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  • Polymer and Materials Science  (658)
  • Life and Medical Sciences  (98)
  • Anaplerotic sequences  (1)
  • ASTROPHYSICS
  • Genetics
  • Wiley-Blackwell  (757)
  • 1965-1969  (757)
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Keywords
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  • Wiley-Blackwell  (757)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Infrared and nuclear magnetic resonance of maleic anhydride copolymers and their half esters (1968)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 2191-2200 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Infrared and NMR group-type methods for the analysis of the anhydride content of maleic anhydride copolymers such as poly(maleic anhydride-co-α-olefin) and the half ester content of their reaction products with alcohols are described. The infrared analyses are based on the integrated absorptivities of the anhydride carbonyl and the combination of the acid and ester carbonyl. The NMR method is based on the intensities of the various chemically shifted groups in the copolymer. The use of dimethyl sulfoxide as an auxiliary solvent has made the infrared analysis possible.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1968.070121001
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  • 2
    Electronic Resource
    Electronic Resource
    Panel discussion: Present status and perspectives in the study of cytodifferentiation at the molecular level. II. Discussion (1968)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 72 (1968), S. 219-230 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1040720415
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  • 3
    Electronic Resource
    Electronic Resource
    Poly(arylene sulfones) prepared by friedel-crafts reactions (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 1802-1804 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150050728
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  • 4
    Electronic Resource
    Electronic Resource
    Kinetics of alcohol-isocyanate reactions with metal catalystsFrom a thesis to be submitted by B. Thir to the Graduate School of the University of Detroit in partial fulfillment of the requirements for the M.S. degree in chemistry. (1965)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 1787-1795 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study has been conducted of the kinetics of the reactions of primary and secondary alcohols with phenyl isocyanate in the presence of metal catalysts. It has been determined that the type and concentration of metal catalyst, the structure of the alcohols, and the type of solvent play an important role in the reaction rates and ratios of rate constants. Catalysis by lead naphthenate increased the reaction rates of 2-methoxy-l-propanol and 1-methoxy-2-propanol more than 3-methoxy-1-propanol, whereas catalysis by dibutyltin dilaurate enhanced the reaction rates of 3-methoxy-1-propanol more than those of 2-methoxy-1-propanol and of 1-methoxy-2-propanol. Dibutyltin dilaurate has been found to impart a high ratio of Kprimary/Ksecondary, where the primary alcohol was 3-methoxy-1-propanol and the secondary alcohol was 1-methoxy-2-propanol. Determinations of mixtures in toluene solutions containing up to 75%, of 3-methoxy-1-propanol were made with good accuracy.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1965.070090514
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  • 5
    Electronic Resource
    Electronic Resource
    Some viscoelastic properties of ABS polymer (1968)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 1343-1353 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The discrete relaxation spectrum of an ABS (acrylonitrile-butadiene-styrene) polymer at 190°C. was calculated by using results from tensile relaxation moduli and the principle of reduced variables. The shift factor was found to conform well to the WLF equation, and the free volume fraction at Tg was calculated to be 0.026 in good agreement with the universal value. The values of the thermal expansion coefficient of free volume were calculated to be 9.8 X 10-4 deg.-1 and 7.0 × 10-4 deg.-1, respectively, from the WLF coefficients and from dilatometric results. The width of the entanglement plateau of the relaxation spectrum was observed to be a factor of approximately 2 larger than that calculated from molecular weights between entanglement couplings determined either from rubber elasticity theory or from an assumed molecular model which discounts the presence of the butadiene in the ABS system. By using Pao's theory, flow curves at 190°C. were calculated both from the discrete relaxation spectrum and from the dynamic modulus. These curves were essentially identical. However, the stress values of these curves were found to be about a decade higher than those experimentally determined from capillary flow measurements. Nevertheless, the shapes of the curves are in good agreement, and an explanation is suggested for existing discrepancies. Flow instability, processing variables, and residual strains are discussed in light of the flow curves and the calculated recoverable shear strains.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1968.070120606
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  • 6
    Electronic Resource
    Electronic Resource
    The influence of intermolecular hydrogen bonding on the flow behavior of polymer melts (1969)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 2721-2733 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of hydrogen bonding on the flow behavior of polymer melts at high shear rate has been investigated using a capillary extrusion rheometer. The systems studied were copolymers of ethylene and acrylic or methacrylic acid. Hydrogen bonding was found to substantially enhance both flow activation energy and viscosity level, as well as the degree of dependence of viscosity on rate of shear. It was also found that hydrogen bonding does not influence the critical shear stress for onset of “melt fracture.” The data support the view that hydrogen bonds act effectively as temporary (quasi-) crosslinks during the short time scales of deformation involved in flow at high shear rates.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1969.070131219
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  • 7
    Electronic Resource
    Electronic Resource
    Effect of stereosequence length on crystallization kinetics of propylene oxide polymersPresented to the Division of Polymer Chemistry, 150th American Chemical Society Meeting, Atlantic City, N. J., September 1965. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 715-729 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Crystallization kinetics of crystalline fractions of propylene oxide polymers made with different catalysts have been studied by isothermal dilatometric and microscopical measurements. Isothermal microscopical measurements indicate that spherulite growth in these polymers proceeds from predetermined nuclei. The half time for spherulitic appearance is less than, but of the same order as, the half time for complete crystallization. Only by taking this factor into account can the dilatometric data be represented by the Avrami equation. The deviation of the crystallization isotherm from that predicted from the microscopical data using the Avrami theory is attributed to a secondary crystallization process taking place within the spherulite. Crystallization continues long after spherulites completely occupy the available volume in the polymer. By assuming that the secondary crystallization proceeds as a first-order process in the uncrystallized, but crystallizable, portions of the melt, it is shown that the crystallization isotherms can be completely described in terms of four parameters. These are: (1) the time constant for the primary crystallization process; (2) the time constant for nucleation; (3) the time constant for the secondary crystallization process, and (4) the extent of secondary crystallization. The important conclusions of these studies are: the rates of nucleation and of spherulitic growth are far more dependent on temperature than on stereoregularity; the ratio of the rate of the secondary crystallization process to that of the primary crystallization process is almost independent of temperature, but increases with increasing stereoregularity of the polymer.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040505
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  • 8
    Electronic Resource
    Electronic Resource
    The development of neuromasts in Cirrhina mrigala Ham. Buch. (Cyprinidae) and Ophicephalus (Channa) punctatus Bloch (Channidae) (1967)
    New York, NY : Wiley-Blackwell
    Journal of Morphology 122 (1967), S. 321-343 
    Details
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The development of neuromasts was studied in two species of teleosts, Cirrhina mrigala Ham. Buch. and Ophicephalus punctatus Bloch, and the findings are presented and discussed. It has been discovered, in the course of this investigation, that a neuromast arises by a process of invagination  -  a fact hitherto not reported. The occurrence of the dorsal lateral line and the accessory lateral line of the trunk, in addition to the main lateral line, has also been reported for the first time for teleosts, although known for other bony fishes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jmor.1051220404
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  • 9
    Electronic Resource
    Electronic Resource
    Some rheological properties of molten polypropylene (1968)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 6 (1968), S. 871-883 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The following measurements were carried out on the melts of two samples of polypropylene, one with a narrow and one with a broad molecular weight distribution: viscosity in steady shear flow, dynamic storage and loss moduli, total normal thrust in cone-and-plate apparatus, and flow birefringence. The validity of various theoretical interrelations between the measured quantities is checked. The influence of molecular weight distribution is qualitatively discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1968.160060507
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  • 10
    Electronic Resource
    Electronic Resource
    Elastomeric and mechanical properties of poly-m-carboranylenesiloxanes (1966)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1725-1735 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new high-temperature elastomer, SiB-2, has been investigated by stress relaxation, modulus-temperature, and volume--temperature techniques. SiB-2 was found to be more stable than a related elastomer, radiation-cured silicone rubber, having about twice as long as a chemical relaxation time at 250°C. Possible mechanisms to account for this increased stability are discussed. At low temperatures, Tg for SiB-2 was estimated at -34°C., which compares well with Ti = -30°C. for this polymer. By comparison, SiB-3 has Ti = -60°C., while phenyl-modified SiB-4 was found to have Ti = -25°C. Tm for SiB-2 was estimated to be + 56°C.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1966.070101111
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