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  • Physics  (14)
  • CHEMISTRY  (6)
  • Chemical Engineering  (4)
  • 1970-1974  (24)
  • 1930-1934
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 345-352 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bifunctional arylcyanoacetic esters were oxidatively coupled to high molecular weight, colorless, amorphous polymers, soluble in common organic solvents. Brittle films were obtained by casting or compression molding. Thermal stability of the polymers is poor due to the weak C—C bond formed by oxidative coupling. Radical dissociation-recombination of this bond (evidenced by ESR) results in meso-dl equilibration, lowering the Tg of the polymers.
    Additional Material: 2 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 9 (1971), S. 1893-1899 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The thermal bulk polymerization of cholesteryl acrylate was carried out in the solid phase, the mesomorphic phase, and the liquid phase to study the effect of monomer ordering on polymerization rate and polymer properties. The rate increased with decreasing ordering (or enhanced mobility) of the monomer. Formation of inhibitive by-products during the polymerization limited conversions to 35%. The sedimentation constant S0 = 6.2 S was the same for the polymers obtained in the three phases. The weight-average molecular weight (M̄w) was 480,000 as determined by ultracentrifugation. Poly-(cholesteryl acrylate) formed in bulk is randomly coiled when dissolved in tetrahydrofuran. The thermal properties of the monomer are given.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1005-1010 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Free convection between two vertical coaxial cylinders was studied by solving the governing transport equations as an initial-value problem. The coupled, nonlinear, partial differential equations were converted into a set of difference equations by use of an alternating-direction implicit finite-difference numerical scheme. Twenty-four different combinations of Prandtl and Grashof numbers, and height to annular spacing ratios were used to characterize the problem. The results are presented primarily in the form of contour maps for the steady-state isotherms and streamlines.For Rayleigh numbers greater than 5 × 103, a fully developed boundary-layer flow was found to exist in the cavity. The interior region of the annulus was found to be thermally stratified and to possess a nearly uniform vertical temperature gradient, with a unicellular flow pattern being generated.With Rayleigh numbers of 5 × 104 and greater, it was found that the flow patterns could not be properly described with a grid spacing of 1/10. The variation of the steady-state mean Nusselt number with Prandtl and Rayleigh numbers and with geometric ratios was also investigated.
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 182-186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The gravity-driven coalescence of 1- to 2-cm. diameter air bubbles in glycerine and in water has been studied by high-speed cinematography. The resulting coalescence behavior can be correlated by a simple model which assumes that each bubble trails a wake, and that the bubble coalescing from below accelerates when it enters the wake of the preceding bubble and thus overtakes the first bubble. The predictions of the model are not significantly altered by different assumed wake configurations.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 670-670 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1226-1229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drop formation from submerged nozzles was studied using liquid-liquid systems of widely varying properties. The data were correlated using a momentum balance and a two-stage process of drop formation. The average agreement between data and correlation was 6.3%.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 715-720 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The elastic behavior of different types of rubbery polymers (natural rubber, polybutadiene, silicone, and polyisoprene) networks at various degrees of vulcanization and swelling was examined in extension and compression. The data are represented by the Mooney-Rivlin equation. In compression, although C2 is zero, C1 decreases strongly with increasing swelling to a limiting value which, in some cases, may be correlated with the value of C1 found in extension and hence related to the theoretical modulus for highly swollen networks. A possible explanation is presented in terms of supramolecular order in the amorphous materials.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 975-981 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Samples of cis-polybutadiene were cross-linked in the presence of decalin at values of φr (the volume fraction of rubber) ranging from 0.25 to 0.50. After the diluent had been removed, a study was made of the force-extension and thermoelastic behavior of the networks. Within experimental error, the ratio of the Mooney-Rivlin constants 2C2/2C1 was found to be zero for networks prepared at low φr (0.25 and 0.30) but started to increase towards the conventional value at higher φr. The quantity fe/f was found to be independent of the ratio 2C2/2C1 and of the extension ratio α; the average value of fe/f was found to be 0.11.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 1621-1624 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 11 (1973), S. 2291-2295 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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