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  • 1
    Publication Date: 2000-10-13
    Description: Motivated by the rapid increase in atmospheric CO2 due to human activities since the Industrial Revolution, several international scientific research programs have analyzed the role of individual components of the Earth system in the global carbon cycle. Our knowledge of the carbon cycle within the oceans, terrestrial ecosystems, and the atmosphere is sufficiently extensive to permit us to conclude that although natural processes can potentially slow the rate of increase in atmospheric CO2, there is no natural "savior" waiting to assimilate all the anthropogenically produced CO2 in the coming century. Our knowledge is insufficient to describe the interactions between the components of the Earth system and the relationship between the carbon cycle and other biogeochemical and climatological processes. Overcoming this limitation requires a systems approach.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Falkowski, P -- Scholes, R J -- Boyle, E -- Canadell, J -- Canfield, D -- Elser, J -- Gruber, N -- Hibbard, K -- Hogberg, P -- Linder, S -- Mackenzie, F T -- Moore, B 3rd -- Pedersen, T -- Rosenthal, Y -- Seitzinger, S -- Smetacek, V -- Steffen, W -- New York, N.Y. -- Science. 2000 Oct 13;290(5490):291-6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institute of Marine and Coastal Sciences, Rutgers University, 71 Dudley Road, New Brunswick, NJ 08901, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/11030643" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Atmosphere ; *Carbon/metabolism ; *Carbon Dioxide/metabolism ; *Climate ; *Earth (Planet) ; *Ecosystem ; Greenhouse Effect ; Humans
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2015-06-13
    Description: Jaramillo and Destouni claim that freshwater consumption is beyond the planetary boundary, based on high estimates of water cycle components, different definitions of water consumption, and extrapolation from a single case study. The difference from our analysis, based on mainstream assessments of global water consumption, highlights the need for clearer definitions of water cycle components and improved models and databases.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Gerten, Dieter -- Rockstrom, Johan -- Heinke, Jens -- Steffen, Will -- Richardson, Katherine -- Cornell, Sarah -- New York, N.Y. -- Science. 2015 Jun 12;348(6240):1217. doi: 10.1126/science.aab0031. Epub 2015 Jun 11.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Research Domain of Earth System Analysis, Potsdam Institute for Climate Impact Research, 14473 Potsdam, Germany. gerten@pik-potsdam.de. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. ; Research Domain of Earth System Analysis, Potsdam Institute for Climate Impact Research, 14473 Potsdam, Germany. International Livestock Research Institute, Nairobi, 00100 Kenya. Commonwealth Scientific and Industrial Research Organization, St. Lucia, QLD 4067, Australia. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. Fenner School of Environment and Society, The Australian National University, Canberra, ACT 2601, Australia. ; Center for Macroecology, Evolution, and Climate, University of Copenhagen, Natural History Museum of Denmark, 2100 Copenhagen, Denmark.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/26068844" target="_blank"〉PubMed〈/a〉
    Keywords: *Biological Evolution ; *Climate Change ; *Earth (Planet) ; Humans ; *Ozone Depletion
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
    Publication Date: 2015-01-17
    Description: The planetary boundaries framework defines a safe operating space for humanity based on the intrinsic biophysical processes that regulate the stability of the Earth system. Here, we revise and update the planetary boundary framework, with a focus on the underpinning biophysical science, based on targeted input from expert research communities and on more general scientific advances over the past 5 years. Several of the boundaries now have a two-tier approach, reflecting the importance of cross-scale interactions and the regional-level heterogeneity of the processes that underpin the boundaries. Two core boundaries-climate change and biosphere integrity-have been identified, each of which has the potential on its own to drive the Earth system into a new state should they be substantially and persistently transgressed.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Steffen, Will -- Richardson, Katherine -- Rockstrom, Johan -- Cornell, Sarah E -- Fetzer, Ingo -- Bennett, Elena M -- Biggs, Reinette -- Carpenter, Stephen R -- de Vries, Wim -- de Wit, Cynthia A -- Folke, Carl -- Gerten, Dieter -- Heinke, Jens -- Mace, Georgina M -- Persson, Linn M -- Ramanathan, Veerabhadran -- Reyers, Belinda -- Sorlin, Sverker -- New York, N.Y. -- Science. 2015 Feb 13;347(6223):1259855. doi: 10.1126/science.1259855. Epub 2015 Jan 15.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. Fenner School of Environment and Society, The Australian National University, Canberra, ACT 2601, Australia. will.steffen@anu.edu.au. ; Center for Macroecology, Evolution, and Climate, University of Copenhagen, Natural History Museum of Denmark, Universitetsparken 15, Building 3, 2100 Copenhagen, Denmark. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. ; Department of Natural Resource Sciences and McGill School of Environment, McGill University, 21, 111 Lakeshore Road, Ste-Anne-de-Bellevue, QC H9X 3V9, Canada. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. Centre for Studies in Complexity, Stellenbosch University, Private Bag X1, Stellenbosch 7602, South Africa. ; Center for Limnology, University of Wisconsin, 680 North Park Street, Madison WI 53706 USA. ; Alterra Wageningen University and Research Centre, P.O. Box 47, 6700AA Wageningen, Netherlands. Environmental Systems Analysis Group, Wageningen University, P.O. Box 47, 6700 AA Wageningen, Netherlands. ; Department of Environmental Science and Analytical Chemistry, Stockholm University, 10691 Stockholm, Sweden. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. Beijer Institute of Ecological Economics, Royal Swedish Academy of Sciences, SE-10405 Stockholm, Sweden. ; Research Domain Earth System Analysis, Potsdam Institute for Climate Impact Research (PIK), Telegraphenberg A62, 14473 Potsdam, Germany. ; Research Domain Earth System Analysis, Potsdam Institute for Climate Impact Research (PIK), Telegraphenberg A62, 14473 Potsdam, Germany. International Livestock Research Institute, P.O. Box 30709, Nairobi, 00100 Kenya. CSIRO (Commonwealth Scientific and Industrial Research Organization), St. Lucia, QLD 4067, Australia. ; Centre for Biodiversity and Environment Research (CBER), Department of Genetics, Evolution and Environment, University College London, Gower Street, London WC1E 6BT, UK. ; Stockholm Environment Institute, Linnegatan 87D, SE-10451 Stockholm, Sweden. ; Scripps Institution of Oceanography, University of California at San Diego, 8622 Kennel Way, La Jolla, CA 92037 USA. TERI (The Energy and Resources Institute) University, 10 Institutional Area, Vasant Kunj, New Delhi, Delhi 110070, India. ; Stockholm Resilience Centre, Stockholm University, 10691 Stockholm, Sweden. Natural Resources and the Environment, CSIR, P.O. Box 320, Stellenbosch 7599, South Africa. ; Division of History of Science, Technology and Environment, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25592418" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere ; *Biological Evolution ; *Climate Change ; *Earth (Planet) ; Fresh Water ; Humans ; *Ozone Depletion
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2016-01-09
    Description: Human activity is leaving a pervasive and persistent signature on Earth. Vigorous debate continues about whether this warrants recognition as a new geologic time unit known as the Anthropocene. We review anthropogenic markers of functional changes in the Earth system through the stratigraphic record. The appearance of manufactured materials in sediments, including aluminum, plastics, and concrete, coincides with global spikes in fallout radionuclides and particulates from fossil fuel combustion. Carbon, nitrogen, and phosphorus cycles have been substantially modified over the past century. Rates of sea-level rise and the extent of human perturbation of the climate system exceed Late Holocene changes. Biotic changes include species invasions worldwide and accelerating rates of extinction. These combined signals render the Anthropocene stratigraphically distinct from the Holocene and earlier epochs.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Waters, Colin N -- Zalasiewicz, Jan -- Summerhayes, Colin -- Barnosky, Anthony D -- Poirier, Clement -- Galuszka, Agnieszka -- Cearreta, Alejandro -- Edgeworth, Matt -- Ellis, Erle C -- Ellis, Michael -- Jeandel, Catherine -- Leinfelder, Reinhold -- McNeill, J R -- Richter, Daniel deB -- Steffen, Will -- Syvitski, James -- Vidas, Davor -- Wagreich, Michael -- Williams, Mark -- Zhisheng, An -- Grinevald, Jacques -- Odada, Eric -- Oreskes, Naomi -- Wolfe, Alexander P -- New York, N.Y. -- Science. 2016 Jan 8;351(6269):aad2622. doi: 10.1126/science.aad2622.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. ; Department of Geology, University of Leicester, University Road, Leicester LE1 7RH, UK. ; Scott Polar Research Institute, Cambridge University, Lensfield Road, Cambridge CB2 1ER, UK. ; Department of Integrative Biology, Museum of Paleontology, and Museum of Vertebrate Zoology, University of California-Berkeley, Berkeley, CA 94720, USA. ; Morphodynamique Continentale et Cotiere, Universite de Caen Normandie, Centre National de la Recherche Scientifique (CNRS), 24 Rue des Tilleuls, F-14000 Caen, France. ; Geochemistry and the Environment Division, Institute of Chemistry, Jan Kochanowski University, 15G Swietokrzyska Street, 25-406 Kielce, Poland. ; Departamento de Estratigrafia y Paleontologia, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco/Euskal Herriko Unibertsitatea, Apartado 644, 48080 Bilbao, Spain. ; School of Archaeology and Ancient History, University of Leicester, University Road, Leicester LE1 7RH, UK. ; Department of Geography and Environmental Systems, University of Maryland-Baltimore County, Baltimore, MD 21250, USA. ; Laboratoire d'Etudes en Geophysique et Oceanographie Spatiales (CNRS, Centre National d'Etudes Spatiales, Institut de Recherche pour le Developpement, Universite Paul Sabatier), 14 Avenue Edouard Belin, 31400 Toulouse, France. ; Department of Geological Sciences, Freie Universitat Berlin, Malteserstrasse 74-100/D, 12249 Berlin, Germany. ; Georgetown University, Washington, DC, USA. ; Nicholas School of the Environment, Duke University, Box 90233, Durham, NC 27516, USA. ; The Australian National University, Canberra, Australian Capital Territory 0200, Australia. ; Department of Geological Sciences, University of Colorado-Boulder, Box 545, Boulder, CO 80309-0545, USA. ; Marine Affairs and Law of the Sea Programme, The Fridtjof Nansen Institute, Lysaker, Norway. ; Department of Geodynamics and Sedimentology, University of Vienna, A-1090 Vienna, Austria. ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, Beijing Normal University, Beijing 100875, China. ; Institut de Hautes Etudes Internationales et du Developpement, Chemin Eugene Rigot 2, 1211 Geneve 11, Switzerland. ; Department of Geology, University of Nairobi, Nairobi, Kenya. ; Department of the History of Science, Harvard University, Cambridge, MA 02138, USA. ; Department of Biological Sciences, University of Alberta, Edmonton, Alberta T6G 2E9, Canada.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/26744408" target="_blank"〉PubMed〈/a〉
    Keywords: Aluminum/analysis ; *Biota ; Carbon Cycle ; Climate ; Construction Materials/analysis ; *Earth (Planet) ; Fossil Fuels/adverse effects ; Geologic Sediments/*chemistry ; *Human Activities ; Humans ; Ice/analysis ; Introduced Species ; Plastics/analysis ; Radioactive Fallout/analysis ; Radioisotopes/analysis
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 4171-4179 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Depolarized Rayleigh spectra of ortho-terphenyl (OTP) were measured in the temperature range from Tg to Tg+190 K. Two samples prepared with and without "clusters'' were used for the measurement. Four different Fabry–Perot interferometers covering the time range from about 0.5 ps to 100 ns were employed. Two relaxation modes were observed: a slow mode with all its characteristics of the α process, and a fast mode with a constant, temperature independent relaxation time of about 3 ps. The fast mode has not been reported heretofore. The intensity of the fast mode vanishes at about the Vogel–Fulcher–Tamman temperature T0. The relaxation times of these two processes are found to be identical for both OTP with and without clusters. The temperature dependence of the relaxation time of the α process is Arrhenius at high temperatures, but shows a Williams–Landel–Ferry (WLF) behavior in the range from Tg to Tg+80 K for both samples with and without the long-range density fluctuations (i.e., cluster).
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 695-703 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Depolarized Rayleigh scattering (DRS) and dielectric spectroscopy (DS) are employed to study the solvent and polymer dynamics in the polystyrene (PS)/toluene system and for PS concentration up to 0.6 g/ml. The DRS measurements were made in the temperature range from 255 to 373 K with different interferometers making possible the separation of the "fast'' solvent (in the ps time scale) from the "slow'' polymer dynamics (in the ns time scale). The DS measurements were made in the temperature range from 128 to 310 K and two processes could also be observed. With DRS and DS we investigate the very different mobilities in the PS/toluene solutions over a frequency range of ∼10 decades. The prominent features of the experimental data are (i) the existence of two primary (α−) relaxations in the macroscopically homogeneous solutions which have been analyzed using both techniques and (ii) that these relaxations reflect the polymer and solvent dynamics and display the usual Vogel–Fulcher–Tammann behavior, however, with a broad distribution of relaxation times, especially at low temperatures. The existence of two time scales in the solutions is discussed in terms of concentration heterogeneities composed of PS-rich and toluene-rich domains, large enough to exhibit two glass transitions. As a result of the strong temperature dependence for the fast solvent reorientation times the rate of change of solvent friction with polymer concentration becomes temperature dependent at low temperatures.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 104 (1996), S. 248-254 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The decay of a spatial transient temperature grating created within the molecular glass former phenolphthalein-dimethylether (PDE) relates to the hydrodynamic heat diffusion and the dynamics of local density fluctuations. The characteristics of the latter process agree well with the structural α relaxation observed by photon correlation and dielectric spectroscopy near and above the glass transition temperature Tg. When the α-relaxation time approaches the experimental timescale set-in by the thermal diffusivity the specific heat undergoes a dispersion. In either side of this dynamic regime, heat diffusion and α relaxation are independent modes. "Two fluid'' models of the vitreous state conform to the experimental observations. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 113 (2000), S. 4751-4762 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Wide angle x-ray scattering and classical molecular-dynamics simulations were employed to study structural and dynamic properties of two low-molecular weight glass-forming liquids, propylene carbonate, and salol. We observe pronounced changes in the liquid structure as a function of temperature in a wide temperature range bracketing the glass transition temperature. The experimental and simulation results compare the x-ray scattering from the liquid slightly and far above the experimental glass transition temperature, Tgexp. The simulations largely reproduce the characteristic behavior of the experimental x-ray intensities, which is interpreted in terms of clusterlike heterogeneities forming in the liquid as Tgexp is approached. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 2312-2315 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A knee-shaped feature observed earlier in light scattering spectra of Ca0.4K0.3(NO3)1.4 (CKN) below Tc is used as a strong argument in favor of mode-coupling theory of the glass transition (MCT). Our careful measurements reveal no "knee" in the spectra of two glass forming liquids, CKN and ortho-terphenyl. Instead of the knee the spectra show nontrivial broadening and an increase of the intensity with a temperature increase. Both variations are confirmed by neutron scattering measurements on CKN and are neither expected in the asymptotic MCT predictions nor in any other model. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 8401-8408 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Depolarized dynamic light scattering (DDLS) experiments are performed on the glass forming materials ortho terphenyl (OTP), bis-methyl-methoxy-phenyl-cyclohexane (BMMPC), and bis-methyl-phenyl-cyclohexane (BMPC). Depolarized spectra are obtained for the bulk liquids and for solutions of varying concentration in CCl4. Effective optical anisotropies of the molecules are obtained from the solution spectra. A detailed analysis of the DDLS spectra, as well as a comparison with the results of quasielastic neutron scattering (QENS) experiments, indicates that the DDLS spectra in the bulk liquids result from at least two physical mechanisms: (i) The low frequency part of the spectrum, in the frequency range of the α peak, arises mainly from the molecular reorientation mechanism. The integrated intensity of this contribution is proportional to the square of the effective molecular anisotropy. (ii) At higher frequencies (but still below the Boson peak), the predominant contribution to the DDLS spectrum arises from interaction-induced scattering. The intensity of this contribution increases with increasing temperature (decreasing density) in the way expected for the cancellation effect. The implications of these results for the comparison of DDLS and QENS experiments and for the comparison of the data to the predictions of mode coupling theories of glass forming liquids are discussed. © 1997 American Institute of Physics.
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