-running laser oscillator by a master oscillator and power amplifier system. The master oscillator is operational and the first results of measurements of its beam quality and stability are presented. © 1998 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 72 (1998), S. 249-251 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a method to study separately the electrical transport properties of the grain boundaries (GBs) formed at the top and at the bottom edges of YBa2Cu3O7−δ(YBCO) step-edge Josephson junctions. The step-edge junctions were fabricated on (100) LaAlO3 steps using tilted Ar ion milling to define the electrodes and the microbridges. Due to the shadowing effect of the step, a continuous YBCO stripe remains along and at the bottom of the step on both sides of a microbridge. We found that the top GB is responsible for the weak link behavior of our step-edge junctions. The transport properties were correlated with the different microstructural properties of the two GBs formed at the edges of the step. © 1998 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 2591-2593 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the observation in current–voltage characteristics of YBa2Cu3O7−δ (YBCO) step-edge Josephson junctions of resistive branches generated by a current injected close to the grain-boundary region through two symmetrical Au/YBCO contacts. The current amplitude and voltage tunability of the branches is measured as a function of injected current and sample temperature and the observed effects are explained in terms of flux-flow dynamics in long Josephson junctions. As the voltage of the branches can be tuned up to 2.5 mV, the investigated phenomenon is also appealing for practical applications in the submillimeter-wave range of the electromagnetic spectrum. We estimate the available power and the linewidth of the electromagnetic radiation associated with typical bias points. © 2000 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 9 (1997), S. 2429-2442 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The Navier–Stokes equations have been solved, by a pseudospectral method, for pressure-driven flows between a no-slip wavy wall and a slip flat wall. Periodic boundary conditions were used in the streamwise and spanwise directions. The physical domain is mapped into a computational domain that is a rectangular parallelepiped using a nonorthogonal transformation. The pseudospectral solution procedure employed in previous studies, for example, Lam and Banerjee [Phys. Fluids A 4, 306 (1992)], eliminated the pressure and solved for the wall–normal velocity and vorticity. The other velocity components were calculated using the definition of vorticity, and the continuity equation. This procedure leads to oscillations in the pressure field when solutions were attempted in the mapped computational domain. To overcome the problem, the procedure had to be modified and the pressure solved for directly using a fractional time step technique. For the cases examined here, these modifications resulted in spectral accuracy being maintained. Flow over sinusoidal wave trains has been simulated and the results compare well with available experiments. The simulations show significant effects of the wavy boundary on the mean flow and the turbulence statistics. The mean velocity profile differs substantially from the profile for the flat-wall case, particularly in the buffer region where the fluid is under the influence of both the wavy wall and the slip boundary. The velocity fluctuations in the streamwise direction decrease in the buffer region. This effect becomes more pronounced when the wave amplitude increases. Most of the redistribution of energy, from the streamwise direction to the spanwise and wall–normal directions, occurs in a thin layer close to the boundary, downstream of the wave troughs. The energy primarily redistributes into spanwise fluctuations. High shear stress regions form downstream of the wave troughs, and streaky structures and quasi-streamwise vortices are also seen to initiate in these regions. The length of the streaks, and the extent of the quasi-streamwise vortices, scale with wave length for the two cases investigated. © 1997 American Institute of Physics.
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