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  • Polymer and Materials Science  (41)
  • CHEMISTRY  (19)
  • Inorganic Chemistry  (6)
  • Life and Medical Sciences  (6)
  • 1965-1969  (72)
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 1805-1806 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 4 (1966), S. 2831-2842 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetra- and heptanuclear N-heterocycles, their dimers and their polymers have been prepared by condensation of o-phenylenediamine or 3,3'-diaminobenzidine with 2,3-dihydroxyquinoxaline, 2,3,2,3'-tetrahydroxy-6,6'-bisquinoxaline, or 2,3,7,8-tetrahydroxy-1,4,6,9-tetraazaanthracene in polyphosphoric acid, or with the O-phenyl derivatives of the latter three compounds in phenol. The condensation products are highly colored compounds with characteristic absorption spectra. The polymers show good thermal stability.
    Additional Material: 1 Ill.
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  • 3
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The mechanism of respiration in the bullfrog has been analyzed by means of pressure recordings from the buccal cavity, the lungs and the abdominal cavity, by cinematography and cinefluorography, and by electromyography of buccal, laryngeal and abdominal muscles. Gas flow was investigated by putting frogs in atmospheres of changing argon and nitrogen content and monitoring the concentration of the nostril efflux.Three kinds of cyclical phenomena were found. (1) Oscillatory cycles consist of rhythmical raising and lowering of the floor of the mouth, with open nares. They have a definite respiratory function in introducing fresh air into the buccal cavity. (2) Ventilatory cycles involve opening and closing of the glottis and nares and renewal of a portion of the pulmonary gas. More muscles are involved and the pattern of muscular activity is more complex than in the oscillatory cycles. (3) Inflation cycles consist of a series of ventilation cycles, interrupted by an apneic pause. The intensity of the ventilatory cycles increases before this pause and decreases immediately thereafter. This results in a stepwise increase in pulmonary pressure, to a plateau (coincident with the pause) followed by a sudden or stepwise decrease.The respiratory mechanism depends on the activity of a buccal force pump, which determines pulmonary pressure whose level is always slightly less than the peak pressure values of the ventilation cycles. The elevated pulmonary pressure is responsible for the expulsion of pulmonary gas during the second phase of the next ventilation cycle. This pressure is maintained by the elastic fibers (and the smooth masculature) of the lungs.
    Additional Material: 16 Ill.
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  • 4
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The secretory processes in the shell gland of laying chickens were the subject of this study. Three cell types contribute secretory material to the forming egg: ciliated and non-ciliated columnar cells of the uterine surface epithelium, and cells of tubular glands in the mucosa. The ciliated cells as well as the non-ciliated cells have microvilli, which undergo changes in form and extent during the secretory cycle. At the final stages of shell formation they resemble stereocilia. It is postulated that the microvilli of both cells are active in the production of the cuticle of the shell.The ciliated cell which has both cilia and microvilli manufactures secretory granules which arise from the Golgi complex in varying amounts throughout the egg laying cycle. Granule production reaches its greatest intensity during the early stages of shell deposition. The ciliated cell probably supplies proteinaceous material to the matrix of the forming egg shell.The non-ciliated cell has only microvilli. Secretory granules, containing an acid mucopolysaccharide, arise from the Golgi complex. Some granules are extruded into the uterine lumen where they supply the egg shell with organic matrix. Others migrate towards the supranuclear zone. Here a number of them disintegrate. This is accompanied by the formation of a large membraneless space, which is termed “vacuoloid.” Subsequently the vacuoloid regresses and during regression an extensive rough endoplasmic reticulum with numerous polyribosomes of spiral configuration appears. It is suggested that material in the vacuoloid originating from the disintegrating granules is resynthesized and utilized for the formation of secretory product.The uterine tubular gland cells have irregular, frondlike microvilli. During egg shell deposition, these microvilli form large blebs and are probably related to the elaboration of a watery, calcium-containing fluid.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 1296-1299 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 859-864 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A linear polymer with a high melting point is obtained from the water-formaldehyde-hydrogen sulfide system in the presence of sulfuric acid. This polymer is substantially formed by a polythiomethylene chain with a few oxymethylene units. Its formation involves a topochemical reaction of the mercaptomethanol present in solution on the first separation solid of the system. On heating, the polymer loses oxymethylene units; in the same way, the first solid product separated from the system loses formaldehyde and undergoes a morphological and chemical transformation to polythiomethylene.
    Additional Material: 2 Tab.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 909-919 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ion-permselective membranes containing polyethylene in their base material have been examined by direct transmission electron micrography and x-ray diffraction. All of the electron micrographs showed white lines of about 100 A. thickness between somewhat thinner black lines composed of granules. These lines often occur as black-white-black triplets. We tentatively explain these structural elements by assuming that they are cross sections of the crystallite platelets, characteristic for polyethylene, reacted on both of their faces during sulfochlorination. It is known, that these platelets are about 100 A. thick, X-ray diffraction experiments also showed the characteristic lines of polyethylene crystallites, their intensity decreasing after sulfonation. The velocity of heterogeneous sulfochlorination of polyethylene sheets decreases abruptly when the film contains 6% S and 7% Cl (after hydrolysis). This m̰eans six substituted sites on a chain element across the platelet for a 100% crystalline film and accordingly less for a partially amorphous material. It is known that five CH2 groups of each chain element are exposed at the surface of the platelets, in good agreement with our findings.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 1073-1081 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic mechanical properties were determined in polypyromellitimide at acoustic frequencies over a wide temperature range (80-750°K). Two distinct secondary relaxation effects were found: one (β′) at lower temperature, characterized by a loss maximum at 250°K, and another (β) at higher temperatures with a loss maximum at 400°K. The lower temperature peak is shifted towards higher temperature with increasing frequency following an Arrhenius-type equation (apparent activation energy: 15 kcal/mole); the relaxation strength increases with water content and becomes practically zero when samples dried under vacuum at 200°C are examined. The β′ relaxation process is thus attributed to the presence of adsorbed water molecules. The higher-temperature (β) dispersion, which persists even after dehydration, on the basis of some results obtained for other polymers containing p-oxylphenylene rings in the backbone, is tentatively attributed to torsional oscillations of aromatic rings along the chain.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 1 (1967), S. 179-196 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Warp-knitted velour fabrics of Dacron, nylon, polypropylene, and Rayon have been backed with Silastic to form a laminate. Prior to heat curing, the composite can be molded into many shapes and has been successfully used to line the luminal side of blood pumps and vascular grafts. Prosthetic heart valves are being covered with velour in an attempt to promote a more compatible surface. Velour suture rings are being evaluated as a more efficient anchor for prosthetic heart valves. Silastic tubes with velour bonded to the outer wall have been used to inhibit infection and sinus tract formation where percutaneous lead wires and conduits are necessary. As a flat sheet, the Silastic-velour laminate has been used experimentally as an artificial skin, but the most noteworthy experimental results have been obtained in rats using a double layer of nylon velour, separated by an impermeable layer of poly(vinyl fluoride). Future application will include attempts to anchor artificial limbs via a velour interface and made functional by tendinous attachment.
    Additional Material: 16 Ill.
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  • 10
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The fusion in vitro of embryonic myoblasts to form multinucleated myotubes requires the addition of serum to a basal nutrient medium. The serum requirement for fusion can be satisfied by insulin with somatotropin potentiating its effect. Myotubes formed under these conditions fail to differentiate to cross-striated, spontaneously contractile muscle fibers. This arrest of development is reversible if serum is restored to the medium.Development of the enzyme glycogen synthetase was studied as an additional indicator of muscle differentiation. In cultures developing in the presence of serum, this enzyme was demonstrated by autoradiography to be highly concentrated in myotubes as compared to mononuclear cells. The activity of the enzyme remains low in (1) cultures formed in response to insulin and somatotropin in the absence of serum, as well as (2) in cultures formed in unsupplemented basal medium which are virtually lacking in myotubes. The addition of serum to (1) restores the development of this enzyme. Serum which has been extensively digested with the proteolytic preparation, pronase, and subjected to boiling temperature, when combined with insulin and somatotropin is also capable of promoting the development of glycogen synthetase to a specific activity which exceeds the control. The serum factor is not lost on exhaustive dialysis, nor can enzyme promoting activity be liberated by heat denaturation of serum proteins.
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