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  • oxidation  (26)
  • Springer  (26)
  • American Geophysical Union
  • 1980-1984  (10)
  • 1975-1979  (14)
  • 1970-1974  (2)
  • 1935-1939
Collection
Keywords
Publisher
  • Springer  (26)
  • American Geophysical Union
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    The oxidation of Ni-70 wt.%Cr in oxygen between 1073 and 1473°K (1980)
    Springer
    Oxidation of metals 14 (1980), S. 263-277 
    Details
    ISSN: 1573-4889
    Keywords: oxidation ; Ni-Cr alloys ; two-phase alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation of the relatively simple, two-phase alloy Ni-70 wt.%Cr in oxygen between 1073 and 1473°K results in the formation of a Cr2O3 scale containing less than O.5 wt.% Ni in solid solution. The oxidation kinetics are irreproducible for an initial period, which is brief at 1073 and 1273°K but much more pronounced at 1473°K, both in duration and degree. This behavior is associated with the failure of the protective Cr2O3 scale. However, after longer periods a compact layer of Cr2O3 becomes established under isothermal conditions and results in a change to more reproducible kinetics, especially at 1073 and 1273°K. Oxidation causes chromium depletion and the formation of a single-phase zone which separates the scale and the two-phase bulk alloy. The depth of Cr2O3 internal oxide coincides with this zone. The oxidation behavior is compared with that of more Ni-rich, single-phase Ni-Cr alloys, with particular reference to the effects of the constitution of the underlying alloy and the integrity of the protective oxide.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00604568
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  • 2
    Electronic Resource
    Electronic Resource
    Oxidation of nickel-manganese alloys in the temperature range 873–1273 K (1982)
    Springer
    Oxidation of metals 18 (1982), S. 295-314 
    Details
    ISSN: 1573-4889
    Keywords: Nickel-manganese alloys ; oxidation ; solid solution scales ; internal oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Ni-Mn alloys containing up to 38% Mn have been oxidized in pure oxygen between 873 and 1273 K and the parabolic rate constants measured. The scale morphologies and oxide compositions are interpreted in terms of modifications to the scale on pure Mn caused by the presence of Ni. The scales are composed predominantly of two layers at all temperatures, giving the sequences of phases alloy/cubic monoxide (Ni, Mn)O/ternary spinel, with the cubic (Ni, Mn)O layer always having the greater thickness. There is limited evidence for a third, very thin, outer layer in the scales on all alloys at 873 K and for Ni-38%Mn at 1073 K, which is tentatively considered to be Mn2O3, giving layers in the order alloy/cubic monoxide/ternary spinel/Mn2O3, by analogy with the scale formed on pure Mn. The distribution of the alloy components in the scale is discussed in relation to the Ni-Mn-O phase diagram and in terms of recent theoretical treatments of solid solution scale formation on binary alloys, as far as the available diffusion data allow. The occurrence of internal and intergranular oxidation and the formation of a Mn-depleted zone coincident with the band of uniform internal oxide are considered briefly.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00656573
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  • 3
    Electronic Resource
    Electronic Resource
    Role of kinetic effects on metal partition at the alloy-scale interface during the oxidation of alloys (1975)
    Springer
    Oxidation of metals 9 (1975), S. 215-223 
    Details
    ISSN: 1573-4889
    Keywords: cation diffusion ; oxidation ; metal partition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An alternative mass balance at the alloy-scale interface is proposed for the Wagner theory of binary alloy oxidation. A simple relation between the bulk composition of the alloy and the scale composition at the alloy-scale interface, ξ′, is derived in terms of the transport properties of the scale and the limit of application of the relation defined. There is good agreement between calculated and measured values of ξ′.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00613274
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  • 4
    Electronic Resource
    Electronic Resource
    Thickness determination of oxide films on iron by electron back-scattering Mössbauer spectroscopy (1978)
    Springer
    Oxidation of metals 12 (1978), S. 247-256 
    Details
    ISSN: 1573-4889
    Keywords: oxidation ; iron ; magnetite ; oxide thickness ; electron back-scattering Mössbauer spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Magnetite films in the range 265–4520 Å have been grown on natural iron substrates and subsequently investigated by electron back-scattering Mössbauer spectroscopy. In particular, the percentage, P, of the total spectrum area contributed by the oxide has been determined as a function of oxide thickness, d. It was found that d up to ≈ 3000Å may be expressed (to an accuracy of ∼ 5%) by d (Å)=−1.95 × 103 ln (1–0.01 P). The experimental data have been compared with the theoretical predictions of both Huffman and Bainbridge. Good agreement between experiment and Huffman's predictions of P is obtained using values of the electron attenuation coefficient, μ, of 1.10 × 104 cm2 g−1 for the 7.3 keV electrons and 1.73 × 104 cm2 g−1 for the 5.4 keV electrons. A good fit of our data to Bainbridge's expression requires a somewhat lower effective μ, value of 0.8 × 104 cm2 g−1. The experimental P value for the thickest oxide (4520 Å) is lower than the theoretical predictions, probably as a result of a neglected mechanism recently identified by Tricker, Ash, and Cranshaw.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00616099
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  • 5
    Electronic Resource
    Electronic Resource
    Low-temperature oxidation of Fe-24 wt.%Cr (1979)
    Springer
    Oxidation of metals 13 (1979), S. 437-456 
    Details
    ISSN: 1573-4889
    Keywords: Fe-Cr ; oxidation ; kinetics ; oxide morphology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Ferritic polycrystalline Fe-24 wt.% Cr was oxidized in pure oxygen at 190 ≤ T≤490° C and pressures in the range 5.3×10−2–13.3 Pa for periods of up to 5 hr. The reaction proceeded in three stages. An initial period of accelerating rate was accompanied by oxide island nucleation and growth. Following island coalescence the rate was approximately logarithmic at low temperatures and somewhat slower than parabolic at high temperatures. Rate control during this period was thought to be due to mass transport through the oxide grain boundaries left by the island impingement process. During these first two stages the oxide formed was γ-M2O3 with possibly some spinel. The final stage of reaction involved the appearance of α-M2O3 on the outer oxide surface and a substantial slowing of the oxidation rate due to the low diffusivity in this phase.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00605109
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  • 6
    Electronic Resource
    Electronic Resource
    The pharmacokinetics of acetanilide and of diphenylhydantoin sodium (1974)
    Springer
    European journal of clinical pharmacology 7 (1974), S. 461-466 
    Details
    ISSN: 1432-1041
    Keywords: Acetanilide ; oxidation ; diphenylhydantoin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Medicine
    Notes: Summary Acetanilide and diphenylhydantoin have a similar first stage biotransformation in that both are oxidized in the para position of the benzene ring incorporated in each of the two molecules. The elimination of acetanilide from the plasma was studied in thirty healthy volunteer subjects following a single oral dose of 50 mg per kg metabolically active mass (MAM = weight to the power of 0.7). Plasma clearance values varied from 12.4 to 25.11 per hour. A dose of 5 mg diphenylhydantoin sodium (DPH) per kg MAM was then given thrice daily for 13 days to the same volunteers. The steady state plasma concentrations of DPH varied from 3.4 to 19.6 µg per ml. Statistically significant correlation was demonstrated between plasma acetanilide clearance and DPH clearance (r=+0.4984). This finding suggests either a common enzyme acceptor or a common rate-limiting step in the metabolism of the two drugs. It is possible that the pharmacokinetics of other widely used drugs known to be oxidized, especially phenylbutazone, may also be correlated with the kinetics of acetanilide and of DPH. If this were so, then certain individuals might be at a relatively high risk (due to drug accumulation) of developing adverse effects from drugs metabolized mainly by oxidation, and certain other individuals who metabolize these compounds at a fast rate are likely not to derive therapeutic benefit. A single dose study with simple measurement of acetanilide pharmacokinetics could be used to identify these groups.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00560359
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  • 7
    Electronic Resource
    Electronic Resource
    Metabolic oxidation of methaqualone in extensive and poor metabolisers of debrisoquine (1982)
    Springer
    European journal of clinical pharmacology 23 (1982), S. 147-150 
    Details
    ISSN: 1432-1041
    Keywords: methaqualone ; debrisoquine ; pharmacogenetics ; metabolism ; oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Medicine
    Notes: Summary The metabolism of methaqualone to the glucuronides of 5 C-monohydroxy metabolites and to the N-oxide has been studied in 2 groups of healthy young adults phenotyped as extensive and poor metabolisers of debrisoquine. No significant interphenotype differences were observed with respect to the excretion of any of the 6 metabolites. It is probable that the genetic regulation of the pathways leading to these metabolites is at a locus other than that which is responsible for the regulation of the oxidation of debrisoquine, guanoxan, phenacetin, phenytoin and sparteine.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00545969
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  • 8
    Electronic Resource
    Electronic Resource
    Effect of the possible fcc stabilizers Mn, Fe, and Ni on the high-temperature oxidation of Co-Cr alloys (1974)
    Springer
    Oxidation of metals 8 (1974), S. 393-407 
    Details
    ISSN: 1573-4889
    Keywords: cobalt alloys ; oxidation ; manganese
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Earlier studies have suggested that manganese might be attractive as an alternative fcc stabilizer to nickel in cobalt base alloys because of its beneficial effect on the sulfidation resistance. Because it has relatively high oxygen affinity, it seemed possible that it might modify the ability of the alloys to form a protective Cr 2O3 scale. Thus, a range of alloys having compositions close to the critical Co-20 Cr value have been investigated in the temperature range 900–1150° C for times up to 240 hr in air and oxygen. Similar, but less extensive studies, have been conducted on alloys containing iron or nickel. None of these elements has a significant effect on the oxidation behavior, or on the ability of the alloys to develop a protective Cr 2O3 layer. However, manganese has a significant adverse effect on the scale spallation, apparently because of its increasing the brittleness of the oxide, particularly the CoO.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00603389
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  • 9
    Electronic Resource
    Electronic Resource
    The oxidation and hot corrosion behavior of tungsten-fiber reinforced composites (1975)
    Springer
    Oxidation of metals 9 (1975), S. 45-67 
    Details
    ISSN: 1573-4889
    Keywords: oxidation ; hot corrosion ; nickel alloys ; composites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation and hot corrosion behavior of a tungsten-fiber, reinforced Ni~ 20Cr alloy has been examined under the following exposure conditions: (a) pure oxygen at 1 atm pressure; (b) sulfidation in H2–10 %H2S; (c) presulfidation in H2–10 %H2S followed by oxidation in oxygen; and (d) oxidation in 1 atm oxygen after precoating with approximately 1 mg/cm2 of Na2SO4. Rapid oxidation of the tungsten fibers causes considerable distortion of the matrix and catastrophic degradation of the matrix follows. Inter diffusion between the matrix and the fibers is also important. During sulfidation, only the matrix forms sulfides, the fibers remaining unaffected. Consequently, presulfidation, although having a dramatic effect on the oxidation of the matrix does not have a damaging effect on the fibres. Equally, the presence of sodium sulfate is not critical, although severe oxidation of the exposed tungsten fibers is still observed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00613494
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  • 10
    Electronic Resource
    Electronic Resource
    Effect of oxide grain structure on the high-temperature oxidation of Cr (1975)
    Springer
    Oxidation of metals 9 (1975), S. 459-472 
    Details
    ISSN: 1573-4889
    Keywords: Cr ; oxidation ; kinetics ; Cr2O3 grain size ; short-circuit diffusion ; surface ; preparation ; Fe-Cr
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Cr was oxidized in 1 aim O2 at 980, 1090, and 1200°C. ElectropolishedCr and some orientations of etched Cr oxidize rapidly and develop compressive stress in the growing Cr2O3; other orientations oxidize slowly, apparently free of stress. SEM examination of fracture sections shows that the thick oxide is polycrystalline whereas the thin oxide on etched Cr is monocrystalline. It is deduced that the monocrystalline oxide grows by lattice diffusion of cations outward, and the polycrystalline layer by the two-way transport of cation diffusion outward and anion diffusion inward along oxide grain boundaries. The consequent formation of oxide within the body of the polycrystalline layer generates compressive stress and leads to wrinkling by plastic deformation. The activation energy for oxidation of Cr by cation lattice transport is 58 kcal/mole. Polycrystalline Cr2O3 forms on Fe-26Cr alloy, whether electropolished or etched; oxidation is accordingly rapid and accompanied by compressive stress.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00611694
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