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  • General Chemistry  (18)
  • Inorganic Chemistry  (11)
  • Analytical Chemistry and Spectroscopy  (3)
  • 78.55.-m  (2)
  • 68.55.+b  (1)
  • 1980-1984  (21)
  • 1965-1969  (14)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 33 (1984), S. 97-105 
    ISSN: 1432-0630
    Keywords: 78.65.-s ; 71.70.-d ; 68.55.+b
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Low-temperature photoluminescence measurements on nominally undoped AlxGa1−xAs/GaAs quantum well heterostructures (QWHs) grown by molecular beam epitaxy (MBE) exemplified the exclusivelyintrinsic free-exciton nature of the luminescence under moderate excitation conditions. Neither any spectroscopic evidence for alloy clustering in the AlxGa1−xAs barriers nor any extrinsic luminescence due to recombination with residual acceptors has been detected in single and double QWHs when grown at 670 °C under optimized MBE growth conditions. Carrier confinement in AlxGa1−xAs/GaAs QWHs starts at a well width ofL z≌30 nm when x≌0.25. The minor average well thickness fluctuation ofΔL z=4×10−2nm as determined from the excitonic halfwidth allowed the realization of well widths as low asL z=1 nm and thus a shift of the free-exciton line as high as 2.01 eV which is close to the conduction band edge of the employed Al0.43Ga0.57As confinement layer. The measurements further revealed a strongly enhanced luminescence efficiency of the quantum wells as compared to bulk material which is caused by the modified exciton transition probabilities due to carrier localization.
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  • 2
    ISSN: 1432-0630
    Keywords: 68.55.+ b ; 71.55.-i ; 72.20.-i ; 78.55.-m
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Hall effect, DLTS and low-temperature photoluminescence measurements were used to study the effect of dimeric (As2) vs tetrameric (As4) vapour species on the electrical and optical properties of nominally undoped and of Ge-doped GaAs layers grown by molecular beam epitaxy (MBE). The arsenic molecular beam was generated from separate As2 and As4 sources, respectively, and from a single source providing an adjustable As2/As4 flux ratio. The occurence of the previously described defect related bound exciton lines in the luminescence spectra at 1.504–1.511 eV was found to be directly correlated with the presence of three deep states (M1, M3, M4) which are characteristic of MBE grown GaAs. The intensity of the extra luminescence lines and simultaneously the concentration of the deep electron traps can be reduced substantially simply by decreasing the As4/As2 flux ratio. The incorporation of defect related centers as well as of amphoteric dopants like Ge strongly depends on the surface chemistry involved. Therefore, a considerably lower autocompensation ratio in Ge-dopedn-GaAs is obtained with As2 molecular beam species which provide a higher steady-state arsenic surface population.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 33 (1984), S. 9-17 
    ISSN: 1432-0630
    Keywords: 81.15.-z ; 78.55.-m ; 78.20.-e
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Nominally undoped AlxGa1−xAs grown by molecular beam epitaxy from As4 species at elevated substrate temperatures of 670°C exhibits well-resolved excitonic fine structure in the low-temperature photoluminescence spectra, if the effective As-to-(Al+Ga) flux ratio on the growth surface is kept within a rather narrow range of clearly As-stabilized conditions. In contrast to previous results on AlxGa1−xAs of composition 0.15〈x〈0.25, the prominent carbon-related recombination at ∼23 meV below the bound exciton line was foundnot to shift in energy by changing the excitation intensity. This implies a simple freeelectron carbon-acceptor recombination mechanism for the line without any participation of a donor. In AlxGa1−xAs of composition close to the direct-to-indirect cross-over point, two distinct LO-phonons separated by 34 and 48 meV from the (D 0,C 0) peak position at x=0.43 were observed which were before only detectable by Raman scattering experiments. The intensity of the carbon-impurity related luminescence lines in bulk-type AlxGa1−xAs and GaAs layers was found to be strongly reduced, as compared to the excitonic recombination lines, if the respective active layer was covered by a very thin confinement layer of either GaAs on top of AlxGa1−xAs or vice versa grown in the same growth cycle.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 99 (1966), S. 1704-1711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In Ergänzung der II. Mitteilung wurden mit Hilfe säurestabiler Diazoverbindungen die Protonenaktivitäten starker und sehr starker Säuren (bis zur Chlorsulfonsäure) bestimmt, sowie diese Säuren nach Ermittlung der Säureempfindlichkeitskonstanten der Diazoverbindungen an die früher aufgestellte dynamische Aciditätsreihe nach oben angeschlossen. Dadurch konnte der der Messung zugängliche lückenlose Aciditätsbereich auf nunmehr ca. 16 pk-Einheiten erweitert werden.
    Additional Material: 3 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 3748-3756 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die NMR- und IR-Spektren einer Reihe von sekundären und tertiären Oxoniumsalzen (sowie einiger Vergleichsverbindungen) werden im Hinblick auf die chemische Verschiebung der verschiedenen Protonensignale und auf den Nachweis sehr stabiler Protonenbrücken in den Ätheraddukten der sekundären Oxoniumsalze diskutiert.
    Additional Material: 5 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 3757-3764 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konfiguration des mesomeriefreien dreibindigen Oxonium-O-Atoms wurde durch Synthese des chinuclidinanalogen 1-Oxonia-bicyclo[2.2.2]octan-Ringsystems im Sinne einer pyramidalen Ligandenanordnung sichergestellt (zumindest für diesen Spezialfall). Der zweite Ringschluß gelingt wegen der ungünstigen Konformationsverhältnisse nur in geringen Ausbeuten und nur bei der Umsetzung von 4-[β-Jod-äthyl]-tetrahydropyran mit Silber-hexafluoroantimonat, während mit Silber-tetrafluoroborat als Ausweichreaktion eine intermolekulare Alkylierung des Äthersauerstoffs zu einem Polyoxoniumsalz erfolgt.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 98 (1965), S. 3765-3776 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Auf Grund der schon früher zur Messung von Säurestärken verwandten Geschwindigkeit der Säurezersetzung aliphatischer Diazoverbindungen wurde ein Aciditätsbestimmungsverfahren ausgearbeitet, das bei Verwendung mehrerer Diazoverbindungen abgestufter Säureempfindlichkeit einen bereits nahezu 10 Zehnerpotenzen breiten Aciditätsbereich lückenlos erfaßt. Die als Maß der Aciditätsdifferenz zweier Säuren dienenden Quotienten der Reaktionsgeschwindigkeitskonstanten sind innerhalb der Fehlergrenzen unabhängig von den jeweils zur Messung verwandten Diazoverbindungen, so daß eine rechnerische Eliminierung des Einflusses der letzteren und damit die Aufstellung einer eindeutigen Aciditätsreihe ermöglicht wird.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 99 (1966), S. 566-574 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die PMR-Spektren von cis- und trans-2.3-Dichlor-dioxan werden im Hinblick auf chemische Verschiebungen und Kopplungskonstanten vollständig analysiert. An Hand dieser Parameter werden die Konformationen beider Verbindungen diskutiert.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 115 (1982), S. 804-807 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acetylenedicarbonyl DichlorideIn situ prepared carbonyl chloride 2 can be used as „activated acetylenedicarboxylic acid“ in Diels-Alder syntheses.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 79 (1967), S. 422-422 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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