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  • Physics  (296)
  • COMMUNICATIONS  (238)
  • Analytical Chemistry and Spectroscopy  (235)
  • Cell & Developmental Biology
  • GENERAL
  • 1970-1974  (1,000)
  • 1955-1959  (57)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 445-454 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The fundamental vibrational frequencies of an isolated chain of cis-1,4-polybutadiene have been calculated. Infrared and polarized Raman data are used in the force constant refinement routine. The assignments of the vibrational frequencies are discussed in terms of the potential energy distribution.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acrylonitrile (AN) was graft-polymerized onto gelatinized cationic starch (CS) possessing diethylaminoethyl ether groups by cerium (IV) initiation to give stable latexlike copolymer dispersions. Dispersions of the latex copolymers, having up to 50% grafted polyacrylonitrile (PAN), air- and heat-dry on glass to clear, adhesive films. Sonification of up to 8% dispersions at 20 Khz reduced their viscosities from 1500-3000 cP to 15-40 cP. Scanning electron microscopy revealed that both nonsonified and sonified dispersions consist of ball-like particles measuring about 0.05-0.15 μ in diameter when dry. The films are formed by coalescence of these particles. The degree to which AN grafts onto CS at ambient temperature is related to the nitrogen content of CS, gelatinization time of CS at 95°C, sequence of AN and cerium(IV) addition, concentration of cerium (IV), concentration of AN, and severity of reaction agitation. Number-average molecular weight values of PAN were about 106 when grafting was conducted under stirring and about 5 × 105 when conducted under shaking action.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 1213-1224 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthetic details of solution polymerization in benzene and bulk polymerization of vinylferrocene are reported. In benzene solutions, with azobisisobutyronitrile (AIBN) as the initiator, small yields of low-polydispersity low molecular weight (M̄n ≃ 5000) polyvinylferrocene is obtained. However, high yields can be obtained by continuous or multiple AIBN addition. Higher molecular weight polymers and binodal polymers can be obtained as the monomer concentration is increased. In bulk polymerizations, yields of 80% can be obtained. The molecular weight increases as temperature decreases from 80 to 60°C in bulk polymerizations, and an increasing amount of insoluble polymer results. The soluble portion is often binodal, the higher molecular weight node consisting of an increasingly branched structure. Lower molecular weight polymer was readily fractionated into narrow fractions from benzene-methanol systems, but higher molecular weight polymer proved impossible to fractionate into narrow fractions due to branching.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2011-08-16
    Description: The objectives of the Apollo 17 Lunar Sounder Experiment (ALSE) were to detect subsurface geologic structures, to generate a continuous lunar profile, and to image the moon at radar wavelengths. A three-wavelength synthetic-aperture radar (SAR) operating at 60, 20, and 2 m wavelengths was designed to attain these objectives. The design choices reflected a balance of scientific requirements versus Apollo mission and hardware constraints. The radar data from the lunar mission were recorded on photographic film in a conventional SAR format, and were returned to earth for processing. A combination of optical and digital processing and exploitation techniques was applied to the scientific interpretation of the data. Some preliminary results from the lunar mission have been obtained.
    Keywords: COMMUNICATIONS
    Type: IEEE; vol. 62
    Format: text
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  • 5
    Publication Date: 2016-06-07
    Description: A color-television display system and interactive graphics equipment on-line to an IBM 360/44 computer are used to develop a variety of interactive displays which aid in analyzing remote sensor data. These interactive displays are used to: (1) analyze data from a multispectral scanner; (2) develop automatic pattern recognition systems based on multispectral scanner measurements; and (3) analyze data from non-imaging sensors such as the infrared radiometer and microwave scatterometer.
    Keywords: COMMUNICATIONS
    Type: Its 3d Ann. Earth Resources Program Rev., Vol. 2; p 19
    Format: application/pdf
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  • 6
    Publication Date: 2019-06-27
    Keywords: GENERAL
    Type: NASA-CR-126424 , Am. Assoc. for Advan. of Sci. Mariner to Mars; 4 p
    Format: text
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  • 7
    Publication Date: 2019-06-27
    Description: A method for analysis and classification of verbal communications typically associated with manned space missions or simulations was developed. The study was carried out in two phases. Phase 1 was devoted to identification of crew tasks and activities which require voice communication for accomplishment or reporting. Phase 2 entailed development of a message classification system and a preliminary test of its feasibility. The classification system permits voice communications to be analyzed to three progressively more specific levels of detail and to be described in terms of message content, purpose, and the participants in the information exchange. A coding technique was devised to allow messages to be recorded by an eight-digit number.
    Keywords: COMMUNICATIONS
    Type: NASA-CR-128837
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  • 8
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Development of the secondary palate in Swiss white mouse embroyos was studied from age nine-and-one-half days in utero to the stage of mesenchymal coalescence in the secondary palate (approximately fifteen-and-one-half days). The greatest changes observed occur in the mesenchyme. At early stages, mesenchymal cells underlying oral ectoderm of the head are few and only occasionally contact the ectoderm. Electron micrographs show large intercellular spaces between the ectodermal cells. As embryogenesis continues, the mesenchymal cells become more numerous, closer to each other and closer to the epithelium. Just prior to horizontal transposition of shelves, the mesenchymal cells spread farther from each other and from the palatal epithelium and epithelium of the palatal tip becomes stretched. Ultrastructurally the intercellular spaces between epithelial cells of the palate tip have become much smaller. Some mitochondria in some epithelial cells are swollen and have clear matrices and distorted cristae. The shelves become horizontal and meet in the midpalate. Cells with degeneration bodies are seen in the epithelial seam. The seam undergoes autolysis and is replaced by mesenchyme. The morphological changes described, particularly in the mesenchyme, may play an important role in determining the effect of various teratogens at different stages of palatal development. The changes in both mesenchyme and epithelial cells in the later stages may constitute part of the process of preparing shelves for fusion as postulated by Pourtois ('66).
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 869-882 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystallization kinetics of a high molecular weight fraction of linear polyethylene was studied in dilute solutions of p-xylene, n-hexadecane, and decalin by dilatometric methods. For all solvents and temperatures, the experimental isotherms could be quantitatively described by the Avrami formulation for the complete transformation. This result is unique in the realm of polymer crystallization, since marked deviations from this theory are usually observed in more concentrated systems. The Avrami exponent is found to be n = 4 in all cases. The temperature coefficients of the rate constants are indicative of a nucleation controlled process. The data fit either a two-dimensional or three-dimensional nucleation mode, and a discrimination can not be made between these two cases. The interfacial free energies are found to be independent of the solvent medium. It is also shown that, irrespective of the type of nucleation control governing the kinetics, the same type governs the crystallite thickness of the lamella-like crystals that are formed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 1415-1445 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A reaction rate model of fracture in polymer fibers is described. This model assumes that bond rupture is governed by absolute reaction rate theory with a stress-aided activation energy. It is demonstrated that the key in obtaining good agreement between the model and experiment lies in taking proper account of the variation of stress on the tie-chain molecules. The more taut chains rupture first, and the load is redistributed among the remaining unruptured tie chains. The effect of varying the temperature both in the model and in experiments on fracture in fibers is explored. Good agreement between predictions of the model and experiment is possible only with an undeterstanding of the distribution in stress on the tie chains. The distribution in stress on the chains was experimentally determined by monitoring the kinetics of bond rupture with electron paramagnetic resonance (EPR) spectroscopy. Temperature is found to have two effects on macroscopic strength. (1) The thermal energy aids the atomic stress in breaking the atomic bonds; as a consequence the rate of bond rupture of a family of bonds under a given molecular stress is increased. In this respect temperature might be viewed as decreasing the “strength” of a bond. (2) Temperature also serves to “loosen” the molecular structure and in this way modify the distribution in stress on the tie chains. To explain bond rupture and macroscopic fracture behavior quantitatively, account must be taken of both effects.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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